Abstract
The Lince–Estefanía stratabound copper deposit in the Michilla district is one of the most important deposits in the Coastal Cordillera of northern Chile and is one of the most representative of this type of deposit. Chalcocite and bornite characterize the main stage of hypogene copper sulfide mineralization. Rhenium and osmium isotopes are used here to constrain the age of hypogene mineralization and the source of osmium contained in these ore minerals. A Re–Os isochron yielded an age of 160±16 Ma (2σ), with an associated initial 187Os/188Os ratio of 1.06±0.09 (mean square of weighted deviates=1.8). This age is consistent with available geochronological data from volcanic rocks that host the mineralization and associated alteration phases. The high initial 187Os/188Os ratio indicates a lower crustal component for the source of Os and, by inference, the Cu sulfides that contain this Os. Late hematite occurs as an isolated phase or, more commonly, is associated with the chalcocite–bornite and supergene chalcocite–covellite associations. Analyses performed on pure hematite indicate a disturbance of the Re–Os system, and hence, this mineral phase is not useful as a Re–Os geochronometer.
References
Astudillo O (1983) Geología y metalogénesis del distrito minero Carolina de Michilla, Antofagasta, II Región, Chile. Thesis, Universidad del Norte, Departamento de Geociencias, Antofagasta p 131
Barra F, Ruiz J, Mathur R, Titley S (2003) A Re–Os study of sulfide minerals from the Bagdad porphyry Cu–Mo deposit, northern Arizona, USA. Miner Depos 38:585–596
Birck JL, RoyBarman M, Capmas F (1997) Re–Os measurements at the femtomole level in natural samples. Geostand Newsl 20:19–27
Boric R, Díaz F, Maksaev V (1990) Geología y yacimientos metalíferos de la Región de Antofagasta. Servicio Nacional de Geología y Minería, Santiago, Bol 40, p 246
Campano P, Guerra N (1979) Contribución al estudio geoquímico de rocas volcánicas del Norte de Chile comprendidas entre las latitudes 22°00′ y 26°30′S. Actas 2do Congreso Geológico Chileno, Arica, pp J109–J126
Chávez W (1985) Geological setting and the nature and distribution of disseminated copper mineralization of the Mantos Blancos district, Antofagasta province, Chile. Ph.D. Thesis, California University
Creaser RA, Papanastassiou DA, Wasserburg GJ (1991) Negative thermal ion mass spectrometer of Os, Re and Ir. Geochim Cosmochim Acta 55:397–401
Espinoza S (1981) Esbozo metalogénico del Distrito Carolina de Michilla, Segunda Región, Chile. Actas 1er Coloquio sobre Volcanismo y Metalogénesis, Departamento de Geociencias, Universidad del Norte, Antofagasta, pp 71–79
Espinoza S (1982) Definición del tipo diseminado infravolcánico de sulfuros de cobre, vol. 3. Actas 3rd Congr Geológico Chileno, Concepción, pp E201–E219
Espinoza S, Palacios C (1982) Metalogénesis de los yacimientos de cobre en la Cordillera de la Costa entre Taltal y Tocopilla (22°–26° S), Chile, vol 3. Actas 5th Congr Latinoamericano de Geología, Buenos Aires, pp 51–63
Espinoza S, Orquera W (1988) El yacimiento de cobre Buena Esperanza, geología y alteración de la zona de superficie. Nuevas evidencias sobre edad y génesis, vol. 3. Actas 5th Congr Geológico Chileno, Santiago, pp G1–G20
Foster JG, Lambert DD, Frick LR, Maas R (1996) Re–Os isotopic evidence for genesis of Archean nickel ores from uncontaminated komatiites. Nature 382:703–706
Frei R, Nägler T, Schonberg R, Kramers J (1998) Re–Os, Sm–Nd, U–Pb and stepwise lead leaching isotope systematics in shear zone hosted gold mineralization: genetic tracing and age constraints of crustal hydrothermal activity. Geochim Cosmochim Acta 62:1925–1936
