Abstract
The Zn–Pb–Cu ore deposit of Rammelsberg is characterized by a complex fluid flow history. The main phase of ore deposition occurred during the Middle Devonian in the Rhenohercynian basin. The Kniest zone underlying the stratiform ore is interpreted as the feeder zone, along which hydrothermal fluids migrated upward and were expelled on the sea floor. Mineralizing brines possibly had a minimum temperature of 130°C, and salinity ranged between 4.9 and 10.3 eq. wt.% NaCl. The ore and its host rock became folded during the Variscan orogeny, and low salinity fluids (1.0 to 2.3 eq. wt.% NaCl) were mobilized during this tectonic period. Remobilization of the ore took place during the Mesozoic by a high salinity (17.3 to 20.2 eq. wt.% NaCl) H2O–NaCl–CaCl2 fluid.
References
Amstutz GC, Zimmermann RA, Schot EH (1971) The Devonian mineral belt of western Germany (the mines of Meggen, Ramsbeck and Rammelsberg), geotectonic framework. Sedimentology of parts of central Europe. Guidebook 8 Int Sediment Congress, pp 253–272
Anger G, Nielsen H, Puchelt H, Ricke W (1966) Sulfur isotopes in the Rammelsberg ore deposit (Germany). Econ Geol 61:511–536
Bakker RJ (1997) Clathrates: computer programs to calculate fluid inclusion V–X properties using clathrate melting temperatures. Comput Geosci 23:1–18
Behr HJ, Gerler J, Hein UF, Reutel CJ (1993) Tectonic Brines und Basement Brines in den mitteleuropäischen Varisziden: Herkunft, metallogenetische Bedeutung und geologische Aktivität. Gött Arb Geol Paläontol 58:3–28
Boni M, Muchez P, Schneider J (2002) Permo-Mesozoic multiple fluid flow and mineralization in Sardinia and the post-Variscan evolution of Western Europe. In: Blundell DJ, Neubauer F, van Quadt A (eds) The timing and location of major ore deposits in an evolving orogen, vol 204. Geological Society of London, London, pp 199–212 (Spec Publ)
Brown EB (1989) FLINCOR: a microscopic program for the reduction and investigation of fluid inclusion data. Am Mineral 74:1390–1393
Burkhard M (1993) Calcite twins, their geometry, appearance and significance as stress-strain markers and indicators of tectonic regime: a review. J Struct Geol 15:351–368
Crawford ML (1981) Phase equilibria in aqueous fluid inclusions. In: Hollister LS, Crawford ML (eds) Short course in fluid inclusions: applications to petrology, vol 6. Mineralogical Association of Canada, Ottawa, pp 75–100
Duan Z, Möller N, Weare JH (1996) A general equation of state for supercritical fluid mixture PVTX properties. Geochim Cosmochim Acta 60:1209–1216
Franke W (1995) Stratigraphy. in: Dallmeyer D, Franke W, Weber K (eds) Pre-Permian geology of central and Eastern Europe. Springer, Berlin Heidelberg New York, pp 34–39
Hannak WW (1981) Genesis of the Rammelsberg ore deposit near Goslar Upper Harz. In: Wolf KH (ed) Handbook of stratabound and stratiform ore deposits, vol 9. Elsevier, Amsterdam, pp 551–642
Hein UF (1993) Synmetamorphic Variscan siderite mineralisation of the Rhenish Massif, central Europe. Mineral Mag 57:451–467
Hein UF, Osswald U, Behr HJ (1993) The fluid inclusion record of siliceous exhalites, lower carboniferous of Rhenish Massif Germany. Arch Mineral 49:96–98
Hein UF, Osswald U, Behr HJ (1994) Zur Charakterisierung erzbildender lösungen mittels fluideinschlußuntersuchungen: unterkarbonische eisenkiesel als fallstudie für die exhalativ-sedimentäre lagerstättenbildung. Berl Geowiss Abh 167:197–204
