Abstract
The kinetics of gold-bromide loading onto activated carbon was investigated in a batch stirred reactor. Based on a second-order equation, the amount of gold adsorbed by the carbon was correlated with time. From a 30°C solution containing 25 ppm Au and 0.8 g/L carbon, the rate constant for gold-bromide species onto activated carbon ranged from 0.27 × 10−3 to 1.2 × 10−3 (kg/t)−1min−1. The equilibrium saturation capacity (Qe) was 36 ± 3.0 kg/t from the same system. The rate of loading increased with increasing temperature and decreasing particle size, pH and solution gold concentration. The calculated activation energy (Ea) was 8.8 kcal/mole, significantly higher than those reported for physical adsorption. The equilibrium saturation capacity (Qe) increased with increasing concentration of gold in solution but was independent of other variables such as temperature, agitation speed, particle size and pH. These rate constants and equilibrium saturation capacity for the gold-bromide species are higher than those reported for the gold-cyanide systems.
Similar content being viewed by others
References
Adams, M.D., McDougall, G.J., and Hancock, R.D., 1987, “Model for adsorption of aurocyanide onto activated carbon, Part III,” Hydrometallurgy, 19, pp. 95–115.
Avraamides, J., Hefter, G., and Budeselic, C., 1985, “The uptake of gold from chloride solutions,” Proc. Aust. I.M.M., 290, pp. 59–62.
Cho, E.H., Dixon, S.N., and Pitt, C.H., 1979, “The kinetics of gold cyanide adsorption on activated charcoal,” Metall. Trans., 10B, p. 185.
Faulkner, W.D., Urbanic, J.E., and Ruckel, R.W., 1987, “Activated carbon for precious metals recovery,” Proc. 110th. Ann. Meeting SME, Denver, CO, February 23–27.
Hughes, H.C., and Linge, H.G., 1989, “The kinetics of gold loading from gold(III) chloride solution onto fresh activated carbon,” Hydrometallurgy, 22, p. 57.
McDougall, G.J., Hancock, R.D., Nicol, M.J., Wellington, O.L., and Copperwaite, R.G., 1980, “The Mechanism of the adsorption of gold cyanide on activated carbon,” J. S. African Inst. Min. Metall., Vol. 80, pp. 344–356.
Mensah-Biney, R.K., Hepworth, M.T., and Reid, K.J., 1993, “Loading characteristics of gold-bromo species onto activated carbon,” Minerals and Metallurgical Processing, pp. 13–19.
Mensah-Biney, R.K., 1991, “Recovery of Gold From Bromide Solutions Using Ion Exchange Resins and Activated Carbon,” Ph.D. Thesis, University of Minnesota, Minneapolis, MN.
Nicol, M.J., Fleming, C.A., and Cromberge, G, 1984, “The adsorption of gold cyanide onto activated carbon. III, Application of kinetic model to multistage absorption circuits,” J. S. African. Inst. Min. Metall, 84(3), p. 70.
Peel, R.G., Benedek, A., and Crowe, C.M., 1981, “A branched pore kinetic model for activated carbon adsorption,” A. I. Ch. E. J., 27, 26.
Van Deventer, J.S.J., 1986, “Kinetic model for the reversible adsorption of gold cyanide on activated carbon,” Chem. Eng. Commun, Vol. 44, pp. 257–274.
Author information
Authors and Affiliations
Additional information
SME preprint 96-73, SME Annual Meeting March 11–14, 1996, Phoenix, AZ. M&MP paper 96–609. Discussion of this peer-reviewed paper is invited and must be submitted, in duplicate, prior to May 31, 1997.
Rights and permissions
About this article
Cite this article
Mensah-Biney, R., Reid, K.J. & Hepworth, M.T. Kinetics of gold-bromide loading onto activated carbon. Mining, Metallurgy & Exploration 14, 7–13 (1997). https://doi.org/10.1007/BF03402745
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03402745