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Silver polymer electrolyte membranes for facilitated olefint transport: carrier properties, transport mechanism and separation performance

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Abstract

Facilitated transport membranes for the separation of olefin/paraffin mixtures have long been of interest in separation membrane science because olefins, such as propylene and ethylene, which are important chemicals in petrochemical industries, are currently separated by energy-intensive cryogenic distillation processes. Recently, solid polymer electrolyte membranes containing silver ions have demonstrated remarkable performance in the separation of olefin/paraffin mixtures in the solid state and, thus, they can be considered as alternatives to cryogenic distillation. Here, we review recent progress, and critical issues affecting in the use of facilitated olefin transport membranes; in particular, we provide a general overview with reference to carrier properties, transport mechanisms, and separation performance.

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Authors and Affiliations

  1. Center for Facilitated Transport Membranes, Korea Institute of Science and Technology, Cheongryang, P. O. Box131, 130-650, Seoul, Korea

    Jong Hak Kim & Yong Soo Kang

  2. Department of Applied Chemistry, Sejong University, 143-747, Seoul, Korea

    Jongok Won

Authors
  1. Jong Hak Kim
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  2. Yong Soo Kang
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  3. Jongok Won
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Kim, J.H., Kang, Y.S. & Won, J. Silver polymer electrolyte membranes for facilitated olefint transport: carrier properties, transport mechanism and separation performance. Macromol. Res. 12, 145–155 (2004). https://doi.org/10.1007/BF03218383

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  • DOI: https://doi.org/10.1007/BF03218383

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