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Catalytic gold

Applications of elemental gold in heterogeneous catalysis

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Abstract

Although gold as been little used in heterogeneous catalysis hitherto, the metal shows some very interesting properties which ensure continued study of it for this field. In particular its remarkably high selectivity in some reactions and striking activity in oxygen transfer catalysis have received significant attention.

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References

  1. M. Batista-Leal, J.E. Lester and C.A. Lucchesi,J. Electron Spectrosc. Relat. Phenom., 1977,11, 333–337

    CAS  Google Scholar 

  2. W.N. Delgass, M. Boudart and G. Parravano,J. Phys. Chem., 1968,72, 3563

    CAS  Google Scholar 

  3. I.W. Bassi, F.W. Lytle and G. ParravanoJ. Catal., 1976,42, 139–147

    CAS  Google Scholar 

  4. G. Cocco, S. Enzo, G. Fagherazzi, L. Schiffini, I.W. Bassi, G. Vlaic, S. Galvagno and G. ParravanoJ. Phys. Chem., 1979,83, 2527–2538

    CAS  Google Scholar 

  5. B.M.W. Trapnell,Proc. Roy. Soc. (London), 1953,A218, 566

    Google Scholar 

  6. R.J. Mikowski, M. Boudart and H.S. TaylorJ. Am. Chem. Soc, 1954,76, 3814–3819

    Google Scholar 

  7. R. Culver, J. Pritchard, and F.C. Tompkins, in ‘Proc. 2nd Int. Congr. Surf. Act.’, Vol. 2, p. 243, 1957

    CAS  Google Scholar 

  8. I. Pritchard and F.C. Tompkins,Trans. Faraday Soc., 1960,56, 540

    CAS  Google Scholar 

  9. B.J. Wood and H. Wise,J Phys. Chem., 1961,65, 1976–1983

    CAS  Google Scholar 

  10. M.U. Kislyuk and I.I. Tret’yakov,Kinet.Katal., 1977,18, 577

    CAS  Google Scholar 

  11. M.U. Kislyuk and I.I. Tret’yakov,Kinet. Katal., 1976,17, 1515–1518

    CAS  Google Scholar 

  12. H. Wise and K.M. SancierJ. Catal., 1963,2, 149–151

    CAS  Google Scholar 

  13. M.A. Avdeenko, G.K. Boreskov and M.G. Slin’ko, in ‘Problems of Kinetics and Catalysis’, Vol. 9, USSR Acad. Sci. Press, Moscow, 1957, p. 61

