Abstract
A systematic study was carried out to investigate the reduction reaction mechanism of oxygen on pyrite surface using electrochemical techniques. The polarization curves showed two distinct regions, the Tafel region for superoxide formation and limiting current region for diffusion of dissolved oxygen to form hydrogen peroxide. These results were confirmed with a-c impedance measurements.
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Ahmed, S.M., 1978, “Electrochemical Studies of Sulfides, I. The Electrocatalytic Activity of Galena, Pyrite and Cobalt Sulfide for Oxygen Reduction in Relation to Xanthate Adsorption and Flotation,” International Journal of Mineral Processing, Vol. 5, pp. 163–174.
Biegler, T., Rand, D.A.J. and Woods, R., 1975, “Oxygen Reduction on Sulfide Minerals, Part I, Kinetics and Mechanism at Rotated Pyrite Electrodes,” Journal of Electroanalytical Chemistry, Vol. 60, pp. 151–162.
Biegler, T., 1976, “Oxygen Reduction on Sulfide Minerals, Part II, Relation Between Activity and Semiconducting Properties of Pyrite Electrodes,” Journal of Electroanalytical Chemistry, Vol. 70, pp. 265–275.
Biegler, T., Rand, D.A.J., and Woods, B.J., 1977, “Oxygen Reduction on Sulfide Minerals,” Trends in Electrochemistry, J.O.M. Bockris, et al., eds., Plenum Press, New York, pp. 291–302.
Chander, S. and Briceno, A., 1987, “Kinetics of Pyrite Oxidation,” Minerals & Metallurgical Processing Vol. 4, pp. 171–176
Hoare, J. P., 1968, The Electrochemistry of Oxygen, Interscience Publishers, New York, pp. 117–142.
Kowal, A. and Pomianowski, A., 1973, “Cyclic Voltammetry of Ethyl Xanthate on a Natural Copper Sulfide Electrode,” Electroanalytical Chemistry Interfacial Electrochemistry, Vol. 46, pp. 411–420.
Levich, V. G., 1962, Physicochemical Hydrodynamics, Prentice Hall, N. J., 1962, p. 325.
Macdonald, J. R., 1982, “The Applicability and Power of Complex Nonlinear Least Squares for the Analysis of Impedance and Admittance Data,” Journal of the Electrochemical Society, Vol. 131, pp. 77–95.
Majima, H. and Peters, E., 1969, “Electrochemistry of Sulfide Dissolution in Hydrometallugical Systems,” Proceedings, 8th Mineral Processing Congress, Leningrad, Institute Mekhanobr, Leningrad, Vol. 2, pp. 5–22.
Peters, E. and Majima, H., 1968, “Electrochemical Reactions of Pyrite in Acid Perchlorate Solutions,” Canadian Metallurgical Quarterly, Vol. 7, No. 3, pp. 111–117.
Reid, J.D. and David, A.P., 1987, “Impedance Behavior of a Sulfuric Acid-Cupric Sulfate/Copper Cathode Interface,” Journal of the Electrochemical Society, Vol. 134, No. 6, pp. 1389–1394.
Sato, M., 1960, “Oxidation of Sulfide Ore Bodies. II. Oxidation Mechanism of Sulfide Minerals at 25°C,” Economic Geology, Vol. 55, pp. 1202–1231.
Sawyer, D. T., 1977, “One-Electron Mechanism for the Electrochemical Reduction of Molecular Oxygen,” Inorganic Chemistry, Vol. 16, pp. 499–501.
Sluyters-Rehbach, M., and Sluyters, J. H., 1974, “Sine Wave Methods in the Study of Electrode Processes,” Electroanalytical Chemistry, A.J. Bard, ed., Vol. 4, Marcel Dekker, Inc., New York, pp. 1–128.
Tarasevich, M.R., Sadkowski, A., and Yeager E., 1983, “Oxygen Electrochemistry,” Comprehensive Treatise of Electrochemistry, B.E. Conway, et al., eds., Vol. 7, Plenum Press, New York, pp. 301–398.
Tolun, R., and Kitchener, J.A., 1964, “Electrochemical Study of the Galena-Xanthate-Oxygen Flotation System,” Transactions, IMM, Vol. 73, pp. 313–322.
Usul, A. H. and Tolun, R., 1974, “Electrochemical Study of the Pyrite-Oxygen-Xanthate System,” International Journal of Mineral Processing, Vol. 1, pp. 135–140.
Woods, R., 1976, “Electrochemistry of Sulfide Flotation,” Flotation, M. C. Fuerstenau, ed., Vol. 1, AIME, New York, pp. 298–333.
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M&MP paper 88-664. Discussion of this paper must be submitted, in duplicate, prior to Jan. 31, 1990.
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Doo, S.G., Sohn, H.J. Electrochemical reduction of oxygen on a pyrite surface. Mining, Metallurgy & Exploration 6, 201–205 (1989). https://doi.org/10.1007/BF03403466
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DOI: https://doi.org/10.1007/BF03403466