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Evaluation of wood treated with Paraloid B72® and boric acid: thermal behavior, water absorption and mold resistance

Abstract

Consolidation of wood is one of the actions to be taken once wood materials are degraded by biotic or abiotic factors to keep its structural functions. While maintaining structural integrity is a priority in consolidation work, consolidant system should also be compatible and must allow the combination of additives. Besides improved performance, proper protection against thermal degradation is needed as well when consolidated wood is subjected to elevated temperatures. Mass loss calorimeter tests and thermogravimetric analyses of wood treated with Paraloid B72® copolymer and boric acid were first performed. Effects of the copolymer on boron leaching and mold resistance of the Paraloid B72®-modified specimens were also studied. Water absorption and wettability tests, FTIR and SEM evaluations were performed for characterization on the specimens after modifications with Paraloid B72®. Mass loss calorimeter tests indicated that Paraloid B72® treatments alone decreased the fire resistance of test specimens; however, incorporation of boric acid into Paraloid B72®-treated specimens enhanced the fire resistance. Thermogravimetric analyses showed significant increases in boric acid and Paraloid B72®-treated specimens when compared to Paraloid B72® treatments alone. Paraloid B72® copolymer treatments resulted in less water absorption values in the specimens; however, the copolymer did not effectively limit boron release from modified specimens. While Paraloid B72® treatments increased the hydrophobicity of the specimens, boric acid has partial effect on the wetting properties. No mold inhibition was seen in Paraloid B72® only treated specimens; however, significantly lower mold growth rates were observed in boric acid and Paraloid B72®-treated specimen by vacuum.

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References

  • American Society for Testing Materials (ASTM) (2009) ASTM E 84–09 Standard test method for surface burning characteristics of building materials. American Society for Testing and Materials, West Conshohocken

    Google Scholar 

  • American Society for Testing Materials (ASTM) (2019) ASTM D4445–10. In: Standard Test Method For Fungicides For Controlling Sapstain And Mold On Unseasoned Lumber (Laboratory Method) Annual Book of ASTM Standards, Vol 04.10. ASTM, West Conshohocken, Pennsylvania, USA

  • American Wood Protection Association (AWPA) (2021b) AWPA A21–16. In: Standard Method for the Analysis of Wood and Wood Treating Solutions by Inductively Coupled Plasma Emission Spectrometry. Annual Book of AWPA Standards. AWPA, Birmingham, Alabama, USA

  • Arao Y, Nakamura S, Tomita Y, Takakuwa K, Umemura T, Tanaka T (2014) Improvement on fire retardancy of wood flour/polypropylene composites using various fire retardants. Polym Degrad Stabil 100:79–85

    Article  CAS  Google Scholar 

  • American Wood Protection Association (AWPA) (2021a) AWPA A7–19. In: Standard Wet Ashing Procedures for Preparing Wood for Chemical Analysis. Annual Book of AWPA Standards. AWPA, Birmingham, Alabama, USA

  • Babrauskas V, Peacock RD (1992) Heat release rate: the single most important variable in fire hazard. Fire Saf J 18(3):255–272

    Article  CAS  Google Scholar 

  • Cai L, Lim H, Fitzkee NC, Cosovic B, Jeremic D (2020) Feasibility of manufacturing strand-based wood composite treated with β-cyclodextrin–boric acid for fungal decay resistance. Polymers 12:274

    Article  CAS  Google Scholar 

  • Carretti E, Dei L (2004) Physicochemical characterization of acrylic polymeric resins coating porous materials of artistic interest. Prog Org Coat 46:282–289

    Article  Google Scholar 

  • Cataldi A, Dorigato A, Deflorian F, Pegoretti A (2014) Thermo-mechanical properties of innovative microcrystalline cellulose filled composites for art protection and restoration. J Mater Sci 49:2035–2044

    Article  CAS  Google Scholar 

  • Davidson A, Brown GW (2012) Paraloid TM B-72: practical tips for the vertebrate fossil preparator. Collect Forum 26(1–2):99–119

    Google Scholar 

  • Gao L, Gan W, Xiao S, Zhan X, Li J (2016) A robust superhydrophobic antibacterial Ag–TiO2 composite film immobilized on wood substrate for photodegradation of phenol under visible-light illumination. Ceram Int 42(2):2170–2179