Krebs W, Gwosdz W (1985) Ore controlling parameters of Devonian stratiform lead–zinc–barite ores in central Europe. Geol Jahrb D70:9–36
Large DE (2003) The tectonic setting of base-metal mineralization in the Rhenohercynian terranes of central Europe. In: Keely JG, Andrew CJ, Ashton JH, Boland MB, Earls G, Fusciardi L, Stanley G (eds) Europe’s major base metal deposits. Irish Association for Economic Geology, Dublin, pp 155–168
Large DE, Walcher E (1999) The Rammelsberg massive sulphide Cu–Zn–Pb–Ba-deposit, Germany: an example of sediment-hosted, massive sulphide mineralisation. Miner Depos 34:522–538
Lüders V, Möller P (1992) Fluid evolution and ore deposition in the Harz Mountains (Germany). Eur J Mineral 4:1053–1068
Muchez Ph, Marshall JD, Touret JLR, Viaene WA (1994) Origin and migration of palaeofluids in the Upper Visean of the Campine basin, northern Belgium. Sedimentology 41:133–145
Oncken O, Von Winterfeld C, Dittmar U (1999) Accretion and inversion of a rifted passive margin—the Late Palaeozoic Rhenohercynian fold and thrust belt. Tectonics 18:75–91
Passchier CW, Touw RAJ (1996) Microtectonics. Springer, Berlin Heidelberg New York
Peterek A, Rauche H, Schröder B, Franzke HJ, Bankwitz B, Bankwitz E (1997) The late- and post-Variscan tectonic evolution of the Western Border fault zone of the Bohemian Massif (WBZ). Geol Rundsch 86:191–202
Ramdohr P (1953) Mineralbestand, Strukturen und Genesis der Rammelsberg-Lagerstätte. Geol Jahrb D67:367–494
Sperling H, Walcher E (1990) Die Blei-Zink-Erzlagerstätte Rammelsberg (ausgenommen Neues Lager). Geol Jahrb D91:3–153
Van den Kerhof AM, Hein UF (2001) Fluid inclusion petrography. Lithos 55:27–47
Werner W (1989) Contribution to the genesis of the SEDEX-type mineralizations of the Rhenish Massif (Germany)—implications for future Pb–Zn exploration. Geol Rundsch 78:571–598
Werner W (1990) Examples of structural control of hydrothermal mineralization: fault zones in epicontinental sedimentary basins—a review. Geol Rundsch 79:279–290
Werner W, Walther HW (1995) Metallogenesis. In: Dallmeyer D, Franke W, Weber K (eds) Pre-Permian geology of Central and Eastern Europe. Springer, Berlin Heidelberg New York, pp 87–95
Wilkinson JJ (2001) Fluid inclusions in hydrothermal ore deposits. Lithos 55:229–272
Wilkinson JJ, Jenkin GRT, Fallick AE, Foster RP (1995) Oxygen and hydrogen isotopic evolution of Variscan crustal fluids, south Cornwall, UK. Chem Geol 123:239–254
Acknowledgements
We would like to thank Duncan Large, Ulrich Hein, and Bernd Lehmann for their constructive reviews and suggestions. We are grateful to Stijn Dewaele, Wouter Heijlen, and Jens Schneider for stimulating discussion on the Rammelsberg ore deposits. We would like to thank Karl Strauss (Institut für Minerlogie und Mineralische Rohstoffe, TU Clausthal), who kindly helped us with the sampling at the mineral collection at the TU Clausthal, and Ir. Koch and Ir. Meier (Bergbau Goslar GmbH) for the permission to take samples of the Rammelsberg collection. Jacques Wautier kindly provided the microprobe analysis, and Herman Nijs carefully prepared sections and doubly polished wafers.
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Muchez, P., Stassen, P. Multiple origin of the ‘Kniest feeder zone’ of the stratiform Zn–Pb–Cu ore deposit of Rammelsberg, Germany. Miner Deposita 41, 46–51 (2006). https://doi.org/10.1007/s00126-005-0039-1
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DOI: https://doi.org/10.1007/s00126-005-0039-1