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Effect of two isomeric tetrapyrazolyl ligands on the catalytic oxidation of 3,5-di-tert-butylcatechol

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Abstract

Copper(II) salts were combined with a tetrapyrazolyl ligand ({N,N,N’,N’-tetrakis-[(3,5-dimethylpyrazol-1-yl)methyl)-1,4-phenylenediamine}L1 or {N,N,N’,N’-tetrakis-[(1,5-dimethylpyrazol-3-yl)methyl)-1,4-phenylenediamine}L2) and assessed as oxidation catalysts. The corresponding dioxygen complexes were generated in situ by mixing the copper salt and the pyrazolyl donor ligand in air. The oxidation of 3,5-di-tert-butylcatechol (DTBC), which affords 3,5-di-tert-butylquinone (DTBQ), was studied. The reaction rate was found to depend essentially on the nature of the junction linking two pyrazolyl neighbours.

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Authors and Affiliations

  1. Laboratory of Physical Organic Chemistry, Department of Chemistry, Faculty of Sciences, University Mohammed the First, B.P. 524, 60000, Oujda, Morocco

    I. Bouabdallah, R. Touzani, I. Zidane & A. Ramdani

  2. University Mohammed the First, Faculty Pluridisciplinary of Nador, B.P.300, 62700, Selouane, Nador, Morocco

    R. Touzani

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  1. I. Bouabdallah
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  2. R. Touzani
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  3. I. Zidane
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  4. A. Ramdani
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Correspondence to I. Bouabdallah.

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Bouabdallah, I., Touzani, R., Zidane, I. et al. Effect of two isomeric tetrapyrazolyl ligands on the catalytic oxidation of 3,5-di-tert-butylcatechol. JICS 4, 299–303 (2007). https://doi.org/10.1007/BF03245978

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  • DOI: https://doi.org/10.1007/BF03245978

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