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Control of calcium ion via chemical precipitation — ultrasonic treatment in selective flocculation

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Abstract

Selective flocculation of iron ores is extremely sensitive to the type and amount of soluble salts in pulp solutions. Chemical precipitation of alkaline earth ions combined with ultrasonic treatment deactivates their adverse effects without using any environmentally ill-defined reagents. The manner in which ultrasonic treatment affects starch adsorption on hematite, dissolution of quartz, and the selective flocculation process was investigated. Selective flocculation tests were conducted in the presence of up to 400 ppm calcium ion on a quartz-hematite mixture by precipitation as calcium carbonate, and the role that silicate ion generated by ultrasonic treatment plays in achieving the selectivity of separation is discussed.

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References

  • Crawford, A.E., 1955, Ultrasonic Engineering, Butterworth, London, 344 pp.

    Google Scholar 

  • Gaudin, A.M., 1957, Flotation, McGraw-Hill, New York, 573 pp.

  • Greenberg, S.A., 1961, “Reaction between silica and calcium hydroxide solutions. I. Kinetics in the temperature 30 to 85°,” Journal of Physical Chemistry, Vol. 65, pp. 12–16.

    Article  Google Scholar 

  • Heerema, R.H., and Iwasaki, I., 1980, “Chemical precipitation of alkaline earth cations and its effect on flotation and flocculation of quartz,” Trans. SME-AIME, Vol. 268, pp. 1510–1516.

    Google Scholar 

  • Heerema, R.H., Lipp, R.J., and Iwasaki, I., 1982, “Complexation of calcium ion in selective flocculation of iron ores,” Trans. SME-AIME, Vol. 272, pp. 1879–1884.

    Google Scholar 

  • Iwasaki, I., 1979, “Selective flocculation of iron ores — principles,” Beneficiation of Mineral Fines: Problems and Research Needs, Report of NSF Workshop, New York, pp. 257–262.

    Google Scholar 

  • Iwasaki, I., Smith, K.A., Lipp, R.J., and Sato, H., 1980, “Effect of calcium and magnesium ions on selective desliming and cationic flotation of quartz from iron ores,” Fine Particle Processing, AIME, New York, pp. 1057–1082.

    Google Scholar 

  • Krishnan, S.V., and Iwasaki, I., 1982, “Sodium silicate as a dispersant in the selective flocculation of iron ores,” Trans. SME-AIME, Vol. 272, pp. 1984–1988.

    Google Scholar 

  • Krishnan, S.V., and Iwasaki, I., 1984, “Pulp dispersion in selective desliming of iron ores,” International Journal of Mineral Processing, Vol. 12, pp. 1–13.

    Article  Google Scholar 

  • Krishnan, S.V., and Iwasaki, I., 1986, “Heterocoagulation versus surface precipitation in quartz-Mg(OH)2 system,” Environmental Science Technology, Vol. 20, pp. 1224–1229.

    Article  Google Scholar 

  • Learmont, M.E., Lipp, R.J., and Iwasaki, I., 1984, “Complexation of calcium ion with NTA in the selective flocculation of iron ores,” Trans. SME-AIME, Vol. 276, pp. 1817–1818.

    Google Scholar 

  • Marshall, J.K., and Kitchener, J.A., 1966, “The deposition of colloidal particles on smooth solids,” Journal of Colloid Interface Science, Vol. 22, pp. 342–351.

    Article  Google Scholar 

  • Moscow Institute for Steel and Alloys, 1973, The Use of Ultrasonics in Extractive Metallurgy, Technicopy, England, 215 pp.

  • Usui, S., 1972, “Heterocoagulation,” Progress in Surface and Membrane Science, Vol. 5, J.F. Danielli et al., eds., Academic Press, New York, pp. 223–266.

    Google Scholar 

  • Walker, R., 1979, “The role of ultrasound in the electrowinning and electrofining of metals,” Hydrometallurgy, Vol. 4, pp. 209–215.

    Article  Google Scholar 

  • Yeager, E., and Hovorka, F., 1953, “Ultrasonic waves and electrochemistry. I. A survey of the electrochemical applications of ultrasonic waves,” Journal, Acoustical Society of America, Vol. 25, pp. 443–455.

    Article  Google Scholar 

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SME preprint 87-34, SME-AIME Annual Meeting, Denver, CO, February 1987. MMP paper 87–609. Discussion of this paper must be submitted, in duplicate, prior to Jan. 31, 1988.

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Manukonda, V.R., Iwasaki, I. Control of calcium ion via chemical precipitation — ultrasonic treatment in selective flocculation. Mining, Metallurgy & Exploration 4, 217–222 (1987). https://doi.org/10.1007/BF03402696

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  • DOI: https://doi.org/10.1007/BF03402696

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