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Very strong centrosymmetric [O...H...O]+ and asymmetric [O-H...O]+ hydrogen bonds in a new POM-Based hybrid material

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Abstract

A specific assembly process, driven by coexisting X-H...O hydrogen bonding and X...O short intermolecular contacts (X = C, N, O) is described, in which the pseudo-Keggin polyoxoanion and two types of molecule...cation pairs (with C1 and Ci symmetries) were assembled to the programmed supramolecular architecture. Cooperation of the positive-charge, resonance effect and the O=C...Oterminal intermolecular contact led to the short and strong symmetrical [O...H...O]+ hydrogen bond (O...O = 2.449(13) Å) in one of the molecule...cation pairs [C4H9NO...H...ONC4H9]+ with the H-bonded proton in the center of inversion. The other [C4H9NOH...ONC4H9]+ molecule...cation pair (non-centrosymmetric) was formed through a very strong asymmetric [O.H.O]+ hydrogen bond of 2.431(13) Å in length which was created via the synergistic effect between the minor N-H...O secondary interaction, +CAHB (positive-charge-assisted hydrogen bond) and RAHB (resonance assisted hydrogen bond) mechanisms.

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Authors and Affiliations

  1. Department of Chemistry, Ferdowsi University of Mashhad, Mashhad, 91779, Iran

    M. Pourayoubi

  2. Department of Chemistry, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran

    M. Pourayoubi & A. R. Mahjoub

Authors
  1. M. Pourayoubi
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  2. A. R. Mahjoub
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Correspondence to A. R. Mahjoub.

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Pourayoubi, M., Mahjoub, A.R. Very strong centrosymmetric [O...H...O]+ and asymmetric [O-H...O]+ hydrogen bonds in a new POM-Based hybrid material. JICS 7, 864–874 (2010). https://doi.org/10.1007/BF03246081

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  • DOI: https://doi.org/10.1007/BF03246081

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