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On Heterometallic Ferrocenyl Compounds of Gold and Platinum

Über heterometallische Ferrocenylderivate des Golds und Platins

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Summary.

 The syntheses, properties, and chemical shifts of the heterometal gold(I) complexes FcNAuċP(C6H4Cl-4)3 (1), FcN′[AuċPPh3]2 (2), and Fc′[AuċPPh3]2 (3) are reported. The electrochemical behaviour of complexes 1 and 3 is compared with that of the related platinum derivatives (FcN)2Pt (4) and FcNPtClċPPh3 (5). Cyclovoltammetric measurements confirm reversible one-electron transfers..

Zusammenfassung.

 Die Synthesen, Eigenschaften und chemischen Verschiebungen von Heterometallorganika des einwertigen Golds mit den Formeln FcNAuċP(C6H4Cl-4)3 (1), FcN′[AuċPPh3]2 (2) und Fc′[AuċPPh3]2 (3) werden mitgeteilt. Cyclovoltammetrische Messungen an 1 bzw. 3 im Vergleich mit jenen an den Organoplatinderivaten (FcN)2Pt (4) bzw. FcNPtClċPPh3 (5) bestäigen reversible Einelektronenübergänge..

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Authors and Affiliations

  1.  Institute of Inorganic Chemistry of Martin Luther University Halle-Wittenberg, D-06217 Merseburg, Germany, DE

    Klaus Jacob & Frank Voigt

  2.  Dipartimento di Chimica dell’Università di Siena, I-53100 Siena, Italy, IT

    Piero Zanello & Marco Fontani

Authors
  1. Klaus Jacob
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  2. Piero Zanello
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  3. Frank Voigt
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  4. Marco Fontani
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Additional information

Received May 13, 1998. Accepted (revised) July 24, 1998

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Jacob, K., Zanello, P., Voigt, F. et al. On Heterometallic Ferrocenyl Compounds of Gold and Platinum. Monatshefte fuer Chemie 129, 1213–1223 (1998). https://doi.org/10.1007/PL00010133

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  • DOI: https://doi.org/10.1007/PL00010133

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