Abstract
The critical micelle concentration (CMC) of hexadecylpyridinium bromide (HDPB) is determined conductometrically in binary mixtures of water + cosolvent at various temperatures and at low concentrations of sodium bromide, ranging from 0 to 2.4 × 10−2 M. Dimethylsulfoxide (DMSO) and acetonitrile (AN) were used as cosolvents added to water. The ability of NaBr to lower the CMC of HDPB in water is inhibited by DMSO and AN. Thermodynamic parameters of micellization ΔHm o, ΔSm o, and ΔGm o are evaluated according to the pseudo-phase model. The contribution of DMSO and AN in the micellization process of HDPB in aqueous electrolyte solutions are discussed in terms of the observed thermodynamic properties.
Similar content being viewed by others
References
D. Myers, Surfactant Science and Technology, VCH Publishers, Weinheim, 1988.
M.L. Corrin, W.D. Harkins, J. Am. Chem. Soc. 69 (1947) 683.
M. Shamsipur, N. Alizadeh, H. Gharibi, Indian J. Chem. 36 (1997) 1031.
C. Tanford, J. Phys. Chem. 78 (1974) 2469.
L. Magid, in: K.L. Mittal (Ed.), Solutions of Surfactants, Plenum, New York, 1979.
M.S. Bakshi, Bull. Chem. Soc. Jpn. 69 (1996) 2723.
F. Jalai, M. Shamsipur, N. Alizadeh, J. Chem. Thermodyn. 32 (2000) 755.
R. Palepu, H. Gharibi, D.M. Bloor, E. Wyn-Jones, Langmuir 9 (1993) 110.
M.S. Bakshi, J. Chem. Soc. Faraday Trans. 89 (1993) 4323.
N. Alizadeh, H. Gharibi, M. Shamsipur, Bull. Chem. Soc. Jpn. 68 (1995) 730.
K. Garcie, D. Turner, R. Palepu, Can. J. Chem. 74 (1996) 1616.
H. Gharibi, B.M. Razavizadeh, A.A. Rafati, Colloids Surf. A 136 (1998) 123.
Y. Moroi, Micelles; Theoretical and Applied Aspects, Plenum Press, New York, 1992.
M.S. Chauhan, K. Sharma, G. Kumar, S. Chauhan, Colloid Surf. A. 221 (2003) 135.
M. Koshinuma, T. Sasaki, Bull. Chem. Soc. Jpn. 48 (1975) 2755.
P. Molyneux, C.T. Rhode, J. Swarbrick, Faraday Trans. Soc. 61 (1965) 1043.
J.H. Clint, T. Walker, J. Chem. Soc. Faraday Trans. 171 (1975) 946.
D.F. Evans, M. Allen, B.W. Ninham, A. FoudaJ. Solution Chem. 13 (1984) 87.
K. Shinoda, M. Kabayashi, N. Yamaguchi, J. Phys. Chem. 91 (1987) 5292.
Z. Guoxi, Z. Buyao Acta Phys. Chim. Sin. 6 (1990) 513.
A. Callaghan, R. Doyle, E. Alexander, R. Palepu Lagmuir 9 (1993) 3422.
G.J. Janz, R.P. Tomkins, Nonaqueous Electrolyts Handbook, Academic Press, New York, 1979.
J.N. Philips, Trans. Faraday Soc. 51 (1955) 561.
D. Varade, T. Joshi, V.K. Aswal, P.S. Goyal, P.A. Goyal, P.A. Hassan, P. Bahadur, Colloid Surf. A. 259 (2005) 95.
D.J. Lee, Colloid Polym. Sci. 273 (1995) 539.
G. Sugihara, M. Hisatomi, J. Colloid Interf. Sci. 219 (1999) 31.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jalali, F., Shaeghi Rad, A. Conductance study of the thermodynamics of micellization of 1-hexadecylpyridinium bromide in mixed solvents containing dilute electrolyte solutions. JICS 5, 309–315 (2008). https://doi.org/10.1007/BF03246123
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF03246123