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Ni–Cu–(PGE) magmatic sulfide deposits in the Yangliuping area, Permian Emeishan igneous province, SW China

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Abstract

The Ni–Cu–PGE sulfide deposits in the Yangliuping area, SW China, are hosted in mafic–ultramafic sills. The four mineralized sills are located in the Yangliuping tectonic dome and intrude Devonian carbonaceous marble, graphitic schist. The sills are 200–300 m thick and 1,000–2,000 m in strike length and now consist chiefly of serpentinite, talc schist, tremolite schist, and meta-gabbro. Disseminated Ni–Cu sulfide mineralisation occurs in the serpentinite in the lower parts of the sills. Massive sulfide mineralisation is located in the base of the sills and in the footwall along fractures beneath the mineralized serpentinite. Although the sulfide ores have been modified by hydrothermal activity, there are relict cumulate textures in the disseminated sulfides indicating a magmatic origin for the ores. The Yangliuping Intrusions and the Dashibao Formation have similar primitive-mantle normalized trace element and platinum group element (PGE) patterns, indicating that they are derived from a common parental magma type. The positive correlation between Cu concentrations and Cu/Zr ratios of the Dashibao Formation basalts indicates that the chalcophile elements were removed before eruption. We propose that fractional crystallization of the Yangliuping magma accompanied by the introduction of S and CO2 from the wall rocks caused the magma to become S-saturated leading to the segregation of magmatic sulfides that became enriched in Ni–Cu–(PGE). The sills acted as conduits for the overlying Dashibao Formation basalts with the sulfide liquid, along with early crystallizing olivine and pyroxene, segregating from the magma as it passed through the conduits prior to eruption.

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References

  • Arne D, Worley B, Wilson C Fa CS, Foster D, Li LZ, Gen LS, Dirks P (1997) Differential exhumation in response to episodic thrusting along the eastern margin of the Tibetan Plateau. Tectonophysics 280:239–256

    Article  CAS  Google Scholar 

  • Arth JG (1976) Behavior of trace elements during magmatic processes-a summary of theoretical models and their applications. J Res US Geol Surv 4:41–47

    CAS  Google Scholar 

  • Barnes S-J. Maier WD (1999) The fractionation of Ni, Cu and the noble metals in silicate and sulfide liquids, In: Keays RR, Lesher CM, Lightfoot PC, Farrow CEG (eds) Dynamic processes in magmatic ore deposits and their application to mineral exploration. Geological Association of Canada, pp 69–107

  • Barnes S-J, Zientek ML, Severson MJ (1997) Ni, Cu, Au and platinum-group element contents of sulfides associated with intraplate magmatism. Can J Earth Sci 34:337–351

    CAS  Google Scholar 

  • Bezmen NS, Asif M, Brugmann GE, Romanekno IM, Naldrett AJ (1994) Experimental determinations of sulfide-silicate partitioning of PGE and Au. Geochim Cosmochim Acta 58:1251–1260

    CAS  Google Scholar 

  • Brugmann GE, Naldrett AJ, Asif M, Lightfoot PC, Gorbachev NS, Fedorenko VA (1993) Siderophile and chalcophile metals as tracers of the evolution of the Siberian Flood Basalts in the Noril'sk region, Russia. Geochem Cosmochim Acta 57:2001–2018

    CAS  Google Scholar 

  • Bruguier O, Lancelot JR, Malavieille J (1997) U–Pb dating on single detrital zircon grains from the Triassic Songpan-Ganze flysch (central China): provenance and tectonic correlations. Earth Planet Sci Lett 152:217–231

    CAS  Google Scholar 

  • Bureau of Geological and Mineral Resources of Sichuan Province (BGMS) (1982) Exploration report of the Zhengziyanwuo and Yangliuping Pt–Ni deposits, Danba, Sichuan (in Chinese)

  • Bureau of Geological and Mineral Resources of Sichuan Province (1991) Regional geology of Sichuan Province (in Chinese with English abstract). Geological Publishing House, Beijing, pp 1–680

  • Chang EZ (2000) Geology and tectonics of the Songpan–Ganzi fold belt, Southwestern China. Int Geol Rev 42:813–831

    Google Scholar 

  • Chung SL, Jahn BM (1995) Plume-lithosphere interaction in generation of the Emeishan flood basalts at the Permian–Triassic boundary. Geology 23:889–892

    Article  CAS  Google Scholar 

  • Cong BL (1988) Formation and evolution of the Panxi rift (in Chinese). Science Publishing House, Beijing

  • Craig JR, Vaughan DJ (1994) Ore microscopy and ore petrography. Wiley, New York

  • Fleet ME, Stone WE (1991) Partitioning of platinum-group elements in the Fe–Ni–S system and their fractionation in nature. Geochim Cosmochim Acta 55:245–253

    CAS  Google Scholar 

  • Gorbachev NS, Kashirceva GA (1986) Fluid-magmatic differentiation of basaltic magma and equilibrium with magmatic sulfides. In: Experiments in the study of important problems in geology. Nauka, Moscow, pp 98–1198

