Development of new sorbents: I. Ordered porous phase of titanium phosphate

Journal of the Iranian Chemical Society volume 2, pages54–59(2005)Cite this article

Abstract

A new phase of titanium phosphate with a highly organized porous framework has been synthesized by a non-thermal digestion method. FTIR, TGA-DTA, XRD and SEM have been employed to study the primary product, calcined and digested materials. Pore diameters in the range of 22–90 Å have been obtained for the digested material as determined by nitrogen absorption measurements. Quantitative removal of copper(II) phthalocyanine and its derivative from aqueous medium have been achieved.

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References

  1. [1]

    J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicg, C.T. Schmitt, C.T.-W. Chu, D.H. Olson, E.W. Sheppard, S.B. Mccullen, J.B. Higgins, J.L. Schlenker, J. Chem. Soc. 114 (1992) 10834.

    CAS  Google Scholar 

  2. [2]

    L. Bonneviot, F. Beland, C. Danumah, S. Giasson, S. Kaliaguine (Eds.), Mesoporous Molecular Sieves, Elsevier, Amsterdam, 1998.

    Google Scholar 

  3. [3]

    S. L. James, Chem. Soc. Rev. 32 (2003) 1039.

    Google Scholar 

  4. [4]

    X.F. Guo, W.P. Ding, X.G.Wang, Q.J. Yan, Chem. Commun. (2001) 709.

  5. [5]

    N.K. Mal, S. Ichikawa, M. Fujiwara, Chem. Commun. (2002) 112.

  6. [6]

    J.S. Chang, S.E. Park, Q.M. Gao, G. Ferey, A.K. Cheetham, Chem. Commun. (2001) 859.

  7. [7]

    J.J. Jimenez, P.M. Torres, P.O. Pastor, E.R. Castellon, A.J. Lopez, D.L. Jones, J. Roziere. Adv. Mater. 10 (1998) 812.

    Google Scholar 

  8. [8]

    D.L. Jones, G. Aptel, M. Brandhorst, M. Jacquin, J.J. Jimenez, A.J. Lopez, P.M. Torres, I. Piwonski, E.P. Castellon, J. Zajac, J. Roziere, J. Mater. Chem. 10 (2000) 1957.

    CAS  Google Scholar 

  9. [9]

    A. Bhaumik, S. Inagaki, J. Am. Chem. Soc. 123 (2001) 691.

    CAS  Google Scholar 

  10. [10]

    A. Bhaumik, Proc. Indian. Acad. Sci. Vol. 114, No. 4 (2002) 451. Compounds, John Wiley & Sons, Inc., New York, 1986, pp. 168 and 477.

    CAS  Google Scholar 

  11. [11]

    C.L. Pan, W.X. Zhang, Y.L. Wang, Z. Zhou, D.Z. Jiang, S.J. Wu, T.H. Wu, Mater. Lett. 4430 (2003) 1.

    Google Scholar 

  12. [12]

    N.B. MeKeown, Chem. and Indust. (1999) 92.

  13. [13]

    K. Münch, A. Oberlinner, H.J. Uschmann, R. Wittlinger, in “Ink Makers Forum” at (European Coating Show) April 2001, Nurenberg, Germany, (International Congress for Printing Ink Manufacturers and their Suppliers).

  14. [14]

    B. Moulton, M.J. Zaworotko, Current Opinion in Solid State and Material Science 6 (2002) 117.

    CAS  Google Scholar 

  15. [15]

    M.J. Stillman, T. Nyokong, in: C. Leznoff, A.B. Lever (Eds.), Phthalocyanines; Properties and Applications, VCH, New York, 1989, p. 133.

    Google Scholar 

  16. [16]

    I. Szymczyk, H. Abramczyk, Pure. Appl. Chem. 76 (2004) 183.

    CAS  Google Scholar 

  17. [17]

    K. Schumacher, M. Grün, K.K. Unger, Micropor. Mesopor. Mater. 27 (1999) 201.

    CAS  Google Scholar 

  18. [18]

    S. Easton, J. Oil Colour Chem. Assoc. 49 (1966) 614.

    CAS  Google Scholar 

  19. [19]

    A. Corma, V. Fornes, Mt. Navarro, J.P. Pariente, J. Catal. 148 (1994) 569.

    CAS  Google Scholar 

  20. [20]

    N.B. Colthup, J. Opt. Soc. Am. 40 (1950) 397.

    CAS  Google Scholar 

  21. [21]

    K. Nakamoto, IR and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons, Inc., New York, 1986, pp. 168 and 477.

    Google Scholar 

  22. [22]

    A. Montes, E. Cosenza, G. Giannetto, E. Urquieta, R.A. de Melo, N.S. Gnep, M. Guisnet, in: L. Bonneviot, F. Beland, C. Danumah, S. Giasson, S. Kaliaguine (Eds.), Mesoporous Molecular Sieves 1998, Elsevier, Amsterdam, 1998, p. 237.

    Google Scholar 

  23. [23]

    M. Jaroniec, M. Kruk, A. Sayari, in: L. Bonneviot, F. Beland, C. Danumah, S. Giasson, S. Kaliaguine (Eds.), Mesoporous Molecular Sieves 1998, Elsevier, Amsterdam, 1998, p.

    Google Scholar 

  24. [24]

    K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouqerol, T. Siemieniewska, Pure. Appl. Chem. 57 (1985) 603.

    CAS  Google Scholar 

  25. [25]

    P. Trens, M.J. Hudson, R. Denoyel, J. Mater. Chem. 8 (1998) 2147.

    CAS  Google Scholar 

  26. [26]

    E.P. Barrett, L.G. Joyner, P.P. Halenda, J. Am. Chem. Soc. 73 (1951) 373.

    CAS  Google Scholar 

  27. [27]

    W.S. Ahn, D.H. Lee, T.J. Kim, J.H. Kim, G. Seo, R. Ryoo, Appl. Catal. 181 (1999) 39.

    CAS  Google Scholar 

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Affiliations

  1. Department of Chemistry, University of Reading, Whiteknights, Box 224, Reading, Berkshire, RG6 6AD, UK

    M. J. Hudson

  2. Department of Applied Chemistry, Chemistry Faculty, University of Tarbiat Moallem, 49-Mofatteh Avenue, Tehran, 15614, Iran

    S. Waqif Husain & M. Anbia

Authors
  1. M. J. Hudson
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  2. S. Waqif Husain
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  3. M. Anbia
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Correspondence to S. Waqif Husain.

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Hudson, M.J., Waqif Husain, S. & Anbia, M. Development of new sorbents: I. Ordered porous phase of titanium phosphate. JICS 2, 54–59 (2005). https://doi.org/10.1007/BF03245780

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Keyword

  • Mesopore
  • Ordered titanium phosphate
  • Copper(II) phthalocyanine removal