Skip to main content
SpringerLink
Log in

Extraction of cesium into nitrobenzene using hydrogen dicarbollylcobaitate in the presence of dibenzo-24-crown-8

  • Short communication
  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Extraction of microamounts of cesium by a nitrobenzene solution of hydrogen dicarbollylcobaltate (H+B−) in the presence of dibenzo-24-crown-8 (DB24C8,L) has been investigated. The equilibrium data have been explained assuming that the complexes HL+ and CsL+ are extracted into the organic phase. The values of extraction and stability constants of the species in nitrobenzene saturated with water have been determined.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. C. J. Pedersen, J. Am. Chem. Soc., 89 (1967) 7017.

    Article  CAS  Google Scholar 

  2. J. M. Lehn, Angew. Chem., Intern. Ed. Engl., 27 (1989) 89.

    Article  Google Scholar 

  3. F. De Jong, D. N. Reinhoudt, Adv. Phys. Org. Chem., 17 (1980) 279.

    Article  Google Scholar 

  4. R. M. Izatt, J. S. Bradshaw, S. A. Nielsen, J. D. Lamb, J. J. Christensen, D. Sen, Chem. Rev., 85 (1985) 271.

    Article  CAS  Google Scholar 

  5. M. F. Hawthorne, D. C. Young, T. D. Andrews, D. V. Hove, R. L. Pilling, A. D. Pitts, M. Reintjes, L. F. Warren, P. A. Wegner, J. Am. Chem. Soc., 90 (1968) 879.

    Article  CAS  Google Scholar 

  6. E. Makrlík, Collect Czech. Chem. Commun., 57 (1992) 289.

    Article  Google Scholar 

  7. T. Iwachido, M. Minami, A. Sadakane, K. Toei, Chem. Lett., (1977) 1511.

  8. Y. Kudo, K. Kanamori, Y. Takeda, H. Matsuda, Analyt. Sci., 11 (1995) 119.

    Article  CAS  Google Scholar 

  9. P. Vańura, Z. Valentová, E. Makrlík, unpUblished results.

  10. P. Vańura, J. Rais, P. Selucký, M. Kyrš, Collect Czech. Chem. Commun., 44 (1979) 157.

    Google Scholar 

  11. P. Vańura, E. Makrlík, Collect Czech. Chem. Commun., 58 (1993) 1324.

    Article  Google Scholar 

  12. L. G. Sillén, B. Warnqvjst, Arkiv Kemi., 31 (1969) 315.

    Google Scholar 

  13. E. Makrlík, J. Hálová, M. Kyrš, Collect. Czech. Chem. Commun., 49 (1984) 39

    Google Scholar 

Download references

Author information

Author notes

  1. P. Vaňura

    Present address: Department of Analytical Chemistry, Prague Institute of Chemical Technology, Technická 5, 16628, Prague 6, Czech Republic

Authors and Affiliations

  1. Doubravčická 2 202, 100 00, Prague 10, Czech Republic

    P. Vaňura

  2. Institute of Interdisciplinary Studies, University of West Bohemia, Husova 11, 306 14, Pilsen, Czech Republic

    E. Makrlík

  3. V. Nezvala 758, 272 04, Kladno, Czech Republic

    Z. Valentová

Authors
  1. P. Vaňura
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. Makrlík
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Z. Valentová
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Vaňura, P., Makrlík, E. & Valentová, Z. Extraction of cesium into nitrobenzene using hydrogen dicarbollylcobaitate in the presence of dibenzo-24-crown-8. Journal of Radioanalytical and Nuclear Chemistry 253, 527–529 (2002). https://doi.org/10.1007/BF03191387

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03191387

Keywords

Search

Navigation