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Electrochemical Investigation of Some Ruthenium-Carborane Complexes at a Glassy Carbon Electrode

Elektrochemische Untersuchung einiger Ruthenium-Carboran-Komplexe an einer Glaskohlenstoffelektrode

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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary.

 Ruthenium complexes of some carboranes were examined using cyclic voltammetry, chronoamperometry, chronopotentiometry, and digital simulation techniques derived from convolution-deconvolution voltammetry. The complexes under consideration are of the type X-RuC2B8H10 (X=hexamethylbenzene, para-cymene); all relevant electrochemical and chemical parameters were deduced and a mechanism is proposed.

Zusammenfassung.

 Rutheniumkomplexe einiger Carborane wurden mit Hilfe zyklischer Voltammetrie, Chronoamperometrie, Chronopotentiometrie und digitaler Simulationstechniken im Zusammenhang mit Konvolutions-Dekonvolutions-Voltammetrie untersucht. Die Komplexe sind vom Typ X-RuC2B8H10 (X=Hexamethylbenzol oder Paracumol). Alle relevanten elektrochemischen und chemischen Parameter wurden abgeleitet; ein Reaktionsmechanismus wird vorgeschlagen.

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Received August 3, 1998. Accepted (revised) October 22, 1998

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Ghoneim, M., El-Hallag, I. Electrochemical Investigation of Some Ruthenium-Carborane Complexes at a Glassy Carbon Electrode. Monatshefte fuer Chemie 130, 525–535 (1999). https://doi.org/10.1007/PL00010231

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  • DOI: https://doi.org/10.1007/PL00010231

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