  • Greenough JD, Owen JV (1992) Platinum-group-element geochemistry of continental tholeiites, analyses of the Long Range dyke swarm, Newfoundland, Canada. Chem Geol 98:203–219

    CAS  Google Scholar 

  • Haughton DR, Roeder PL, Skinner BJ (1974) Solubility of sulfur in mafic magma. Econ Geol 69:451–467

    CAS  Google Scholar 

  • Irvine TN (1975) Crystallization sequences of the Muskox intrusion and other layered intrusions. 11. Origin of chromitite layers and similar deposits of other magmatic ores. Geochim Cosmochim Acta 39:991–1020

    Google Scholar 

  • Irving AJ (1978) A review of experimental studies of crystal/liquid trace element partitioning. Geochim Cosmochim Acta 42:743–770

    Google Scholar 

  • Jenner GA, Longerich HP, Jackson SE, Fryer BJ (1990) ICP-MSa powerful tool for high precision trace element analyses in earth sciences: evidence from analyses of selected USGS reference samples. Chem Geol 83:133–148

    CAS  Google Scholar 

  • Keays RR (1995) The role of komatiitic and picritic magmatism and S-saturation in the formation of ore deposits. Lithos 34:1–18

    CAS  Google Scholar 

  • Keays RR, Nickel EH, Groves DI, McGoldrick PJ (1982) Iridium and palladium as discriminants of volcanic-exhalative, hydrothermal, and magmatic nickel sulfide mineralisation. Econ Geol 77:1535–1547

    CAS  Google Scholar 

  • Li CS, Naldrett (1999) Geology and petrology of the Voisey's Bay troctolite complex: reaction of olivine with trapped sulphide and silicate liquids. Lithos 47:1–31

    Article  CAS  Google Scholar 

  • Li CS, Naldrett AJ, Coats CJA, Johannessen P (1992) Platinum, palladium, gold and copper-rich stringers at Strathcona mine, Sudbury: their enrichment by fractionation of a sulfide liquid. Econ Geol 87:1584–1596

    Google Scholar 

  • Li CS, Maier WD, Waal SAD (2001) The role of magma mixing in the genesis of PGE mineralisation in the Bushveld complex: thermodynamic calculation and new interpretations. Econ Geol 96:653–662

    CAS  Google Scholar 

  • Lightfoot PC, Hawkesworth CJ (1997) Flood basalts and magmatic Ni, Cu and PGE sulfide mineralisation: comparative geochemistry of the Noril'sk (Siberian Flood Basalts) and West Greenland sequences. American Geophysical Union, Washington, DC, pp 357–380

  • Lightfoot PC, Naldrett AJ, Gorbachev NS, Fedorenko VA, Hawkesworth CJ, Doherty W (1994) Chemostratigraphy of Siberian Flood Basalts lavas, Noril'sk district, Russia: Implication and source of flood basalt magmas and their associated Ni–Cu mineralisation. In: Lightfoot PC, Naldrett AJ (eds) Proceedings of the Sudbury-Noril'sk symposium. Ontario Geological Survey Special Publication no 5, pp 283–312

  • Naldrett AJ (1989) Magmatic sulfide deposits. Clarendon Press, New York

  • Naldrett AJ (1999) World-class Ni–Cu–(PGE) deposits: key factors in their genesis. Miner Deposita 34:227–240

    CAS  Google Scholar 

  • Naldrett AJ, Lightfoot PC (1999) Ni–Cu–(PGE) deposits of the Noril'sk region, Siberia, dynamic processes. In: Keays RR, Lesher CM, Lightfoot PC, Farrow CEG (eds) Magmatic ore deposits and their application to mineral exploration. Geological Association of Canada, Washington, DC, pp 195–250

  • Naldrett AJ, Craig JR, Kullerud G (1967) The central portion of the Fe–Ni–S system and its bearing on pentlandite exsolution in iron–nickel sulfide ores. Econ Geol 62:826–847

    CAS  Google Scholar 

  • Naldrett AJ, Lightfoot PC, Federenko VA, Doherty W, Gorbachev NS (1992) Geology and geochemistry of intrusion and flood basalts of the Noril'sk region, USSR, with implication for the origin of the Ni–Cu ores. Econ Geol 87:975–1004

    CAS  Google Scholar 

  • Naldrett AJ, Fedorenko VA, Lightfoot PC, Kunilov VI, Gorbachev NS, Doherty W, Johan Z (1995) Ni–Cu–PGE deposits of the Noril'sk region, Siberia: their formation in conduits for flood basalt volcanism. Trans Inst Mining Metall 104:B1-86

    Google Scholar 

  • Naldrett AJ, Keats H, Sparkes K, Moore R (1996) Geology of the Voisey's Bay Deposit, Labrador, Canada. Explor Mining Geol 5:169–179

    CAS  Google Scholar 

  • Peach CL, Mathez EA, Keays RR, Reeves SJ (1994) Experimentally determined sulfide melt-silicate melt partition coefficients for iridium and palladium. Chem Geol 117:361–377

    CAS  Google Scholar 

  • Rollinson HR (1996) Using geological data: evaluation, Presentation, Interpretation, Longman Group, London

