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Adsorption of gold from iodide solution by activated carbon

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Abstract

The adsorption of gold onto activated carbon in iodide solutions was studied. The adsorption rates were determined as a function of temperature, salt concentration and pH, as well as activated carbon concentration. A kinetic model was developed for the adsorption. The adsorption rate was believed to be controlled by a combined mechanism of film diffusion and pore diffusion with the film diffusion having the most significant effect. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

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References

  • Adams, M.D., and Fleming, C.A., 1989, “The mechanism of adsorption of aurocyanide onto activated carbon,” Metallurgical Transactions B, Vol. 22B, pp. 315–325.

    Article  Google Scholar 

  • Adams, M.D., McDougall, G.J. and Hancock, R.D., 1987, “Models for the adsorption of aurocyanide onto activated carbon. Part III: Comparison between the extraction of aurocyanide by activated carbon, polymeric adsorbents and 1-pentanol,” Hydrometallurgy, Vol. 19, pp. 95–115.

    Article  Google Scholar 

  • Avraamides, J., Hefter, G., and Budiselic, C. 1985, “The uptake of gold from chloride solutions by activated carbon,” Bulletin Proceedings of Aurtraliasian Institute of Mineral and Metallurgy, Vol. 290. No. 7, pp. 59–62.

    Google Scholar 

  • Cho, E.H., and Pitt, C.H., 1979, “The adsorption of silver cyanide on activated charcoal,” Metallurgical Transactions B Vol. 10B, pp. 159–164.

    Article  Google Scholar 

  • Cho, E.H., Dixon, S.N., and Pitt, C.H., 1979, “The kinetics of gold adsorption on activated charcoal,” Metallurgical Transactions B, Vol. 10B, pp. 185–189.

    Article  Google Scholar 

  • Crank, J., 1948, “A diffusion problem in which the amount of diffusing substance is finite. II. Diffusion with nonlinear adsorption,” Phil. Magazine, Vol. 39, pp. 140–49.

    MathSciNet  MATH  Google Scholar 

  • de Siegel, E.A., and Soto, A.M., 1984, “Microscopic observations on adsorption of metallic gold on activated carbon,” Transactions of Institute of Mineral and Metallurgy, Vol. 93, pp. C90–92.

    Google Scholar 

  • Dubinin, M.M., 1967, “Adsorption in micropores,” T. Colloid Interface Science, Vol. 23, pp. 487–99.

    Article  Google Scholar 

  • Fuerstenau, M.C., et al., 1987, “Rate of adsorption of gold cyanide on activated charcoal,” Minerals and Metallurgical Processing, Nov., pp. 177–181.

  • Hall, K.B., 1974, “Homestake uses carbon in pulp to recover gold from slime,” World Minerals, Vol. 27, No. 27, pp. 44.

    Google Scholar 

  • Han, K.N., 1984, “A simple and accurate method of determining the free setting velocity,” T. Korean Institute of Mineral Engineering Research, Vol. 21, 237–240.

    Google Scholar 

  • Hiskey, J.B., and Qi, P., 1993, “The nature of gold uptake from iodide solutions by carbon,” Hydrometallurgy — Fundamentals, Technology and Innovation, J.B. Hiskey and G.W. Warren eds., SME/AIME, Littleton, CO, pp. 437–457.

    Google Scholar 

  • Hiskey, J.B., Jiang, X.H., and Ramadorai, R., 1990, “Fundamental studies on the loading of gold on carbon in chloride solutions.” Gold’ 90, D.M. Hausen, D.N. Halbe, E.U. Petersen and W.J. Tafuri, eds., SME/AIME, Littleton, CO, pp. 369–376.

    Google Scholar 

  • Hughes, H.C., and Linge, H.G., 1989, “The kinetics of gold loading from gold(III) chloride solution onto fresh activated coconut carbon,” Hydrometallurgy, Vol. 22, No. 1 and 2, pp. 57–66.

    Article  Google Scholar 

  • Jeong, H.S., and Sohn, H.J., 1988, “Adsorption of silver thiourea on activated carbon,” Minerals and Metallurgical Processing, Feb., pp. 21–25.

  • Levenspiel, O., 1972, Chemical Reaction Engineering, 2nd ed., John Wiley & Sons, New York, NY. pp. 469–474.

    Google Scholar 

  • Levins, D.M., and Glastonbury, J.R., 1972, “Particle-liquid hydrodynamics and mass transfer In a stirred vessel. I, Particle-liquid motion,” Transactions Institute Chemical Engineering, Vol. 50, pp. 32–41, and pp. 132–146.

    Google Scholar 

  • McAdams, W.H., 1954, Heat Transmission, third edition, McGraw-Hill, New York, pp. 268.

    Google Scholar 

  • McDougall, G.J., and Fleming, C.A., 1987, “Extraction of precious metals on activated carbon,” Ion Exchange and Sorption Process in Hydrometallurgy, M. Street and D. Naden, eds., The Society of Chemical Industry, John Wiley & Sons, pp. 56–126.

  • McGrew, K.J., and Murphy, J.W., 1985, “Iodine leach for the dissolution of gold,” US Patent, No. 4,567,759. Dec. 10.

  • Pesic, B., and Storhok, C., 1992, “Adsorption of gold on activated carbon in bromide solutions.” Metallurgical Transactions B, Vol. 23B, pp. 557–566.

    Article  Google Scholar 

  • Qi, P.H., and Hiskey, J.B., 1991, “Dissolution kinetics of gold in iodide solutions.” Hydrometallurgy, Vol. 27, No. 1, pp. 47–62.

    Article  Google Scholar 

  • Rubcumintara, T., and Han, K.N., 1990, “The effect of concentration and temperature on diffusivity of metal compounds,” Metallurgical Transactions B, Vol. 21B, pp. 429–438.

    Article  Google Scholar 

  • Soto, A.M., and Machuco, R.A., 1989, “Adsorption of gold thiourea complex on activated carbon,” Journal of Chemical Technology and Biotechnology, Vol. 44 No. 3, pp. 219–23.

    Article  Google Scholar 

  • Vu, C., and Han, K.N., 1977, “Leaching behavior of cobalt in ammonia solutions,” Transactions Institute Mineral & Metallurgy, Sec. C, pp. C119–125.

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SME Preprint 93-77, SME Annual Meeting, Feb. 15–18, 1993, Reno, NV. M&MP paper 93-656.

Discussion of this peer-reviewed and approved paper is invited and must be submitted, in duplicate, prior to May 31, 1994.

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Meng, X., Han, K.N. Adsorption of gold from iodide solution by activated carbon. Mining, Metallurgy & Exploration 11, 31–36 (1994). https://doi.org/10.1007/BF03403037

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