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Gold Bulletin

, Volume 43, Issue 2, pp 80–87 | Cite as

Synthesis of gold(III) complexes of 2-(diphenylthiophosphino)aniline

  • Eduardo J. Fernándeza
  • Emma García-Luzuriagaa
  • Antonio Lagunab
  • José M. López-de-Luzuriagaa
  • M. Elena Olmosa
Open Access
Article

Abstract

The gold(III) complex [Au(C6F5)2(SPNH2)]CIO4 (1) containing the S,N-donor ligand 2-(diphenylthiop hosphino)aniline (S=PNH2) can be easily prepared by treatment of S=PNH2 with [Au(C6F5)2(OEt2)2]CIO4 and deprotonated with PPN(acac) to afford [Au(C6F5)2(SPNH)] (2). Complex 2 can also be obtained in a one-step reaction from SPNH2 and [Au(C6F5)2(acac)]. The electronic density in excess in 2 can be employed to incorporate a new metallic fragment to give the mixed complexes [Au(C6F5)2SPNH(MPPh3)]CIO4 (M=Au (3), Ag (4)). The crystal structures of 1 and 2 have been determined by X-ray diffraction, showing that the electronic density in excess in complex 2 is located in the Au-N-C fragment.

Keywords

Aniline Acac Dalton Trans Diphenylphosphino Nitrobenzyl Alcohol 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© World Gold Council 2010

Authors and Affiliations

  • Eduardo J. Fernándeza
    • 1
  • Emma García-Luzuriagaa
    • 1
  • Antonio Lagunab
    • 2
  • José M. López-de-Luzuriagaa
    • 1
  • M. Elena Olmosa
    • 1
  1. 1.Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La RiojaU.A.-CSICLogroñoSpain
  2. 2.Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de AragónUniversidad de Zaragoza-CSICZaragozaSpain

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