Abstract
The stability of lignite humic acids and four regenerated humic acids was estimated by employing differential scanning calorimetry. Induction period for the oxidative decomposition of humic matter was calculated from non-isothermal measurements at six different rates of heating. To simulate the gradual evolution history of humic acids, different intensities of oxidation attack by nitric acid on the original lignite was used. Experimental data showed higher stability of natural humic acids in the temperature range where the decomposition step occurred. On the other hand, extrapolation to lower temperatures and calculated kinetic parameters did not correspond to the order observed at higher temperatures. An oscillating trend of calculated parameters of the two proposed parts of stability was observed, which agreed with data concerning regenerated humic acids production. The approach applied in this work represents a rapid and useful method for evaluation of organic matter stability.
Similar content being viewed by others
References
Buurman P, Aran D (1997) Relation between thermal and microbial degradability in podzol organic matter. In: Drozd J, Gonet SS, Senesi N, Weber J (eds) The Role of Humic Substances in the Ecosystems and in Environmetal Protection. Poland, pp 295–300
Dell’Abate MT, Benedetti A, Brookes PC (2003) Hyphenated techniques of thermal analysis for characterization of soil humic substances. J Sep Sci 26:433–440
Eichinger L, Abbt-Braun G, Frimmel FH (1994) Biodegradation of humic substances. In: Senesi N (ed) Humic substances in the global environment and implications on human health. Elsevier, Amsterdam, pp 283–291
Kučerík J, Pekař M, Klučáková M (2003) South Moravian lignite – potential source of humic substances. Petrol Coal 45:58–62
Kučerík J, Kovář J, Pekař M (2004) Thermoanalytical investigation of lignite humic acids fractions. Therm Anal Cal 76:55–65
Piccolo A (2001) The supramolecular structure of humic substances. Soil Sci 166:810–832
Rausa R, Girardi E, Calemma V (1994) Humic acids from coal. Production, characterization and utilization. In: Senesi N (ed) Humic substances in the global environment and implications on human health. Elsevier, Amsterdam, pp 1225–1244
Siewert C (2001) Investigation of the thermal and biological stability of soil organic matter. Shaker-Verlag, Aachen
Stevenson FJ (1994) Humus chemistry: genesis, composition, reactions. 2nd edn. J. Wiley, New York
Spaccini R, Piccolo A, Haberhauer G, Gerzabek MH (2000) Transformation of organic matter from maize residues into labile and humic fractions of three European soils as revealed by13C distribution and CPMAS-NMR spectra. Eur J Soil Sci 51:583–594
Šimon P, Kučma A (1999) DSC analysis of the induction period in the vulcanisation of rubber compounds. J Therm Anal Cal, 56:1107–1113.
Šimon P, Kolman Ľ (2001) DSC study of oxidation induction periods. J Therm Anal Cal 64:813–820
Šimon P (2004) Isoconversional methods. Fundamentals, meaning and application. J Therm Anal Cal 76:123-132
Acknowledgements
The authors would like to thank to Dr Ashish Deshmukh and the unknown second referee for their help with the manuscript and for inspiring suggestions
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Kučerík, J., Kovář, J., Pekař, M. et al. Evaluation of oxidation stability of lignite humic substances by DSC induction period measurement. Naturwissenschaften 92, 336–340 (2005). https://doi.org/10.1007/s00114-005-0638-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s00114-005-0638-9