Summary.
Whereas the synthesis of α-campholenic compounds starting from α-pinene has been well investigated, only few is known about β-campholenic compounds. We obtained compounds suitable as precursors for the functionalization of the side chain of the β-isomer of the sandalwood flavour Brahmanol®. Now we report about the synthesis and the rearrangement of various β-campholenic epoxides to allylic alcohols or a bicyclic γ-lactone and the synthesis of cyclohexenones from β-campholenic esters.
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Received October 27, 1998. Accepted (revised) January 12, 1999
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Wyßuwa, K., Anhalt, K. & Schulze, K. Darstellung und Reaktionenvon Oxidationsprodukten aus β-Campholenverbindungen. Monatshefte fuer Chemie 130, 809–817 (1999). https://doi.org/10.1007/PL00010262
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DOI: https://doi.org/10.1007/PL00010262