García F (1967) Geología del Norte Grande de Chile. In: Symposium sobre el Geosinclinal Andino, Soc Geológica de Chile, Santiago, p 138 (No 3)
Klohn E, Holmgren C, Ruge H (1990) El Soldado, a strata-bound copper deposit associated with alkaline volcanism in the central Chilean Coastal Range. In: Fontboté L, Amstutz G, Cardozo M, Cedillo E, Frutos J (eds) Stratabound Ore Deposits in the Andes. Springer, Berlin Heidelberg New York, pp 435–448
Kojima S, Astudillo J, Rojo J, Tristá D, Hayashi K (2003) Ore mineralogy, fluid inclusion, and stable isotopic characteristics of stratiform copper deposits in the coastal Cordillera of northern Chile. Miner Depos 38:208–216
Lambert DD, Foster JG, Frick LR, Hoatson DM, Purvis AC (1998) Application of the Re–Os isotopic system to the study of Precambrian magmatic sulfide deposits of Western Australia. Aust J Earth Sci 45:265–284
Lambert DD, Foster JG, Frick LR (1999) Re–Os isotope geochemistry of magmatic sulfide ore systems. Rev Econ Geol 12:29–57
Losert J (1973) Genesis of copper mineralizations and associated alterations in the Jurassic volcanic rocks of the Buena Esperanza mining area. Departamento de Geología, Universidad de Chile, Santiago, p 104 (Publ 40)
Lucassen F, Franz G (1994) Arc related Jurassic igneous and meta-igneous rocks in the Coastal Cordillera of northern Chile, Region Antofagasta. Lithos 32:273–298
Ludwig KR (2001) Isoplot /Ex version 2.49. A geochronological toolkit for Microsoft Excel. Berkeley Geochronological Center Spec Publ la
Maksaev V (1990) Metallogeny, geological evolution, and thermochronology of the Chilean Andes between latitudes 21° and 26° south, and the origin of major porphyry copper deposits. Ph.D. Thesis, Dalhousie University
Marcantonio F, Zindler A, Reisberg L, Mathez EA (1993) Re–Os isotopic systematics in chromitites from the Stillwater Complex, Montana. Geochim Cosmochim Acta 57:4029–4037
Marcantonio F, Reisberg L, Zindler A, Wyman D, Hulbert L (1994) An isotopic study of the Ni–Cu–PGE-rich Wellgreen intrusion of the Wrangellia Terrane: evidence for hydrothermal mobilization of rhenium and osmium. Geochim Cosmochim Acta 58:1007–1017
Marinovic N, Smoje I, Maksaev V, Hervé M, Mpodozis C (1995) Hoja Aguas Blancas, Región de Antofagasta. Servicio Nacional de Geología y Minería, Santiago. Carta Geol Chile 70:150
Mathur R, Ruiz J, Munizaga F (2000) Relationship between copper tonnage of Chilean base-metal porphyry deposits and Os isotope ratios. Geology 28:555–558
McCandless TE, Ruiz J, Campbell AR (1993) Rhenium behavior in molybdenite in hypogene and near-surface environments: implications for Re–Os geochronometry. Geochim Cosmochim Acta 57:889–905
Morelli RM, Creaser RA, Selby D, Kelley KD, Leach DL, King AR (2004) Re–Os sulfide geochronology of the Red Dog sediment-hosted Zn–Pb–Ag deposit, Brooks Range, Alaska. Econ Geol 99:1569–1576
Nägler TF, Frei R (1997) Plug in plug osmium distillation. Schweiz Mineral Petrogr Mitt 77:123–127
Niemeyer H, Standen R, Venegas R (1990) Geología del Distrito Minero Carolina de Michilla. Proyecto de Exploración Geología Distrital. Compañía Minera Michilla S.A. Informe Inédito, p 195
Oliveros V, Féraud G, Aguirre L, Fornari M (2004a) Beginning of the Andean subduction system: new 40Ar/39Ar age and geochemical data from the Coastal Range, Northern Chile (18°30′–24°S, 70–70°30′W). CD-R, IAVCEI, Pucón, Chile
Oliveros V, Féraud G, Aguirre L, Fornari M, Ramirez L, Palacios C, Parada MA, Tristá D (2004b) 40Ar/39Ar dating of magmatic, alteration and copper mineralization events related to the Mesozoic subduction system in the Coastal Range, Northern Chile (22–24° S, 70–70°30′W). CD-R, IAVCEI, Pucón, Chile