    Article  CAS  Google Scholar 

  • Ge X, Li J, Zhang C, Luo J (2018) Liquid superlubricity of polyethylene glycol aqueous solution achieved with boric acid additive. Langmuir 34:3578–3587

    Article  CAS  Google Scholar 

  • Hakkarainen T, Mikkola E, Östman B, Tsantaridis L, Brumer H, Piispanen P (2005) Innovative eco-efficient high fire performance wood products for demanding applications—State of the art. InnoFireWood—Report by VTT, SP Trätek, KTH Biotechnology, May 2005, pp 47

  • Wood Handbook (2021) Wood Handbook - Wood as an Engineering Material. In: General Technical Report FPL-GTR-282. Madison, WI: U.S. Department of Agriculture, Forest Service, Forest Products Laboratory, pp 543

  • Henriques D, Brito J, Duarte S, Nunes L (2014) Consolidating preservative-treated wood: combined mechanical performance of boron and polymeric products in wood degraded by Coniophora puteana. J Cult Herit 15:10–17

    Article  Google Scholar 

  • Henriques DF, Nunes L, Brito J (2010) Performance of Paraloid B72 combined with the application of biocides on wood degraded by fungi. In: Proceedings of 4th international conference on wooden cultural heritage: interaction between wood science and conservation of cultural heritage, COST Action IE0601, Izmir Turkey

  • International Organization of Standards (ISO) (2015) ISO 13927: Plastics—Simple heat release test using a conical radiant heater and a thermopile detector. International Organization for Standardization, Geneva, Switzerland, p 21

  • Kartal SN, Hwang WJ, Imamura Y (2007) Water absorption of boron-treated and heat-modified wood. J Wood Sci 53:454–457

    Article  CAS  Google Scholar 

  • Kartal SN (2009) Boron-based wood preservatives and their use. In: Chung MP (ed) Handbook on borates: chemistry, production and applications. Nova Science Publishers, Inc. ISBN: 978-1-60741-822-1

  • LeVan SL, Tran HC (1990) The role of boron in flame-retardant treatments. In: Proceedings of the 1st international conference on wood protection with diffusible preservatives. November 28–30, Nashville, TN. Forest Products Research Society, Madison, WI, pp. 39–41

  • Li T, Fan Y, Wang K, Song S, Liu X, Bu N, Li R, Zhen Q, Bashir S (2021) Methyl-modified silica hybrid fluorinated Paraloid B-72 as hydrophobic coatings for the conservation of ancient bricks. Constr Build Mater 299:123906

    Article  CAS  Google Scholar 

  • Liu YT (2016) Synthesis and Application of a Kind of Boron Based Environmental Protection Non-Halogen Flame Retardant. Master’s Thesis, Hebei University of Science and Technology, Tianjin, China

  • Mansour MA, Megeed AA, Nasser RA, Salem MZM (2015) Comparative evaluation of some woody tree methanolic mold fungi Alternaria tenuissima and Fusarium culmorum. BioRsources 10(2):2570–2584

    CAS  Google Scholar 

  • Mouritz AP, Gibson AG (2006) Fire properties of polymer composite materials. Springer, Dordrecht (978-1-4020-5356-6)

    Google Scholar 

  • Muhcu D, Terzi E, Kartal SN, Yoshimura T (2017) Biological performance, water absorption, and swelling of wood treated with nano-particles combined with the application of Paraloid B72®. J for Res 28(2):381–394

    Article  CAS  Google Scholar 

  • Nakhla SM (1986) A comparative study of resins for the consolida- tion of wooden objects. Stud Conserv 31:38–44

    CAS  Google Scholar 

  • Nica L, Sandu I, Vasilache V, Hutanu I, Sandu CAI (2013) The consolidation of the wood panels of two icons from XIXth–XXth century, usibg reversible treatments. Pro Ligno 9(4):306–311

    Google Scholar 

  • British Standards European Standard Norm (BS EN) (2020b) BS EN 84. Durability of wood and wood-based products—Accelerated ageing of treated wood prior to biological testing—Leaching procedure. British Standards Institution (BSI), pp 10