    Google Scholar 

  14. A. Couper, D.D. Eley, M.J. Hulatt and D.R. Rossington,Bull. Soc. Chim. Belg., 1958,67, 343–357

    CAS  Google Scholar 

  15. A. Couperand, D.D. Eley,Discuss. Faraday Soc., 1950,8, 172–184

    Google Scholar 

  16. G.K. Boreskov, V.I. Savchenko and V.V. Gorodetskii,Dokl. Akad. Nauk SSSR, 1969,189, 537–540

    CAS  Google Scholar 

  17. M.U. Kislyuk and I.I. Tret’yakov,Kinet. Katal., 1975,16, 791

    CAS  Google Scholar 

  18. I. Iida,Bull. Chem. Soc. Jpn., 1979,52, 2858–2862

    CAS  Google Scholar 

  19. O. Schmidt,Z. Phys. Chem., 1925,118, 193–239

    CAS  Google Scholar 

  20. G.C. Bond and P.A. Sermon,Gold Bull., 1973,6, 102–105

    CAS  Google Scholar 

  21. G.C.Bond, P.A. Sermon, G.Webb, D.A.Buchanan and P.B.WellsJ. Chem. Soc., Chem. Commun., 1973, (13), 444–445

  22. G.C. Bond,U.K. Pat. 1472 061 (1977)

    Google Scholar 

  23. G.C. Bond,U.K. Pat. 1472 062 (1977)

    Google Scholar 

  24. P.A. Sermon, G.C. Bond and P.B. Wells,J. Chem. Soc., Faraday Trans. I, 1979,75, 385–393

    CAS  Google Scholar 

  25. P. Tetenyi and K. Schachter,Acta Chim. (Budapest), 1968,56, 15–23

    Google Scholar 

  26. B.J. Wood and H. Wise,J. Catal., 1966,5, 135–145

    CAS  Google Scholar 

  27. R.S. Yolles, B.J. Wood and H. Wise,J. Catal., 1971,21, 66–69

    CAS  Google Scholar 

  28. R.P. Chambers and M. BoudartJ. Catal., 1966,5, 517–528

    CAS  Google Scholar 

  29. J. Erkelens, C. Kembali and A.K. Galway,Trans. Faraday Soc., 1963,59, 1181–1191

    CAS  Google Scholar 

  30. G. Parravano,J. Catal., 1968,11, 269

    CAS  Google Scholar 

  31. G. Parravano,J. Catal., 1970,18, 320–328

    CAS  Google Scholar 

  32. S. Galvagno and G. Parravano,J. Catal., 1978,55, 178–190

    CAS  Google Scholar 

  33. C.T.H. Stoddard and C. KemballJ. Colloid Sci., 1956,11, 532–542

    Google Scholar 

  34. C. Kemball and C.T.H. Stoddard,Proc. Roy. Soc (London), 1957,A241, 208–222

    Google Scholar 

  35. C. Kemball and R.L. Moss,Proc. Roy. Soc. (London), 1958,A244, 398–410

    CAS  Google Scholar 

  36. M. Legate and P.A. Sermon, in ‘Proc. 6th Int. Congr. Catal’., Vol. 1, pp. 603–610, 1976

    Google Scholar 

  37. S.H. Inami, B.J. Wood and H. Wise,J. Catd., 1969,13, 397–403

    CAS  Google Scholar 

  38. M. Boudart and L.D. Ptak,J. Catal., 1970,16, 90–96

    CAS  Google Scholar 

  39. T. Chevreau and F.G. GaultJ. Catal., 1977,50, 124

    CAS  Google Scholar 

  40. G.R. Lester,U.S. Pat. 3,652,694(1972)

  41. G.R. Lester,U.S. Pat. 3,652, 695 (1972)

    Google Scholar 

  42. LU. Meyer and A. de Meijere,Tetrahedron Lett., 1976, (6), 497–500

  43. U. Burger and E Mazenod,Tetrahedron Lett., 1976, (33), 2885

  44. G. Parravano,J. Catal., 1972,24, 233–240

    CAS  Google Scholar 

  45. R.J. Sampson and C.B. Spencer,U.K. Pat. 1354877 (1974)

  46. S.R. Dolhyj, L.J. Velenyi,U.S. Pat. 4 219 687

  47. D.I. Bradshaw, R.B. Moyes and P.B. Welk, in ‘Proc. 6th Int. Congr. on Catal.,’ Vol. 2, London, pp. 1042–1050, 1976

    Google Scholar 

  48. D.I. Bradshaw, R.B. Moves and P.B. WellsJ. Chem. Soc, Chem. Commun., 1975, (5), 137–138

  49. W.R. MacDonald and K.E. Hayes,J. Catal., 1970,18, 115–118

    CAS  Google Scholar 

  50. M.A. Chesters and G.A. Somorjai,Surf. Sci., 1975,52, 21–28

    CAS  Google Scholar 

  51. N.N. Dobrovol’skii and V.E. Ostrovskii,Kinet. Katal., 1971,12, 1495

    Google Scholar 

  52. N. Endow, B.J. Wood and H. Wise,J Catal., 1969,15, 316–318

    CAS  Google Scholar 

  53. N.N. Dobrovol’skii, V.E. Ostrovskii, A.M. Rabashov and M.I. Temkin,Dokl. Akad. Nauk SSSR, 1968,183, 1120

    Google Scholar 

  54. P.C. Richardson and D.R. Rossington,J. Catal., 1971,20, 420–422

    CAS  Google Scholar 

  55. T. Fukushima, S. Galvagno and G. ParravanoJ. Catal., 1979,57, 177–182

    CAS  Google Scholar 

  56. S. Evans, E.L. Evans, D.E. Parry, M.J. Tricker, M.J. Walters and J.M. Thomas,Faraday Discuss. Chem. Soc., 1975,58, 97