    Google Scholar 

  • Saunders AD, Storey M, Kent RW, Norry MJ (1992) Consequences of plume–lithosphere interaction, In: Storey BC, Alabaster T, Pankhurst RJ, Magmatism (eds) The causes of continental breakup. Geol Soc Lond Spec Publ 68:41–60

    Google Scholar 

  • Bureau of Geology and Mineral Resources of Sichuan Province (1991) Regional geology of Sichuan Province (in Chinese with English abstract). Geological Publishing House, Beijing, pp 1–680

  • Song X-Y, Zhou M-F, Hou Z-Q, Cao Z-M, Wang Y-L, Li Y-G (2001) Geochemical constraints on the mantle source of the Upper Permian Emeishan continental flood basalts, southwestern China. Int Geol Rev 43:213–225

    Google Scholar 

  • Stribrny B (1996) Platinmetall-und Goldagerstatten: Vorkommen, Produktion und Reserven. Erzmetall 49(3):191–195

    Google Scholar 

  • Sun S-S, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implication for mantle composition and processes. In: Saunders AD Norry MJ (eds) Magmatism in the ocean basins. Geol Soc Lond Spec. Publ 42:313–345

    Google Scholar 

  • Sun M, Jain JS, Zhou M-F, Kerrich R (1993) A procedural modification for enhanced recovery of precious metals (Au, PGE) following nickel sulfide fire assay and tellurium coprecipitation: applications for analyses of geological samples by inductively-coupled plasma-mass spectrometry. Can J Appl Spectrosc 38:103–108

    CAS  Google Scholar 

  • Wang DH, Chu Y S, Luo FX (2001) The geochemical characteristics and the mineralisation of the basic-ultrabasic rocks in the Yangliuping Cu–Ni–PGE deposit, Sichuan (in Chinese). J Earth 22(2):135–140

    CAS  Google Scholar 

  • Yan DP, Zhou M-F, Song HL, Fu ZR (2002) Structural style and tectonic significance of the Jianglang metamorphic core complex, eastern margin of the Tibetan Plateau, China. J Struct Geol 5(5):765–779

    Google Scholar 

  • Yund RA, Kullerud G (1966) Thermal stability of assemblages in the Cu–Fe–S system. J Petrol 7:454–488

    Google Scholar 

  • Zhang XY, Luo YN (1988) The Panxi Rift (in Chinese). Geological Publishing House, Beijing

  • Zhong H, Zhou XH, Zhou M-F, Sun M, Liu BG (2002) Platinum-group element geochemistry of the Hongge Fe–V–Ti deposit in the Pan-Xi area, southwestern China. Miner Deposita 37:226–239

    Article  CAS  Google Scholar 

  • Zhou M-F, Malpas J, Sun M, Liu Y, Fu X (2001) A new method to correct Ni- and Cu-argide interference in the determination of the platinum-group elements, Ru, Rh, and Pd, by ICP-MS. Geochem J 35:413–420

    CAS  Google Scholar 

  • Zhou M-F, Malpas J, Song XY, Robinson PT, Sun M, Kennedy AK, Lesher CM, Keays RR (2002a) A temporal link between the Emeishan Large Igneous Province (SW China) and the end-Guadalupian mass extinction. Earth Planet Sci Lett 196:113–122

    Article  CAS  Google Scholar 

  • Zhou M-F, Yang ZX, Song XY, Keays RR, Lesher CM (2002b) Magmatic Ni–Cu–(PGE) sulfide deposits in China. In: Cabri LJ (ed) The geology, geochemistry, mineralogy, mineral benification of the platinum-group elements. Can Inst Mining, Metall Petrol, Spec Vol 54:619–636

  • Zhou M-F, Yan DP, Kennedy AK, Li YQ, Ding J (2002c) SHRIMP U–Pb zircon geochronological and geochemical evidence for Neoproterozoic, arc-magmatism along the western margin of the Yangtze Block, South China. Earth Planet Sci Lett 196:51–67

    Article  CAS  Google Scholar 

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Acknowledgements

This study was funded by the Research Grant Council of the Hong Kong SAR, China (P7301/99P and P7101/01P to MFZ) and grants from China (NSFC no. 40072037 and NKBRSF project G1999043205). We gratefully acknowledge the kind help of Mr. Luo Fu-Xun, Mr. Zhu Ting-Guo, Mr. Chen Jia-Zhong, and other members of the 402 Geological Team of Sichuan Province, China, during our field investigation. We are very grateful to Dr. R.J. Goldfarb and Dr. O. Thalhammer for detailed and insightful comments on an earlier draft. Prof. R.R. Keays, Dr. C. Li, Dr. P.C. Lightfoot, and Prof. P.T. Robinson have considerably improved the current version of this manuscript.

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Correspondence to Xie-Yan Song.

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Editorial handling: H.E. Frimmel

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Song, XY., Zhou, MF., Cao, ZM. et al. Ni–Cu–(PGE) magmatic sulfide deposits in the Yangliuping area, Permian Emeishan igneous province, SW China. Miner Deposita 38, 831–843 (2003). https://doi.org/10.1007/s00126-003-0362-3

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