Abstract
The fractionation of five heavy metals in a washing aggregate sludge, a sewage sludge, a clay-rich sediment, the mixtures of these materials and the lightweight aggregates manufactured with them has been determined by applying the optimized European Community Bureau of Reference sequential extraction procedure in order to evaluate the effects of the heating process on the extraction of these elements. Additionally, preparation of eluates by aggregate leaching has been performed in accordance with the UNE-EN-H44-3 standard. The availability of all the studied heavy metals has been reduced by the thermal treatment, since most of the heavy metals have become part of the undigested material in the lightweight aggregates. Nickel has been the heavy metal that has presented the highest concentration in the eluates obtained after completion of the single extraction procedure in the lightweight aggregates. The studied lightweight aggregates may be used in lightweight concrete manufacturing from the standpoint of heavy metal leaching.
Similar content being viewed by others
References
Cappuyns, V.; Swennen, R., (2009). Sediment characterization during oxidation and ripening and evaluation of its potential reuse. Environ. Tech., 30(8), 785–797 (13 pages).
Castells, X. E., (2000). Reciclaje de residuos industriales, 1st. Ed. Díaz de Santos, S.A., 74–75 (2 pages).
Cheeseman, C. R.; Makinde, A.; Bethanis, S., (2005). Properties of lightweight aggregates produced by rapid sintering of incinerator bottom ash. Resour. Conserv. Recy., 43(2), 147–162 (16 pages).
Chen, H. J.; Wang, S. Y.; Tang, C. W., (2010). Reuse of incineration fly ashes and reaction ashes for manufacturing lightweight aggregate. Constr. Build. Mater., 24(1), 46–55 (10 pages).
Dang, Z.; Liu, C.; Haigh, M. J., (2002). Mobility of heavy metals associated with the natural weathering of coal mine spoils. Environ. Poll., 118(3), 419–426 (8 pages).
Dantas, T. N. C.; Neto, A. A. D.; Moura, M. C. P. A.; Neto, E. L. B.; Forte, K. R.; Leite, R. H. L., (2003). Heavy metals extraction by microemulsion. Water Res., 37(11), 2709–2717 (9 pages).
Davidson, C. M.; Urquhart, G. J.; Ajmone-Marsan, F.; Biasioli, M.; da Costa Duarte, A.; Díaz-Barrientos, E.; Gr čman, H.; Hossack, I.; Hursthouse, A. S.; Madrid, L.; Rodridues, S.; Zupan, M., (2006). Fractionation of potentially toxic elements in urban soils from five European cities by means of a harmonised sequential extraction procedure. Analys. Chim. Acta., 565(1), 63–72 (10 pages).
Deer, W. A.; Howie, R. A.; Zussman, J., (). An introduction to the rock-forming minerals, 2nd. Ed. Longman Scientific and Technical, 431–454 (24 pages).
EHE-08, (). Instrucci’ on de Hormigón Estructural, 2nd. Ed. Permanent Concrete Commission. Ministry of Development of Spain. Centre for Publications.
European Council, (). Decision 2003/33/CE, establishing criteria and procedure for the acceptance of waste at landfill pursuant to Article 16 and Annex II to Directive 1999/31/ CE. Official Journal of European Communities of 16 January 2003.
Gleyzes, C.; Tellier, S.; Astruc, M., (2002). Fractionation studies of trace elements in contaminated soils and sediments: a review of sequential extraction procedures. Trac-Trends Analys. Chem., 21(6–7), 451–467 (17 pages).
Gómez-Ariza, J. L.; Giráldez, I.; Sánchez-Rodas, D.; Morales, E., (2000). Metal sequential extraction procedure optimized for heavily polluted and iron oxide rich sediments. Analys. Chim. Acta., 414(1–2), 151–164 (14 pages).
González-Corrochano, B.; Alonso-Azcárate, J.; Rodas, M., (2009). Production of lightweight aggregates from mining and industrial wastes. J. Environ. Manage., 90(8), 2801–2812 (12 pages).
González-Corrochano, B.; Alonso-Azcárate, J.; Rodas, M.; Barrenechea, J. F.; Luque, F. J., (2011). Microstructure and mineralogy of lightweight aggregates manufactured from mining and industrial wastes. Constr. Build. Mater., 25(8), 3591–3602 (12 pages).
Guevara-Riba, A.; Sahuquillo, A.; Rubio, R.; Rauret, G., (2004). Assessment of metal mobility in dredged harbour sediments from Barcelona (Spain). Sci. Total Environ., 321(1–3), 241–255 (15 pages).
