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Synthesis, spectroscopic, thermal, crystal characterization and biological activity of [Ni(phen)3][Ni(dipic)2]2.17H2O (H2dipic:pyridine-2,6-dicarboxylic acid, phen: 1,10-phenanthroline)

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Abstract

The new [Ni(phen)3][Ni(dipic)2]2.17H2O (1) (phen = 1,10-phenanthroline, dipic = dipicolinate)) has been prepared and characterized by elemental analysis, IR, UV-Vis, magnetic measurement and single crystal X-ray diffraction. The complex consists of two tris(1,10-phenanthroline)nickel(II) cations, two bis(dipicolinato)nickelate(II) anions and seventeen uncoordinated water molecules. The Ni(II) complex crystallizes in the triclinic space group P-1. The complex consisting of cation has distorted octahedral coordination by three bidentate phen ligands. In the complex anion, each dipic ligand simultaneously exhibits tridentate coordination modes through N atom of pyridine ring and oxygen atoms of the carboxylate groups. The crystal packing of 1 is a composite of intermolecular hydrogen bonding, π-π and C-H⃛π interactions. The complex has also been investigated in terms of biological activity and it showed high activity against S. aureus from Gram positive bacteria and C. albicans from yeast tested.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Sciences, Dumlupınar University, Kütahya, Turkey

    A. T. Çolak

  2. Department of Biology, Faculty of Arts and Sciences, Dumlupınar University, Kütahya, Turkey

    F. Çolak

  3. Department of Chemistry, Faculty of Arts and Sciences, Eskişehir Osmangazi University, Eskişehir, Turkey

    O. Z. Yeşilel

  4. Department of Chemistry, Faculty of Arts and Sciences, Atatürk University, Erzurum, Turkey

    E. Şahin

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  1. A. T. Çolak
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  2. F. Çolak
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  3. O. Z. Yeşilel
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  4. E. Şahin
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Correspondence to A. T. Çolak.

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Çolak, A.T., Çolak, F., Yeşilel, O.Z. et al. Synthesis, spectroscopic, thermal, crystal characterization and biological activity of [Ni(phen)3][Ni(dipic)2]2.17H2O (H2dipic:pyridine-2,6-dicarboxylic acid, phen: 1,10-phenanthroline). JICS 7, 384–393 (2010). https://doi.org/10.1007/BF03246024

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  • DOI: https://doi.org/10.1007/BF03246024

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