Macromolecular Research

, Volume 14, Issue 2, pp 205–208 | Cite as

Uniform grafting of poly(1,5-dioxepan-2-one) by surface-initiated, ring-opening polymerization

Article

Abstract

A polymeric film of a biodegradable poly(1,5-dioxepan-2-one) (PDXO) was formed on a gold surface by a combination of the formation of self-assembled monolayers (SAMs) presenting hydroxyl groups and the surfaceinitiated, ring-opening polymerization (SI-ROP) of 1,5-dioxepan-2-one (DXO). The SI-ROP of DXO was achieved by heating a mixture of Sn(Oct)2, DXO, and the SAM-coated substrate in anhydrous toluene at 55°C. The resulting PDXO film was quite uniform. The PDXO film was characterized by polarized infrared external reflectance spectroscopy, X-ray photoelectron spectroscopy, time-of-flight secondary ion mass spectrometry, atomic force microscopy, ellipsometry, and contact angle goniometry.

Keywords

biodegradable self-assembled monolayers poly(1,5-dioxepan-2-one) (PDXO) surface-initiated ringopening polymerization (SI-ROP) 

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Copyright information

© The Polymer Society of Korea and Springer 2006

Authors and Affiliations

  1. 1.Department of ChemistryHannam UniversityDaejeonKorea
  2. 2.Department of PhysicsChung-Ang UniversitySeoulKorea
  3. 3.Department of ChemistryKAISTDaejeonKorea

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