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Adsorption behavior of gold in ammoniacal solutions on activated carbon

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Abstract

The adsorption behavior of gold in ammoniacal solutions on activated carbon was studied. The gold adsorption capacity of the activated carbon and the recovery efficiency were examined. The parameters affecting the adsorption of gold on the activated carbon included temperature, agitation speed, the concentration of cation and anion and the concentration of ammonia.

It was found that the maximum gold adsorption was about 10 kg/t of carbon. The recovery of gold by the adsorption from ammoniacal solutions was found to be dependent upon the initial gold concentration. Under experimental conditions, a gold recovery of 98% was obtained after 120 hrs of adsorption.

It was also found that the initial adsorption rate was relatively fast, when compared to the entire adsorption period. The apparent activation energy for the adsorption was determined to be 15.8 kJ/mol. It was believed that the kinetics of gold adsorption on the activated carbon was controlled by pore diffusion.

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References

  • Adams, M.D., and Fleming, C.A., 1989, “The Mechanism of adsorption of aurocyanide onto activated carbon,” Met. Trans. B., Vol. 22B, pp. 315–325.

    Article  Google Scholar 

  • Adams, M.D., McDougall, G.J., and Hancock, R.D., 1987, “Models for the adsorption of aurocyanide onto activated carbon, Part III: Comparison between the extraction of aurocyanide by activated carbon, polymeric adsorbents and 1-pentanol,” Hydrometallurgy, Vol. 19, pp. 95–115.

    Article  Google Scholar 

  • Avraamides, J., Hefter, G., and Budiselic, C., 1985, “The uptake of gold from chloride solutions by activated carbon,” Bulletin Proceedings of Australiasian Institute of Mineral and Metallurgy, Vol. 290, No. 7, pp. 59–62.

    Google Scholar 

  • Cho, E.H., and Pitt, C.H., 1979, “The adsorption of silver cyanide on activated charcoal,” Met. Trans. B., Vol. 10B, pp. 159–164.

    Article  Google Scholar 

  • Cho, E.H., Dixon, S.N., and Pitt, C.H., 1979, “The kinetics of gold adsorption on activated charcoal,” Met. Trans. B., Vol. 10B, pp. 185–189.

    Article  Google Scholar 

  • Cook, R., Crathorne, E.A., Monhemiou, A.J., and Perry, D.L, 1989, “An XPS study of the adsorption of gold (I) cyanide by carbon,” Hydrometallurgy, No. 22, pp. 171–182.

    Article  Google Scholar 

  • de Siegel, E.A., and Soto, A.M., 1984, “Microscopic observations on adsorption of metallic gold on activated carbon,” Transactions of Institute of Mineral and Metallurgy, Vol. 93, pp. C90–92.

    Google Scholar 

  • Dubinin, M.M., 1967, “Adsorption in micropores,” J. Colloid Interface Sci., Vol. 23, pp. 487–499.

    Article  Google Scholar 

  • Fleming, C.A., 1987, “The recovery of gold from thiourea leach liquors with activated carbon,” Proceedings of the International Symposium on Gold Metallurgy, Metallurgical Society of the Canadian Institute of Mining and Metallurgy, pp. 259–276.

  • Fuerstenau, M.C., Nebo, CO., Kelso, J. R., and R. Zaragoza, M., 1987, “Rate of adsorption of gold cyanide on activated charcoal,” Minerals and Metallurgical Processing, Nov., pp. 177–181.

  • Hall, K.B., 1974, “Homestake uses carbon in pulp to recover gold from slime,” World Min., Vol. 27, No. 27, p. 44.

    Google Scholar 

  • Han, K.N., and Meng, X., 1992, Ammonia Extraction of Gold and Silver from Ores and Other Materials,” US Patent No. 5114687.

  • Han, K.N., and Meng, X., 1994, Ammonia Extraction of Gold and Silver from Ores and Other Materials,” US Patent No. 5308381.

  • Hiskey, J.B., Jiang, X.H., and Ramadorai, R., 1990, “Fundamental studies on the loading of gold on carbon in chloride solutions,” Gold’90., D.M. Hausen et al., eds., SME, Littleton, CO, pp. 369–376.

    Google Scholar 

  • Hiskey, J.B., and Qi, P., 1993, “The nature of gold uptake from iodide solutions by carbon,” HydrometallurgyFundamentals, Technology and Innovation, J.B. Hiskey and G.W. Warren, eds., SME, Littleton, CO, Printed by Cushing-Malloy, Inc., Ann Arbor, MI, pp. 437–457.

    Google Scholar 

  • Hughes, H.C., and Linge, H.G., 1989, “The kinetics of gold loading from gold (III) chloride solution onto fresh activated coconut carbon,” Hydrometallurgy, Vol. 22, Nos. 1 and 2, pp. 57–66.

    Article  Google Scholar 

  • Jeong, H.S., and Sohn, H.J., 1988, “Adsorption of silver thiourea on activated carbon,” Minerals and Metallurgical Processing, February, pp. 21–25.

  • McDougall, G.J., Hancock, R.D., Nicol, M.J., Wellington, J.O., and Copperthwaite, R.G., 1980, “The mechanism of the adsorption of the gold cyanide on the activated carbon,” J. of the south African Inst. of Min. and Metall, pp. 344–356.

  • McDougall, G.J., and Fleming, C.A., 1987, “Extraction of precious metals on activated carbon,” Ion Exchange and Sorption Process in Hydrometallurgy, M. Streat and D. Naden, eds., The Society of Chem. Industry, John Wiley & Sons, 56–126.

    Google Scholar 

  • Meng, X., and Han, K.N., 1994, “Adsorption of gold in iodide solution by activated carbon,” Minerals and Metallurgical Processing., Vol. 11, No. 1, Feb., pp. 31–36.

    Google Scholar 

  • Meng, X., and Han, K.N., 1993, “The dissolution behavior of gold in ammoniacal solutions,” HydrometallurgyFundamentals, Technology and Innovation., J.B. Hiskey and G.W. Warren, eds., SME, Littleton, CO, Printed by Cushing-Malloy, Inc., Ann Arbor, MI, pp. 205–221.

    Google Scholar 

  • Pesic, B., and Storhok, C., 1992, “Adsorption of gold on activated carbon in bromide solutions,” Metallurgical Transactions B., Vol. 23B, pp. 557–566.

    Article  Google Scholar 

  • Rubcumintara, T., and Han, K.N., 1990, “The effect of concentration and temperature on diffusivity of metal compounds,” Metallurgical Transactions B, Vol. 21B, pp. 429–438.

    Article  Google Scholar 

  • Soto, A.M., and Machuco, R.A., 1989, “Adsorption of gold thiourea complex on activated carbon,” J. Chem. Technol. Biotechnol., Vol. 44 (3), pp. 219–223.

    Article  Google Scholar 

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SME preprint 95-6, SME Annual Meeting, March 6–9, 1995, Denver, CO. M&MP paper 96–629. Discussion of this peer-reviewed and approved paper is invited and must be submitted, in duplicate, prior to Feb. 28, 1997.

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Xu, Q., Meng, X. & Han, K.N. Adsorption behavior of gold in ammoniacal solutions on activated carbon. Mining, Metallurgy & Exploration 13, 141–146 (1996). https://doi.org/10.1007/BF03402735

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  • DOI: https://doi.org/10.1007/BF03402735

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