    CAS  Google Scholar 

  57. M.U. Kislyuk and I.I. Tret’yakov,Kinet. Katal., 1979,20, 387–392

    CAS  Google Scholar 

  58. R.W. Clayton and S.V. Norval,Catal. (London), 1980,3, 70–97

    CAS  Google Scholar 

  59. J.G. Hardy and M.W. Robert,J. Chem. Soc., D, Chem. Commun., 1971, (10), 494–495

  60. M.L. Kaliya, S.M. Brailovskii, O.N. Temkin and V.I. Moskovko,Kinet. Katal., 1979,20, 798–801

    CAS  Google Scholar 

  61. C.N. Hodges and L.C. Roselaar,J. Appl. Chem. Biotechnol., 1975,25, 609–614

    CAS  Google Scholar 

  62. G.C. Bond,GoldBull., 1972,5, 11–13

    CAS  Google Scholar 

  63. G.D. Kazakova, Yu. S. Mardashevr and B.V. Erofeev,Dokl. Akad. Nauk SSSR, 1975,220, 1106–1107

    CAS  Google Scholar 

  64. Yu. S. Mardashev and G.D. Kazakova,Dokl. Akad. Nauk B. SSSR, 1976,20, 803–805

    CAS  Google Scholar 

  65. I-D. Huang, L.M. Pilinski and K.K. Rao,Fr. Demanda 2,231,650

  66. I. Brihta and P. Luetic,Croat. Chem. Acta, 1957,29, 419

    CAS  Google Scholar 

  67. P. Tetenyi and K. Schachter,Acta Chim. Acad. Sci. Hung, 1968,56, 141–152

    CAS  Google Scholar 

  68. D.J. Boorh, D. Bryce-Smith and A. Gilbert,Chem. Ind., 1972, (17), 688–689

  69. Fr.Pat. 2,007,925

  70. U.K. Pat. 1152 817,Fr. Pat. 1,567,440 andU.S. Pat. 3,476,808

  71. U.S. Pat. 3,553,220

  72. US. Pat. 3,742,079

  73. German Offen. 1909959

  74. W.A. Bone and G.W. Andrew,Proc. Roy. Soc. (London), 1925,109A, 459

    Google Scholar 

  75. D.Y. Cha and G. ParravanoJ. Catal., 1970,18, 200–211

    CAS  Google Scholar 

  76. J.D. Brandner and H.C. Urey,J. Chem. Phys., 1945,13, 351–362

    CAS  Google Scholar 

  77. S. Galvano and G. Parravano,Ber.Bunsenges,Phys. Chem., 1979,83, 894–899

    Google Scholar 

  78. N.W. Cant and P.W. Frederickson,J. Catal., 1975,37, 531–539

    CAS  Google Scholar 

  79. D.J.C. Yates,Colloid Interface Sci., 1969,29, 194–204; C.R. Guerra and J.H. Schulman,Surf. Sci., 1967,7, 229–249; C.R. Guerra,Colloid Interface Sci., 1969,29, 229–234

