Skip to main content
Log in

Study of Spinel-Containing High Alumina Castable with Different Cements

  • Refractories
  • Published:
Interceram - International Ceramic Review

Abstract

High alumina castable with presynthesized and in situ spinel formation is studied using two different lime-containing high alumina cements. Vibratable castable compositions were studied by conventional processing, using a distribution coefficient of 0.29 and heat treatments at 110, 900, and 1500°C. Slightly lower density and strength values were found for in situ spinel-forming compositions and spinel formation was observed to start around 900°C and near completion at 1500°C in the matrix of the castables.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Maschio, R.D., Fabbri, B., Fiori, C.: Industrial applications of refractories containing magnesium aluminate spinel. Indust. Ceram. 8 (1988) [2] 121–126

    Google Scholar 

  2. Sarkar, R.: Refractory applications of magnesium aluminate spinel. Interceram — Refractories Manual (2010) 11–14

  3. Racher, P.R., McConnell, R.W., Buhr, A.: Magnesium aluminate spinel raw materials for high performance refractories for steel ladles. Proc. 43rd Conf. of Metallurgy, Hamilton, Canada (2004)

  4. Naigai, B., Matsumoto, O., Isobe, T., Nishiumi, Y.: Wear mechanism of castable for steel ladle by slag. Taik. Overs. 12 (1992) [1] 15–20

    Google Scholar 

  5. Yamamura, T., Kubota, Y., Kaneshige, T., Nanba, M.: Effect of spinel clinker composition on properties of alumina-spinel castable. Taik. Overs. 13 (1994) 39–45

    Google Scholar 

  6. Ko, Y.C.: Properties and production of Al2O3-Spinel and Al2O3-MgO castables for steel ladles. Ceram. News 6 (2002) [1] 51–56

    Google Scholar 

  7. Díaz, L.A., Torrecillas, R., de Azab, A.H., Pena, P.: Effect of spinel content on slag attack resistance of high alumina refractory castables. J. Europ. Ceram. Soc. 27 (2007) 4623–4631

    Article  CAS  Google Scholar 

  8. Sumimura, S., Yamamura, T., Cubata, Y., Kanashige, T.: Study on slag penetration of alumina-spinel castable. Proc. UNITECR 1993, Sao Paulo (Brazil), 97–101

  9. Nakashima, M., Isobe, T., Itose, S., Touno, A., Shimizu, I.: Improving the corrosion resistance of alumina-spinel castable by spinel additions. J. Techn. Assoc. Refract. Jpn., 21 (2001) [3] 155–161

    Google Scholar 

  10. Ko, Y.C.: Influence of the characteristics of spinels on the slag resistance of Al2O3-MgO and Al2O3-spinel castables. J. Am. Ceram. Soc., 83 (2000) [9] 2333–2335

    Article  CAS  Google Scholar 

  11. Shima, K., Imaiida, Y., Katani, T.: Application of alumina-spinel castable to teeming ladle for stainless steel. Taik. Overs. 15 (1995) [3] 24–28

    Google Scholar 

  12. Brandao, P., Goncalves, G.E., Duarte, A.K.: Mechanisms of hydration/carbonation of basic refractories. Refract. Appl. 3 (1998) [2] 6–8

    Google Scholar 

  13. Brandao, P., Goncalves, G.E., Duarte, A.K.: Mechanisms of hydration/carbonation of basic refractories. Part 2: Investigation of the kinetics of formation of brucite in fired basic bricks. Refract. Appl. 3 (1998) [2] 9–11

    Google Scholar 

  14. Kaneyasu, A., Yamamoto, S., Yoshida, A.: Magnesia raw materials with improved hydration resistance. Taik. Overs. 17 (1997) [2] 21–26

    Google Scholar 

  15. Kaneyasu, A., Arita, Y., Yoshida, A., Watanabe, T.: Hydration resistance of MgO aggregate with added CaO. Taik. Overs. 19 (1999) [1] 30–34

    Google Scholar 

  16. Kaneyasu, A., Yamamoto, S., Watanabe, T.: MgO raw material with improved hydration resistance. Taik. Overs. 16 (1996) [2] 26–30

    Google Scholar 

  17. Kitamura, A., Onizuka, K., Tanaka, K.: Hydration characteristics of magnesia. Taik. Overs. 16 (1996) [3] 3–11

    Google Scholar 

  18. Lee, W.E., Vieira, W., Zhang, S., Ghanbari Ahari, K., Sarpoolaky, H., Parr, C.: Castable refractory concretes. Int. Mater. Rev. 46 (2001) 145–167.