  • British Standards European Standard Norm (BS EN) (2020a) BS EN 113–1: Durability of wood and wood-based products—Test method against wood destroying basidiomycetes. Part 1: Assessment of biocidal efficacy of wood preservatives. British Standards Institution (BSI), pp 34

  • Olstag TM, Kucerova I (2009) Report of focused meeting within the COST action IE0601. Wood Science for Conservation of Cultural Heritage (WoodCultHer)—consolidation, reinforcement & stabilisation of decorated wooden artefacts. Institute of Chemical Techniques, Prague, Czech Republic

  • Reinprecht L, Vidholdová Z (2017) Growth inhibition of moulds on wood surface in presence of nano-zinc oxide and its combinations with polyacylate and essential oils. Wood Res 62(1):37–44

    CAS  Google Scholar 

  • Terzi E (2018) Thermal degradation of particleboards incorporated with colemanite and common boron-based fire retardants. BioResources 13(2):4239–4251

    Article  CAS  Google Scholar 

  • Terzi E, Kartal SN, Gerardin P, Ibanez CM, Yoshimura T (2017) Biological performance of particleboard incorporated with boron minerals. J for Res 28(1):195–203

    Article  CAS  Google Scholar 

  • Trǎistaru AAT, Timar MC, Campean M, Croittoru C, Sandu I (2012) Paraloid B72 versus Paraloid B72 with nano-ZnO additive as consolidants for wooden artifacts. Mater Plast 49(4):293–300

    Google Scholar 

  • Trǎistaru AAT, Sandu ICA, Timar MC, Dumitrescu GL, Sandu I (2013) SEM-EDX, water absorption, and wetting capability studies on evaluation of the influence of nano-Zinc oxide as additive to Paraloid B72 solutions used for wooden artifacts consolidation. Microsc Res Tech 76:209–218

    Article  Google Scholar 

  • Trǎistaru AAT, Timar MC, Campean M (2011) Studies upon penetration of Paraloid B72 into poplar wood by cold immersion treatments. Bull Transilv Univ Bras ̧ov Agricult Food Eng 4(53):81–88

  • Unger A, Schniewind AP, Unger W (2001) Conservation of wood artifacts. Hhandbook. Springer-Verlag, Germany. ISBN: 978-3-540-41580-0

  • Wang QW, Li J, Winandy JE (2004) Chemical mechanism of fire retardance of boric acid on wood. Wood Sci Technol 38:375–389

    Article  CAS  Google Scholar 

  • Yu L, Cai J, Li H, Lu F, Qin D, Fei B (2017) Effects of boric acid and/or borax treatments on the fire resistance of bamboo filament. BioResources 12(3):5296–5307

    Article  CAS  Google Scholar 

  • Zhang QH, Zhang W, Huang JY (2015) Flame retardance and thermal stability of wool fabric treated by boron containing silica sols. Mater Des 85:796–799

    Article  CAS  Google Scholar 

  • Zhang J, Koubaa A, Xing D, Liu W, Wang Q, Wang XM, Wang H (2020) Improving lignocellulose thermal stability by chemicalmodification with boric acid for incorporating into polyamide. Mater Des 190:108589

    Article  Google Scholar 

Download references

Acknowledgements

The authors thank Istanbul University-Cerrahpaşa, Istanbul, Turkey and Erciyes University, Kayseri, Turkey. Some parts of mold resistance tests and thermogravimetric analyses of this study have been submitted to 18th Annual Meeting of the Northern European Network for Wood Science and Engineering, 21-22 September 2022, Göttingen, Germany.

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All authors contributed to the conceptualisation and methodology of the study. Material preparation, data collection and analysis were performed by SNK, EES, ET, MSÖ, KŞ, and NÇ The first draft of the manuscript was written by SNK and MSÖ and all authors commented on subsequent versions of the manuscript. All authors read and approved the final manuscript.

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Correspondence to S. Nami Kartal.

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Soytürk, E.E., Kartal, S.N., Terzi, E. et al. Evaluation of wood treated with Paraloid B72® and boric acid: thermal behavior, water absorption and mold resistance. Eur. J. Wood Prod. (2023). https://doi.org/10.1007/s00107-023-01932-9

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  • DOI: https://doi.org/10.1007/s00107-023-01932-9