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Synthesis, spectroscopic and electrochemical characteristics of a novel Schiff-base from saccharin and tryptophan

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Abstract

In the present work, a novel Schiff-base was synthesized by the reaction of saccharin with tryptophan and characterized by elemental analysis as well as UV-Vis, FT-IR, 1H NMR spectroscopic data. The voltammetric behavior of Schiff-base was also studied on the hanging mercury drop electrode (HMDE) by using Square-Wave Voltammetry (SWV) and Cyclic Voltammetry (CV) techniques. The voltammograms of the Schiff-base exhibited two irreversible reduction peaks in Britton-Robinson buffer (pH 7.0–10.0) for the potential range from 0.0 V to −1.4 V. These peaks which appeared at more positive potentials than the reduction peaks of tryptophan and saccharin, may be assigned to the cathodic reductions of C-N+ and >C=N- moieties of Schiffbase.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Gazi University, 06500, Teknikokullar-Ankara, Turkey

    S. Çakır

  2. Department of Chemistry, Faculty of Arts and Sciences, Ondokuz Mayıs University, 55139, Kurupelit-Samsun, Turkey

    E. Biçer

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  1. S. Çakır
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  2. E. Biçer
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Correspondence to S. Çakır.

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Çakır, S., Biçer, E. Synthesis, spectroscopic and electrochemical characteristics of a novel Schiff-base from saccharin and tryptophan. JICS 7, 394–404 (2010). https://doi.org/10.1007/BF03246025

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