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Self-doped carboxylated polyaniline: effect of hydrogen bonding on the doping of polymers

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Abstract

This study examined the unique self-doping behavior of carboxylated polyaniline (PCA). The selfdoped PCA was synthesized using an environmentally benign enzymatic polymerization method with cationic surfactants. XPS showed that HCl-doped PCA contained approximately 34% of protonated amines but selfdoped PCA contained 9.6% of the doped form of nitrogen at pH 4. FTIR and elemental analysis showed that although the PCA was doped with the proton of strong acids at low pH via the protonation of amines, the selfdoping mechanism of PCA at pH > 4 was mainly due to hydrogen bonding between the carboxylic acid group and amine group.

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Authors and Affiliations

  1. School of Textiles, Yeungnam University, Gyeungsan, 712-749, Gyungbuk, Korea

    Seong-Cheol Kim

  2. The Center for Advanced Materials, Polymer Science Program, Departments of Chemistry and Physics, University of Massachusetts, 01854, Lowell, MA

    James Whitten & Jayant Kumar

  3. U. S. Army Natick Soldier Development and Engineering Center, 01760, Natick, Massachusetts

    Ferdinando F. Bruno & Lynne A. Samuelson

Authors
  1. Seong-Cheol Kim
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  2. James Whitten
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  3. Jayant Kumar
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  4. Ferdinando F. Bruno
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  5. Lynne A. Samuelson
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Correspondence to Jayant Kumar or Lynne A. Samuelson.

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Kim, SC., Whitten, J., Kumar, J. et al. Self-doped carboxylated polyaniline: effect of hydrogen bonding on the doping of polymers. Macromol. Res. 17, 631–637 (2009). https://doi.org/10.1007/BF03218921

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  • DOI: https://doi.org/10.1007/BF03218921

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