Skip to main content
Log in

Contribution to the Meta I-Carbon-Boron Systems

  • Transaction
  • Published:
JOM Aims and scope Submit manuscript

Abstract

Metal-carbon-boron powder mixtures were hot pressed and the resulting specimens were studied by X-ray diffraction. It was found that regardless of the starting combination of the metal, carbon, or boron powders, a metal boride phase was always the major component in these samples. In the absence of carbon the boride phase formed on hot pressing depended only on the amount of boron present. Two new phases of the system Ti-B were found. They are TUB and Ti2B5. The existence of a controversial face-centered cubic phase of formula TiB was confirmed. Electrical resistivities were measured for various boride phases. It was found that the diborides are generally better conductors than the monoborides of the same metal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. W. Glaser: Powder Metallurgy Bull. (1951) 6, 1, pp. 51–54.

    Google Scholar 

  2. R. Steinitz: Powder Metallurgy Bull. (1951) 6, 1, pp. 54–56.

    Google Scholar 

  3. J. A. Nelson, T. A. Willmore, and R. C. Womeldorph: Refractory Bodies Composed of Boron and Titanium Carbides Bonded with Metals. Presented at the Ninety-Ninth Meeting of the Electrochemical Society, Washington, D. C. April 8–12, 1951.

    Google Scholar 

  4. E. R. Honak: Ueber Hochschmelzende Boride der Uebergangsmetalle. Thesis, Techn. Hochschule Graz. 1951.

    Google Scholar 

  5. L. Andrieux: Annales de Chimie (1929) 12, p. 423.

    Google Scholar 

  6. J. T. Norton, H. Blumenthal, and S. J. Sindeband: Structure of Diborides of Titanium, Zirconium, Columbium, Tantalum and Vanadium. Trans. AIME (1949) 185, pp. 749–751; Journal of Metals (October 1949).

    Google Scholar 

  7. H. M. Greenhouse, O. E. Accountius, and H. H. Sisler: Journal A.C.S. (1951) 73, p. 5086.

    Article  Google Scholar 

  8. P. Ehrlich: Angew. Chem. (1947) 59, p. 163; Ztsch. anorg. allgem. Chem. (1949) No. 1, p. 259.

    Google Scholar 

  9. L. H. Andersson and R. Kiessling: Binary Systems of Boron with Chromium, Columbium, Nickel and Thorium, etc. Acta Chem. Scand. (1950) 4, p. 160.

    Article  Google Scholar 

  10. B. Post and F. W. Glaser: Crystal Structure of ZrB12. To be published in Trans. AIME, Journal of Metals.

  11. H. Blumenthal: To be published in Journal A.C.S.

  12. R. Kiessling: The Binary System Zirconium-Boron. Acta Chem. Scand. (1949) 3.

    Google Scholar 

  13. R. Kiessling: Borides of Tantalum. Acta Chem. Scand. (1949) 3, pp. 605–615.

    Google Scholar 

  14. L. Brewer, D. L. Sawyer, D. H. Templeton, and C. H. Dauben: Journal Amer. Ceramic Soc. (1951) 34, No. 6.

  15. R. Kiessling: Crystal Structures of Tungsten and Molybdenum Borides. Acta. Chem. Scand. (1947) 1, pp. 893–916.

    Google Scholar 

  16. Metals Handbook. (1951) A.S.M. Cleveland.

  17. C. Agte and K. Moers: Ztsch. anorg. allgem. Chem. (1931) 198.

  18. R. Steinitz: The System Mo-B. Journal of Metals (February 1952) p. 148.

    Google Scholar 

  19. B. Post and F. W. Glaser: Unpublished.

Download references

Author information

Authors and Affiliations

Authors

Additional information

Discussion on this paper, TP 3281 E, may be sent, 2 copies, to AIME by June 1, 1952. Manuscript, Aug. 1, 1951; revised, Jan. 22, 1952. New York Meeting, February 1952.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Glaser, F.W. Contribution to the Meta I-Carbon-Boron Systems. JOM 4, 391–396 (1952). https://doi.org/10.1007/BF03397703

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03397703

Navigation