Abstract
The gold(III) complex [Au(C6F5)2(SPNH2)]CIO4 (1) containing the S,N-donor ligand 2-(diphenylthiop hosphino)aniline (S=PNH2) can be easily prepared by treatment of S=PNH2 with [Au(C6F5)2(OEt2)2]CIO4 and deprotonated with PPN(acac) to afford [Au(C6F5)2(SPNH)] (2). Complex 2 can also be obtained in a one-step reaction from SPNH2 and [Au(C6F5)2(acac)]. The electronic density in excess in 2 can be employed to incorporate a new metallic fragment to give the mixed complexes [Au(C6F5)2SPNH(MPPh3)]CIO4 (M=Au (3), Ag (4)). The crystal structures of 1 and 2 have been determined by X-ray diffraction, showing that the electronic density in excess in complex 2 is located in the Au-N-C fragment.
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The group in the University of La Rioja is working in gold chemistry since 1979 and they have produced more than 90 scientific papers and two patents. They focus their interest not only in the synthesis of new homo- and hetero-nuclear gold Compounds, but also in the study of some properties, such as Luminescence or biomedical behaviour, and in the application of theoretical calculations. Some of them have been invited to give talks at different International Conferences or Universities in America, Asia or Europe.
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Fernándeza, E.J., García-Luzuriagaa, E., Lagunab, A. et al. Synthesis of gold(III) complexes of 2-(diphenylthiophosphino)aniline. Gold Bull 43, 80–87 (2010). https://doi.org/10.1007/BF03214972
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DOI: https://doi.org/10.1007/BF03214972