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Poly(N,N′-dichloro-N-ethyl-benzene-1,3-disulfonamide, N,N,N′,N′-tetrachlorobenzene-1,3-disulfonamide, poly(N,N′-dibromo-N-ethyl-benzene-1,3-disulfonamide, and N,N,N′,N′-tetrabromobenzene-1,3-disulfonamide catalyzed formylation of amines and alcohols using ethyl formate under microwave irradiation

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Abstract

A simple, rapid, and efficient procedure for formylation of primary and secondary amines and alcohols using ethyl formate catalyzed with poly(N,N′-dichloro-N-ethyl-benzene-1,3-disulfonamide (PCBS), N,N,N′,N′-tetrachlorobenzene-1,3-disulfonamide (TCBDA), poly(N,N′-dibromo-N-ethyl-benzene-1,3-disulfonamide (PBBS) and also N,N,N′,N′-tetrabromobenzene-1,3-disulfonamide (TBBDA) was adopted. The reactions were performed under microwave irradiation with high yields.

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Authors and Affiliations

  1. Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamadan, Iran

    R. Ghorbani-Vaghei, H. Veisi & M. Amiri

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  1. R. Ghorbani-Vaghei
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  2. H. Veisi
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  3. M. Amiri
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Correspondence to R. Ghorbani-Vaghei.

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Ghorbani-Vaghei, R., Veisi, H. & Amiri, M. Poly(N,N′-dichloro-N-ethyl-benzene-1,3-disulfonamide, N,N,N′,N′-tetrachlorobenzene-1,3-disulfonamide, poly(N,N′-dibromo-N-ethyl-benzene-1,3-disulfonamide, and N,N,N′,N′-tetrabromobenzene-1,3-disulfonamide catalyzed formylation of amines and alcohols using ethyl formate under microwave irradiation. JICS 6, 761–768 (2009). https://doi.org/10.1007/BF03246167

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  • DOI: https://doi.org/10.1007/BF03246167

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