    CAS  Google Scholar 

  80. A.M. Bradshaw and J. Pritchard,Proc. Roy. Soc. (London), 1970,A316, 169

    Google Scholar 

  81. M.L. Kottke, R.G. Greenlet and H.G. Tompkins,Surf. Sci., 1972,32, 231

    CAS  Google Scholar 

  82. J. Schwank, G. Parravano and H.L. GrubetJ. Catal., 1980,61, 19–28

    CAS  Google Scholar 

  83. G.R. Hennig,J Inorg. Nucl. Chem., 1962,24, 1129–1137

    CAS  Google Scholar 

  84. V.E. Ostrovskii and N.N. Dobrovol’skii, in ‘Ptoc. 4th Int. Congr. Catal.’, Vol. 2, pp. 9–19, 1968

    Google Scholar 

  85. W.R. Patterson and C. Kemball,J. Catal., 1963,2, 465–478

    CAS  Google Scholar 

  86. N.W. Cant and W.K. Hall,J. Phys. Chem., 1971,75, 2914–2921

    CAS  Google Scholar 

  87. G. Manara and G. Parravano,J. Catal., 1971,23, 379–387

    CAS  Google Scholar 

  88. G. Manara and G. Parravano,J Catal., 1974,32, 72

    CAS  Google Scholar 

  89. ET. Blues, D. Bryce-Smith, I.W.Lawston and G.D. Wall,J. Chem. Soc. Chem. Commun., 1974, 513–514

  90. E.T. Blues, D. Bryce-Smith and I.W. Lawston,GoldBull., 1976,9, 88–90

    CAS  Google Scholar 

  91. J. Figar and W. Haidinger,GoldBull., 1974,7, 100–102

    CAS  Google Scholar 

  92. J. Figar and W. Haidinget,Chem. Phys. Lett., 1973,19, 564–570

    CAS  Google Scholar 

  93. U.K. Pat. 462487,German Pat. 1192 280

  94. N.H.A. Van Ham, B.E. Nieuwenhuys and W.M.H. Sachtler,J. Catal., 1971,20, 408–411

    Google Scholar 

  95. V.V. Shalya, F.A. Yampol’skaya, R.A. Svishchuk and Ya. B. Gorokhovatskii,Kinet.Katal, 1973,14, 993

    CAS  Google Scholar 

  96. G.K. Boreskov, M.G. Slin’ko and E.I. Volkava,Dokl. Akad. Nauk SSSR, 1953,92, 109–110

    CAS  Google Scholar 

  97. C.G. Vayenas and H.M. SaltsburgJ. Catal., 1979,57, 296–314

    CAS  Google Scholar 

  98. J. Schwank, S. Galvagno and G. Parravano,J. Catal., 1980,63, 415–424

    CAS  Google Scholar 

  99. W.M.H. Sachtler, G.J.H. Dorgelo and A.A. Holsher,Surf. Sci., 1966,5, 221

    CAS  Google Scholar 

  100. T.S. Starostina, A.V. Khasin, G.K. Boreskov and L.M. Plyasova,Dokl. Akad. Nauk SSSR, 1970,190, 394

    CAS  Google Scholar 

  101. E.R.S. WinterJ. Chem. Soc. (London), 1968, A 2889

  102. A. Cros, J. Derrien and F. Salvan,Surf. Sei., 1981,110, 471–490

    CAS  Google Scholar 

  103. K. Gossner and H. Bischof,Z. Phys. Chem. (Frankfurt), 1972,78, 277–297,and 1972,79, 78–82

    CAS  Google Scholar 

  104. M. Dole, D.F.P. Rudd, G.R. Muchow and C. Comte,J. Chem. Phys., 1952,20, 961–968

    CAS  Google Scholar 

  105. Y. Ono, T. Matsumura, N. Kitajima and S. FukuzumiJ. Phys. Chem., 1977,81, 1307

    CAS  Google Scholar 

  106. K. Tamura, K. Tarama and E. Suito,Nippon Kagaku Zasshi, 1959,80, 10

    CAS  Google Scholar 

  107. S. Kishimoto and M. Nishioka,J. Phys. Chem., 1972,76, 1907–1908

    CAS  Google Scholar 

