Journal of the Iranian Chemical Society

, Volume 8, Issue 3, pp 694–707 | Cite as

Stoichiometric and free radical-scavenging kinetic studies of extractable polyphenols from pomegranate husk and pistachio hull

  • H. Haddadi
  • N. AlizadehEmail author
  • M. Shamsipur


In this work, the antiradical activity of fresh and aged skins of two Iranian varieties of pomegranate husk and pistachio hull was measured in order to assess their concentration in antioxidant potential usable in various fields. The radical scavenging capacity (RSC) of pomegranate husks and pistachio hulls samples were studied using the 2,2-diphenyl-1-picrylhydrazyl radical (DPPH.) assay. To determine the RSC and stoichiometric factor of the samplers, the second-order rate constants (k 2) and total H-atom-donating capacities (n) for the oxidation of polyphenol extracts by DPPH. were evaluated. The resulting k 2 values were also compared with those of the natural and synthetic antioxidants. The order of relative second-order rate constants in methanol at 25 °C found to be pomegranate husk > gallic acid > tannic acid > pistachio hull. Furthermore, the RSCs based on the calculation of area under kinetic curve (AUC), total stoichiometric factor of natural phenolics and commercial antioxidants were also compared.

Key words

Natural antioxidant Radical scavenging Pistachio Pomegranate Kinetic studies 


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  1. [1]
    F. Shahidi, P.K. Janitha, P.D. Wanasundara, Crit. Rev. Food Sci. Nutr. 32 (1992) 67.Google Scholar
  2. [2]
    A.J. Angelo, Crit. Rev. Food Sci. Nutr. 36 (1996) 175.Google Scholar
  3. [3]
    I.S. Young, J.V. Woodside, J. Clin. Pathol. 54 (2001) 176.Google Scholar
  4. [4]
    J.C. Espin, C. Soler-Rivas, H.J. Wichers, J. Agric. Food Chem. 48 (2000) 648.Google Scholar
  5. [5]a)
    H. Shi, E. Niki, Lipids 33 (1998) 365Google Scholar
  6. b).
    C. Sanchez-Moreno, J.A. Larrauri, F. Saura-Calixto, J. Sci. Food Agric. 76 (1998) 270.Google Scholar
  7. [6]
    D. Huang, B. Ou, M. Hampsch-Woodill, J.A. Flanagan, R.L. Prior, J. Agric. Food. Chem. 50 (2002) 4437.Google Scholar
  8. [7]
    J. Moore, J.J. Yin, L.L. Yu, J. Agric. Food Chem. 54 (2006) 617.Google Scholar
  9. [8]
    K.K. Adom, R.H. Liu, J. Agric. Food Chem. 53 (2005) 6572.Google Scholar
  10. [9]
    C. Zhihong, M. Jeffrey, Y. Liangli (Lucy), J. Sci. Food Agric. 54 (2006) 7429.Google Scholar
  11. [10]
    W. Brand-Williams, M.E. Cuvelier, C. Berset, Lebensm. Wiss. Technol. 28 (1995) 25.Google Scholar
  12. [11]
    J.C. Espin, C. Soler-Rivas, H.J. Wichers, C. Garcia-Viguera, J. Agric. Food Chem. 48 (2000) 1588.Google Scholar
  13. [12]
    D. Villano, M.S. Fernandez-Pachon, M.L. Moya, A.M. Troncoso, M.C. Garcia-Parrilla, Talanta 71 (2007) 230.Google Scholar
  14. [13]
    O. Dangles, G. Fargeix, C. Dufour, J. Chem. Soc., Perkin Trans. 2 (2000) 1653.Google Scholar
  15. [14]
    B.A. Cevallos-Casals, L. Cisneros-Zevallos, J. Agric. Food 51 (2003) 3313.Google Scholar

Copyright information

© Iranian Chemical Society 2011

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of Basic SciencesTarbiat Modares UniversityTehranIran
  2. 2.Departments of ChemistryRazi UniversityKermanshahIran

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