    Article  CAS  Google Scholar 

  19. Chen, S.K., Cheng, M.Y., Lin, S.C., Ko, Y.C.: Thermal characteristics of Al2O3-MgO and Al2O3-spinel castables for steel ladles. Ceram. Int. 28 (2002) 811–817

    Article  CAS  Google Scholar 

  20. Buhr, A.: High alumina refractory castables for steel applications. Stahl und Eisen 116 (1996) [9] 59–66

    CAS  Google Scholar 

  21. Kriechbaum, G.W. et al.: The influence of SiO2 and spinel on the hot properties of high alumina low cement castables. Proc. 37th Inter. Colloquium Refract. 1994, Aachen (Germany), 150–159

  22. Molin, A., Molin, J., Podworny, J.: Corrosion mechanism of spinel forming and spinel containing refractory castables in lab and plant conditions. Proc. UNITECR 2005, Orlando (USA), 57–62

  23. Nakagawa, Z., Enomoto, N., Yi, I.S., Asano, K.: Effect of corundum/periclase sizes on expansion behavior during synthesis of spinel. Proc. UNITECR 1995, Kyoto (Japan), 1312–1319

  24. Rigaud, M., Palco, S., Wang, N.: Spinel formation in the MgO-Al2O3 system relevant to basic oxides. Proc. UNITECR 1995, Kyoto(Japan), 387–394

  25. Lee, W.E., Vieira, W., Zhang, S., Ahari, K.G., Sarpoolaky, H., Parr, C.: Castable refractory concretes. Int. Mat. Rev. 46 (2001) [3] 145–167

    Article  CAS  Google Scholar 

  26. Braulio, M.A.L., Bittencourt, L.R.M., Poirier, J., Pandolfelli, V.C.: Microsilica effects on cement bonded alumina-magnesia refractory castables. J. Techn. Assoc. Refract. Japan 28 (2008) [3] 180–184

    CAS  Google Scholar 

  27. Nagai, B., Matsumoto, O., Isobe, T.: Development of high-alumina castable for steel ladles. Findings on spinel formation in alumina-magnesia castable. Taik. Overs. 10 (1990) [1] 23–28

    Google Scholar 

  28. Nandi, P., Grag, A., Chattoraj, B.D., Mukhopahyay, M.S.: Effect of silica and temperature on spinel-based high-alumina castables. Am. Ceram. Soc. Bul. 31 (2000) 65–69

    Google Scholar 

  29. Fuhrer, M., Hey, A., Lee, W.E.: Microstructural evolution in self-forming spinel/calcium aluminate castable refractories. J. Eur. Ceram. Soc. 18 (1998) 813–820

    Article  CAS  Google Scholar 

  30. Nanba, M., Kaneshige, T., Hamazaki, Y., Nishio, H., Ebisawa, I.: Thermal characteristics of castables for teeming ladle. Taik. Overs. 16 (1996) [3] 17–21

    Google Scholar 

  31. Dinger, D.R., Funk, J.E.: Particle packing. III — Discrete versus continuous particle sizes. Interceram 41 (1992) [5] 332–34

    Google Scholar 

  32. Fang H.S., Cha C.H., Yong S.Y.: Development of self flow castable. Proc. UNITECR 1995, Kyoto (Japan), 264–71

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to R. Sarkar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sarkar, R., Sharma, A. Study of Spinel-Containing High Alumina Castable with Different Cements. Interceram. - Int. Ceram. Rev. 63, 368–371 (2014). https://doi.org/10.1007/BF03401086

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03401086

Keywords

Navigation