Palacios C, Definis A (1981) Petrología del yacimiento Buena Esperanza, II Región, norte de Chile. In: Actas 1er Coloquio sobre volcanismo y metalogénesis. Departamento de Geociencias, Universidad Católica del Norte, Antofagasta, pp 48–67
Rogers G, Hawkesworth CJ (1989) A geochemical traverse across the North Chilean Andes: evidence for crust generation from the mantle wedge. Earth Planet Sci Lett 91:271–285
Ruiz J, Mathur R (1999) Metallogenesis in continental margins: Re–Os evidence from porphyry copper deposits in Chile. Rev Econ Geol 12:197–204
Ruíz C, Aguilar A, Egert E, Espinoza W, Peebles F, Quezada R, Serrano M (1971) Strata-bound copper sulphide deposits of Chile. Soc Mining Geol Japan Spec Issue 3:252–260
Sato K (1984) Manto type copper deposits in Chile: a review. Bull Geol Surv Japan 35:565–582
Scheuber E, González G (1999) Tectonics of the Jurassic–Early Cretaceous magmatic arc of the north Chilean Coastal Cordillera (22°–26°): a story of crustal deformation along a convergent plate boundary. Tectonics 18:895–910
Scheuber E, Reutter K-J (1992) Magmatic arc tectonics in the Central Andes between 21° and 25°S. Tectonophysics 205:127–140
Shirey SB, Walker RJ (1995) Carius tube digestion for low-blank rhenium-osmium análisis. Anal Chem 67:2136–2141
Venegas R, Munizaga F, Tassinari C (1991) Los yacimientos de Cu–Ag del distrito Carolina de Michilla, Región de Antofagasta, Chile: nuevos antecedentes geocronológicos, vol 1. Actas 6th Congr Geológico Chileno, Viña del Mar, pp 452–455
Vivallo W, Henríquez F (1998) Génesis común de los yacimientos estratoligados y vetiformes de cobre del Jurásico Medio a Superior en la Cordillera de la Costa, Región de Antofagasta, Chile. Rev Geol Chile 25:199–228
Völkening J, Walczyk T, Heumann KG (1991) Osmium isotope ratio determinations by negative thermal ionization mass spectrometry. Inter J Mass Spectr Ion Proc 105:147–159
Wolf F, Fontboté L, Amstutz G (1990) The Susana copper (-silver) deposit in Northern Chile. Hydrothermal mineralization associated with a Jurassic volcanic arc. In: Fontboté L, Amstutz G, Cardozo M, Cedillo E, Frutos J (eds) Stratabound ore deposits in the Andes. Springer, Berlin Heidelberg New York, pp 319–338
Xiong Y, Wood SA (1999) Experimental determination of the solubility of ReO2 and dominant oxidation state of rhenium in hydrothermal solutions. Chem Geol 158:245–256
Xiong Y, Wood SA (2000) Experimental quantification of hydrothermal solubility of platinum-group elements with special reference to porphyry copper environments. Miner Petrol 68:1–28
Acknowledgements
We thank the Geology department of Minera Michilla SA for their help and geological contribution. We thank Mark Baker and John Chesley of The University of Arizona for their assistance with the analytical work. We thank John Chesley and Victor Valencia for helpful comments and discussions. The manuscript has also benefited from reviews by Anders Schersten and an anonymous reviewer. Editorial comments by Bernd Lehmann are greatly appreciated. This study was partially supported by a Mejoramiento de la Equidad y la Calidad de la Educación Superior-Chile scholarship and Minera Michilla SA.
Author information
Authors and Affiliations
Corresponding author
Additional information
Editorial handling: M. Chiaradia
Rights and permissions
About this article
Cite this article
Tristá-Aguilera, D., Barra, F., Ruiz, J. et al. Re–Os isotope systematics for the Lince–Estefanía deposit: constraints on the timing and source of copper mineralization in a stratabound copper deposit, Coastal Cordillera of Northern Chile. Miner Deposita 41, 99–105 (2006). https://doi.org/10.1007/s00126-006-0048-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00126-006-0048-8