Skip to main content
Log in

Synthesis, structure and magnetic property of [Ce(DMSO)2(H2O)Fe(CN)6]

  • Article
  • Published:
Journal of the Iranian Chemical Society Aims and scope Submit manuscript

Abstract

The title complex, [Ce(DMSO)2(H2O)Fe(CN)6] (1), was obtained by solution reactions and structurally characterized by X-ray diffraction. The title complex is characteristic of a novel cyano-bridged two-dimensional stair-like layered structure. The magnetic property of the title complex is reported herein. The χM T value at 300 K is ca. 0.92 emu K mol−1. The temperature dependence behavior of molar magnetic susceptibility of the complex clearly indicates the presence of an antiferromagnetic interaction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. I. Amer, H. Alper, J. Am. Chem. Soc. 111 (1989) 927.

    CAS  Google Scholar 

  2. S. Matsubara, T. Kodama, K. Utimoto, Tetrahedron Lett. 31 (1990) 6379.

    CAS  Google Scholar 

  3. Y. Matuura, S. Matsushima, M. Sakamoto, Y. Sadaoka, J. Mater. Chem. 3 (1993) 767.

    CAS  Google Scholar 

  4. D.F. Mullica, F.H. Alvarez, E.L. Sappenfield, J. Solid State Chem. 129 (1997) 12.

    CAS  Google Scholar 

  5. D.F. Mullica, E.L. Sappenfield, Acta Crystallogr., Sect. C 47 (1991) 2433.

    Google Scholar 

  6. M. Sakamoto, K. Matsuki, R. Ohsumi, Y. Nakayama, A. Matsumoto, Y. Okawa, Bull. Chem. Soc. Jpn. 65 (1992) 2278.

    CAS  Google Scholar 

  7. E. Traversa, P. Nunziante, M. Sakamoto, K. Watanabe, Y. Sadaoka, Y. Sakai, Chem. Lett. 3 (1995) 189.

    Google Scholar 

  8. J.A. Kautz, D.F. Mullica, B.P. Cunningham, R.A. Combs, J.M. Farmer, J. Mol. Struct. 523 (2000) 175.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Y. M. Xie.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xie, Y.M., Wu, J.H. Synthesis, structure and magnetic property of [Ce(DMSO)2(H2O)Fe(CN)6]. JICS 5, 342–345 (2008). https://doi.org/10.1007/BF03246128

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03246128

Keywords

Navigation