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Scaling of Lead in Air

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Abstract

Solid lead obeys a single parabolic weight increase vs. time law. In contrast, liquid lead undergoes three successive parabolic weight increases vs. time laws, the first of which has a low constant relative to the latter two. The conversion times for the change from one parabola to the next decrease with increasing temperature.

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References

  1. C. A. Phalnikar and W. M. Baldwin, Jr.: Scaling of Zirconium. Proc. A.S.T.M. (1951) 51, pp. 1038–1060.

    Google Scholar 

  2. P. H. Morton and W. M. Baldwin, Jr.: Scaling of Titanium. Trans. A.S.M. (1952) 44, pp. 1004–1029.

    Google Scholar 

  3. W. Gruhl: Uber die Oxydation ruhender Bleischmelzen. Ztsch. Metallkunde (1949) 40, pp. 225–240.

    Google Scholar 

  4. L. Horn: Uber die Verzunderung von Nickel mit verschiedenen Zusatzen. Ztsch. Metallkunde (1944) 36, pp. 142–145.

    Google Scholar 

  5. D. Rosenthal: Discussion. Trans. AIME (1941) 143, pp. 269–270.

    Google Scholar 

  6. E. A. Gulbransen and J. W. Hickman: An Electron Diffraction Study of Oxide Films Formed on Iron, Cobalt, Nickel, Chromium, and Copper at High Temperatures. Trans. AIME (1947) 171, pp. 306–331; Metals Technology (October 1946).

    Google Scholar 

  7. B. Lustman: The Rate of Film Formation on Metals. Trans. Electrochemical Soc. (1942) 81, pp. 359–375.

    Article  Google Scholar 

  8. L. L. Bircumshaw and G. D. Preston: Studies on the Oxidation of Metals. Part V, The Oxidation of Molten Lead. Philosophical Magazine (1938) 25, p. 769.

    Google Scholar 

  9. W. Stahl: Uber Dissoziationsspannungen rsp. Sauerstoffdrucke einger Oxyde in den Rost und Schmelzhitzen der Flammofen. Metallurgie (1907) 4, pp. 682–690.

    Google Scholar 

  10. M. H. L. Chatelier: Sur la dissociation due minium. Bull. Soc. Chimie (1897) 17, (3) p. 791.

    Google Scholar 

  11. W. Reinders and L. Hamburger: Die höheren Oxyde des Bleis und ihre Dissoziation. Ztsch. anorg. allgem. Chem. (1914) 89, p. 71.

    Article  Google Scholar 

  12. E. Moles and A. P. Vitoria: Uber das System Pb02-Pb3O4-PbO. Chem. Zentralblatt (1930) 1, 28. Original publication: Anoles Soc. Espanola Fiscia Quim (1929) 27, pp. 520–528.

    Google Scholar 

  13. K. W. Grosheim-Krisko, W. Hofmann, and H. Hanemann: Uber die Löslichkeit von Sauerstoff in Blei. Ztsch Metallkunde (1944) 36, pp. 91–93.

    Google Scholar 

  14. G. Tammann: Ztsch. anorg. allgem. Chem. (1920) 111, pp. 78–89.

    Article  Google Scholar 

  15. N. B. Pilling and R. E. Bedworth: The Oxidation of Metals at High Temperatures. Journal Inst. Metals (1923) 29, pp. 529–581.

    Google Scholar 

  16. A. Krupkowski and S. Balicki: Das Problem der Oxydations-geschwindigkeit flussiger Metalle Zink, Blei, Silber, Kupfer. Chem. Zentralblatt (1937) 2, p. 2594. Original publication: Hutnik (1937) 9, pp. 138–152.

    Google Scholar 

  17. H. M. McCullough, M. G. Fontana, and F. H. Beck: Formation of Oxides on Some Stainless Steels at High Temperatures. Trans. A.S.M. (1951) 43, pp. 404–421.

    Google Scholar 

  18. E. Cohen and N. Addink: Die Metastabilität der Elemente und Verbindungen als Folge von Enantiotropie oder Monotropie XVII. Das Bleioxydproblem. Ztsch. Physik Chemie (1934) 168, pp. 188–201.

    Google Scholar 

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Discussion on this paper, TP 3313DE, may be sent, 2 copies, to AIME. Manuscript, Nov. 23, 1951. Philadelphia Meeting, October 1952, and Los Angeles Meeting, February 1953.

This paper is based on a thesis by E. Weber submitted in partial fulfillment of the requirements for the degree of Master of Science in Physical Metallurgy to the Dept. of Metallurgical Engineering, Case Institute of Technology.

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Weber, E., Baldwin, W.M. Scaling of Lead in Air. JOM 4, 854–859 (1952). https://doi.org/10.1007/BF03398151

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  • DOI: https://doi.org/10.1007/BF03398151

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