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Oxidation of Alcohols by Montmorillonite K-10 Supported Bis(trimethylsilyl)chromate

Oxidation von Alkoholen mit an Montmorillonit K-10 adsorbiertem Bis(trimethylsilyl)chromat

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Summary.

 Bis(trimethylsilyl)chromate generated from chromic anhydride and hexamethyldisiloxane in dichloromethane was applied onto a montmorillonite K-10 surface. This reagent proved to be suitable for oxidizing alcohols of various types to the corresponding carbonyl compounds..

Zusammenfassung.

 Bis(trimethylsilyl)chromat, dargestellt aus Chromsäureanhydrid und Hexamethyldisiloxan in Dichlormethan, wurde an Montmorillonit K10 adsorbiert. Mit diesem Reagens werden unterschiedliche Alkohole in sehr guten Ausbeuten zu den entsprechenden Carbonylverbindungen oxidiert..

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Authors and Affiliations

  1. Chemistry and Chemical Engineering Research Center of Iran, Tehran, Iran, IR

    Majid M. Heravi, Dariush Ajami & Kourosh Tabar-Heydar

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  1. Majid M. Heravi
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  2. Dariush Ajami
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  3. Kourosh Tabar-Heydar
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Additional information

Received March 16, 1998. Accepted (revised) April 27, 1998

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Heravi, M., Ajami, D. & Tabar-Heydar, K. Oxidation of Alcohols by Montmorillonite K-10 Supported Bis(trimethylsilyl)chromate. Monatshefte fuer Chemie 129, 1305–1308 (1998). https://doi.org/10.1007/PL00010142

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  • DOI: https://doi.org/10.1007/PL00010142

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