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AlCl3.6H2O as a catalyst for simple and efficient synthesis of gem-dihydroperoxides from ketones and aldehydes using aqueous H2O2

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Abstract

AlCl3.6H2O was explored as an efficient catalyst for the synthesis of ingem-dihydroperoxides (DHPs) from ketones and aldehydes. The reactions took place within a short period of time using (30%) aqueous H2O2 as a “green” oxidant in acetonitrile under neutral conditions at room temperature to afford the products in high yields.

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Authors and Affiliations

  1. Department of Chemistry, Bu-Ali Sina University, Hamedan-65178, Islamic Republic of Iran

    D. Azarifar & K. Khosravi

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  1. D. Azarifar
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  2. K. Khosravi
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Correspondence to D. Azarifar.

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Azarifar, D., Khosravi, K. AlCl3.6H2O as a catalyst for simple and efficient synthesis of gem-dihydroperoxides from ketones and aldehydes using aqueous H2O2 . JICS 8, 1006–1013 (2011). https://doi.org/10.1007/BF03246556

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