Huang, S.C.; Chang, F.C.; Lo, S. L.; Lee, M.Y.; Wang, C. F.; Lin, J. D., (2007). Production of lightweight aggregates from mining residues, heavy metal sludge, and incinerator fly ash. J. Hazard. Mater., 144(1–2), 52–58. (7 pages).
Kapoor, A.; Viraraghavan, T., (1998). Removal of heavy metals from aqueous solutions using immobilized fungal biomass in continuous mode. Water Res., 32(6), 1968–1977 (10 pages).
Ma, L. Q.; Rao, G. N., (1997). Chemical fractionation of cadmium, copper, nickel, and zinc in contaminated soils. J. Environ. Qual., 26(1), 259–264 (6 pages).
Meegoda, J. N.; Kamolpornwijit, W.; Vaccari, D. A.; Ezeldin, A. S.; Walden, L.; Ward, W. A.; Noval, B. A.; Mueller, R. T.; Santora, S., (). Aggregates for construction from vitrified chromium contaminated soils. Engineered Contaminated Soils and Interaction of Soil Geomembranes (GSP 59). 31–46 (16 pages).
Moreno Grau, M. D., (). Toxicología Ambiental. Evaluación de Riesgo para la Salud Humana, 1st. Ed. Mc Graw Hill.
Nouri, J.; Khorasani, N.; Lorestani, B.; Karami; M. Hassani; Hassani, A. H.; Yousefi, N. (2009). Accumulation of heavy metals in soil and uptake by plant species with phytoremediation potential. Environ. Earth Sci. 59(2), 315–323 (9 pages).
Quevauviller, Ph., (1998). Operationally defined extraction procedures for soil and sediment analysis I. Standardization. Trac Trends Analys. Chem., 17(5), 289–298 (10 pages).
Rauret, G., (1998). Extraction procedures for the determination of heavy metals in contaminated soil and sediment. Talanta, 46(3), 449–455 (7 pages).
Rodrigo, M. A.; Rodríguez, L.; Cristina, A. C., (2004). Manual de operación y mantenimiento de la E.D.A.R. del campus tecnológico de Toledo, en el marco del proyecto de I+D “Desarrollo de sistemas de gestión de la explotación de estaciones de aguas residuales”, University of Castilla-La Mancha, Spain.
Royal Decree 1310/1990, of 29 October, regulating the use of sludge from sewage treatment plants in the agricultural sector. BOE n∘. 262, of 1 November 1990.
Sahuquillo, A.; López-Sánchez, J. F.; Rubio, R.; Rauret, G.; Thomas, R. P; Davidson, C. M.; Ure, A. M., (1999). Use of a certified reference material for extractable trace metals to assess sources of uncertainty in the BCR three-stage sequential extraction procedure. Analys. Chim. Acta., 382(3), 317–327 (11 pages).
Sahuquillo, A.; Rigol, A.; Rauret, G., (2003). Overview of the use of leaching/extraction tests for risk assessment of trace metals in contaminated soils and sediments. Trac Trends Analys. Chem., 22(3), 152–159 (8 pages).
Schlieker, M.; Schüring, J.; Hencke, J.; Schulz, H. D., (2001). The influence of redox processes on trace element mobility in a sandy aquifer — an experimental approach. J. Geochem. Explor., 73(3), 167–179 (13 pages).
UNE-EN-1744-3, (). Ensayos para determinar las propiedades químicas de los áridos. Parte 3: Preparación de eluatos por lixiviación de áridos.
U.S. E.P.A., (1995). Test methods for evaluating solid waste. Physical/chemical methods, SW-846, 3rd. Ed. U.S. Government Printing Office, Washington, DC.
Wunsch, P.; Greilinger, C.; Bieniek, D.; Kettrup, A., (1996). Investigation of the binding of heavy metals in thermally treated residues from waste incineration. Chemosphere, 32(11), 2211–2218 (8 pages).
Zemberyova, M.; Bartekova, J.; Hagarova, I., (2006). The utilization of modified BCR three-step sequential extraction procedure for the fractionation of Cd, Cr, Cu, Ni, Pb and Zn in soil reference materials of different origins. Talanta, 70(5), 973–978 (6 pages).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Corrochano, B.G., Azcárate, J.A. & Gonzalez, M.R. Heavy metal chemical fractionation and immobilization in lightweight aggregates produced from mining and industrial waste. Int. J. Environ. Sci. Technol. 8, 667–676 (2011). https://doi.org/10.1007/BF03326251
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/BF03326251