Abstract
This’paper presents equilibrium data on the reaction of water vapor with vanadium dissolved in liquid iron at 1600°C. The thermodynamic behavior of vanadium and oxygen when present together in the melt is discussed. A deoxidation diagram is presented which shows the concentrations and activities of vanadium and oxygen in equilibrium with V2O3 or FeV2O4.
Similar content being viewed by others
References
M. G. Fontana and J. Chipman: Trans. ASM (1936) 24, p. 313.
J. Chipman and K. L. Fetters: Trans. ASM (1941) 29, p. 953.
M. N. Dastur and J. Chipman: Trans. AIME (1949) 185, p. 441; Journal of Metals (Aug. 1949) TP 2661C.
F. Körber and W. Oelsen: Mitt. Kaiser-Wilhelm-Inst. für Eisenfor. (1933) 15, p. 271.
D. C. Hilty and W. Crafts: Trans. AIME (1950) 188, p. 425; Journal of Metals (Feb. 1950) TP 2806E.
H. C. Vacher and E. H. Hamilton: Trans. AIME (1931) 95, p. 124.
S. Marshall and J. Chipman: Trans. in ASM (1942) 30, p. 695.
H. Wentrup and G. Hieber: Archiv für das Eisenhüttenwesen (1939) 13, p. 15.
D. C. Hilty and W. Crafts: Trans. AIME (1950) 188, p. 414; Journal of Metals (Feb. 1950) TP 2805C.
G. Derge: Trans. AIME (1946) 167, p. 93; Metals Technology (Aug. 1946) TP 2004C.
H. M. Chen and J. Chipman: Trans. ASM (1947) 38, p. 70.
M. N. Dastur and N. A. Gokcen: Trans. AIME (1949) 185, p. 665; Journal of Metals (Oct. 1949) TP 2693C.
C. H. Mathewson, E. Spire and C. H. Samans: Trans. A.S.S.T. (1932) 20, p. 357.
H. Siemonsen and H. Ulich: Ztsch. Electrochemie (1940) 46, p. 141.
K. K. Kelley: U. S. Bureau Mines Bulletin No. 434.
F. M. Jaeger and W. A. Veenstra: Recueil des Travaux Chimiques (1934) 53, p. 677.
O. A. Cook: Journal Amer. Chem. Soc. (1947) 69, p. 331.
Basic Open Health Steelmaking. AIME 1st Ed. p. 480; 2nd Ed. chapter 16.
Author information
Authors and Affiliations
Additional information
Discussion of this paper, TP 3006C, may be sent (2 copies) to AIME by April 1, 1951. Manuscript, Oct. 16, 1950. St. Louis Meeting, February 1951.
Rights and permissions
About this article
Cite this article
Chipman, J., Dastur, M.N. Vanadium-Oxygen Equilibrium in Liquid Iron. JOM 3, 111–115 (1951). https://doi.org/10.1007/BF03397282
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03397282