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Strain-Induced Porosity and Hydrogen Embrittlement in Zirconium

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Abstract

Pronounced porosity, decreasing with distance from the fracture surface, is found in the necked region of tensile specimens tested at room temperature or liquid nitrogen temperature. A hydrogen solution treatment followed by a quench prevents pore formation in tests at —196°C, but has little effect on tests made at room temperature. Reduction of area values at —196°C are strikingly improved by the same treatment, but show no improvement in room temperature tests. The experimental results support the hypothesis that strain-induced porosity results with hydride initially present or, in material containing less than 50 ppm H, with hydride precipitated by strain aging.

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References

  1. M. J. Manjoine and W. L. Mudge, Jr.: Creep Properties of Annealed Unalloyed Zirconium. Trans. ASTM (1954) 54, p. 1050.

    Google Scholar 

  2. J. H. Keeler: Tensile Characteristics of Unalloyed Zirconium at Low and Moderate Temperatures. Trans. ASM (1955) 47, p. 157.

    Google Scholar 

  3. W. L. Mudge, Jr.: Effect of Hydrogen on the Embrittlement of Zirconium and Zirconium-Tin Alloys. Zirconium and Zirconium Alloys. (1953) Cleveland. ASM.

    Google Scholar 

  4. C. M. Schwartz and M. W. Mallett: Observations on the Behavior of Hydrogen in Zirconium. Trans. ASM (1954) 46, p. 640.

    Google Scholar 

  5. C. A. Zapffe: Hydrogen Theory for Brittle Ship Plates. Metal Progress (1951) 59, p. 802.

    Google Scholar 

  6. J. H. Keeler and H. M. Davis: Density and Hydrogen Occlusion of Some Ferrous Metals. Trans. AIME (1953) 197, p. 44; Journal of Metals (January 1953). I

    Google Scholar 

  7. W. A. Bell and A. H. Sully: Some Effects of Hydrogen on the Delayed Fracture of High-Tensile Steel. Journal Iron and Steel Inst. (1954) 178, p. 15.

    Google Scholar 

  8. E. A. Gulbransen and K. F. Andrew: Crystal Structure and Thermodynamic Studies on the Zirconium-Hydrogen Alloys. Journal Electrochemical Soc. (1954) 101, p. 474.

    Article  Google Scholar 

  9. E. A. Gulbransen and K. F. Andrew: The Solubility and Decomposition Pressures of Hydrogen in α-Zirconium. Trans. AIME (1955) 203, p. 136; Journal of Metals (January 1955).

    Google Scholar 

  10. G. Hägg: Röntgenuntersuchungen über die Hydride von Titan, Zirkonium, Vanadin und Tantal. Ztsch. für Physikalische Chemie (1930) B11, p. 433.

    Google Scholar 

  11. H. Schwartzbart and W. F. Brown, Jr.: Notch-Bar Tensile Properties of Various Materials and Their Relation to the Unnotched Flow Curve and Notch Sharpness. Trans. ASM (1954) 46, p. 998.

    Google Scholar 

  12. J. D. Lubahn: Notch Tensile Testing. Fracturing of Metals. (1948) Cleveland. ASM.

    Google Scholar 

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TP 4088E. Manuscript, Apr. 12, 1955. Philadelphia Meeting, October 1955.

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Forscher, F. Strain-Induced Porosity and Hydrogen Embrittlement in Zirconium. JOM 8, 536–543 (1956). https://doi.org/10.1007/BF03377724

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  • DOI: https://doi.org/10.1007/BF03377724

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