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Extraction of As from Copper Refining Electrolyte

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Abstract

SAMIM—Centro Ricerche Veneto has investigated the possibility of extracting arsenic by an aliphatic long-chain alcohol according to a solvating mechanism without adding any other completing or solvating agent. Laboratory tests were carried out with different extraction equipment: mixer settlers, contactors and columns. It was demonstrated that the highest efficiency of the process is reached by using a pulsed column with organic/aqueous ratio of 5/1. At the pilot scale with a pulsed column using an industrial electrolyte, the yield of recovery is high, and the recovery from the strip solution is easy and complete.

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Authors

Additional information

Agostino Baradel received his degree in chemistry from the University of Pavia. He is currently Senior Chemist at ENIRICHERCHE, S. Donato Milanese in Milan, Italy.

Renato Guerriero received his degree in physics from the University of Padera in 1968. He is currently Director at SAMIM—Centro Ricerche Veneto in Venice, Italy. Professor Guerriero is also a member of TMS.

Letizia Meregalli received her degree in industrial chemistry from the University of Venice in 1977. She is currently Head of the Studies and Planning Section at SAMIM—Centro Ricerche Veneto in Venice, Italy. Dr. Meregalli is also a member of TMS.

Italo Vittadini received his degree in chemistry in 1950. He is currently Head of the Hydro-metallurgy Section at SAMIM—Centro Ricerche Veneto in Venice, Italy.

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Baradel, A., Guerriero, R., Meregalli, L. et al. Extraction of As from Copper Refining Electrolyte. JOM 38, 32–37 (1986). https://doi.org/10.1007/BF03257918

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