  108. S. Kishimoto,J. Phys. Chem., 1973,77, 1719

    CAS  Google Scholar 

  109. M.A. Bhakta and H.A. Taylor,J. Chem. Phys., 1966,44, 1264–1270

    CAS  Google Scholar 

  110. V.D. Yagodovskii and D.N. Gruzdev,Kinet. Katal., 1969,10, 833

    CAS  Google Scholar 

  111. M.A. Bhakta,Corr. Sci., 1981,50, 490–491

    CAS  Google Scholar 

  112. W.M.H. Sachtler and J. Fahrenfort, in ‘Proc. 2nd Int. Congr. Caral.’, Vol. 1, Paris, 1960, (publ. 1961), pp. 838–848.

    Google Scholar 

  113. W.M.H. Sachtler and N.H. deBoer,J. Phys. Chem., 1960,64, 1579–1580

    CAS  Google Scholar 

  114. J. Fahrenfort, L.L. van Rijen and W.M.H. Sachtler, in ‘Proc. Symp. Mech. Heterogen. Catal.’, Amsterdam, 1959, pp. 23–48.

  115. D.D. Eley and P. Luetic,Trans. Faraday Soc., 1957,53, 1483–1487

    CAS  Google Scholar 

  116. G.M. Schwab and G. Holz,Z. Anorg. u. Allgem. Chem., 1944,252, 205

    CAS  Google Scholar 

  117. G.M. Schwab and H. Knoezinger,Z. Phys. Chem. (Frankfurt), 1963,37, 230–242

    CAS  Google Scholar 

  118. C.N. Hinshelwood and C.R. Prichard,Proc. Roy.Soc. (London), 1925,108A, 211

    Google Scholar 

  119. D.D. Eley and C.F. Knights,Proc. Roy. Soc., 1966,A294, 1–19

    Google Scholar 

  120. V.M. Stepanov, V.D. Yagodovskii and H. Agilar,Russ. J. Phys. Chem., 1975,49, 2275–2279

    CAS  Google Scholar 

  121. J.G. Hardy and M.W. Roberts,J. Chem. Soc. D., 1971, (10), 494–495

  122. C.N. Hinshelwood and C.R. Prichard,J. Chem. Soc., 1925,127, 1551–1555

    Google Scholar 

  123. A.G. Nasini, G. Saini, L. Trosarelli and E. Campi, in ‘Proc. 2nd Int. Congr. Catal.’, Vol. 2, Paris, 1960 (publ. 1961), p. 1873.

    Google Scholar 

  124. A.G. Nasini, G. Saini and L. Trosarelli,Pure Appl. Chem., 1962,4, 255–270

    CAS  Google Scholar 

  125. German Pat. 1277 249,Japanese Kokai 73-71387,German Offen. 25 11 364

  126. Y. Anju, I. Mochida, H. Yamamoto, A. Kato and T. Seiyama,Bull. Chem. Soc. Jpn., 1972,45, 2319

    CAS  Google Scholar 

  127. R.N. Haszeldine and F. Smith,J. Chem. Soc., 1950, 2689–2694

  128. L. Balsenc, H. Berthou and C.K. Joergensen,Chimia, 1975,29, 64

    Google Scholar 

  129. S.A. Cochran and H.H. Farrell,Surf. Sci., 1980,95, 359

    CAS  Google Scholar 

  130. F.P. Netzer, E. Bertel and J.A.D. Matthew,Solid State Commun., 1980,33, 519

    CAS  Google Scholar 

  131. E. Bertel and F.P. Netzer,Surf. Sci., 1980,97, 409

    CAS  Google Scholar 

  132. K. Kishi and S. Ikeda,J. Phys. Chem., 1974,78, 107

    CAS  Google Scholar 

  133. N.D. Spencer and R.M. Lambert,Surf. Sci., 1981,107, 237

    CAS  Google Scholar 

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Schwank, J. Catalytic gold. Gold Bull 16, 103–110 (1983). https://doi.org/10.1007/BF03214632

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