Abstract
Two aromatic-type chelating agents, 1, 10 phenanthroline (phen) and 8-quinolinol (quin), were tested as specific depressants for magnetite in the cationic silica flotation of magnetic taconite concentrates. Micro and batch flotation tests, along with zeta potential and adsorption measurements, were used. In the presence of a cationic collector, dodecylammonium chloride (DAC), the Fe/phen surface chelate electrostatically repelled DAC, and the magnetite was depressed. The negatively charged Fe(quin)2(OH)2− on the magnetite surface attracted the cationic collector and made magnetite floatable.
Similar content being viewed by others
References
Agarwala, V.S., 1990, “Corrosion inhibition by phenanthrolines,” Corrosion, Vol. 46, No. 5, pp. 376–379.
Albert, A., 1953, “Quantitative studies of the avidity of naturally occurring substances for trace metals,” Biochem, J., Vol. 54, pp. 646–654.
Fresco, J., and Freiser, H., 1961, Talanta, Vol. 8, 693 p.
Iwasaki, I., 1990, “Bridging theory and practice in iron ore flotation,” Advances in Coal and Mineral Processing Using Flotation, Chander, S. and Klimpel, R., eds, Chap. 20, pp. 177–190.
Kim, Y.S., 1959, MS Thesis, Univ. of Minnesota.
Krishnan, S.V., and Iwasaki, I., 1985, “Floc formation in quartz-Mg(OH)2 system,” Colloids & Surface, Vol. 15, pp. 89–100.
Leidheiser, H., Jr., Konno, H., and Vertes, A., 1983, “Inhibition of the oxygen reduction reaction using 8-hydroxyquinoline”, Preprint No. 7, Conf. Corrosion Inhibition, Dallas, TX, May.
Marabini, A.M., Babaro, M., and Criachi, M., 1983, “Calculation method for selection of complexing collectors,” Trans. IMM, Vol. 92, pp. 20–26.
Perrin, D.D., 1964, “Organic complexing reagents: Structure, behavior, and application to inorganic analysis,” Intersci. Pub., New York.
Sastri, V.S., and Packwood, R.H., 1987, “Surface analysis in corrosion inhibition mechanisms,” Werkstoffe und korrosion, Vol. 38, pp. 77–82.
Schilt, A.A., 1969, Analytical Applications of 1, 10 Phenanthroline and Related Compounds, Pergamon Press, New York.
Snell, F.D., and Snell, C.T., 1954, Colorimetric Methods of Analysis, van Nostrand Co., New York, Vol. 4, 31 p.
Weisstuch, A., Carter, D.A., and Nathan, C.C., 1971, “Chelation compounds as cooling water corrosion inhibitors,” Materials Protection & Performance, Vol. 10, No. 4, April, pp. 11–15.
Author information
Authors and Affiliations
Additional information
SME preprint 95-28, SME Annual Meeting, March 6–9, 1995, Denver, CO. M&MP paper 95–624. Discussion of this peer-reviewed and approved paper is invited and must be submitted, in duplicate, prior to Aug. 31, 1996.
Rights and permissions
About this article
Cite this article
Dho, H., Iwasaki, I. Chelating modifiers in the cationic silica flotation of magnetic taconite concentrates. Mining, Metallurgy & Exploration 13, 65–68 (1996). https://doi.org/10.1007/BF03402721
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03402721