Skip to main content
Log in

Charging characteristics of alumina in molten aluminum

  • Published:
Metals and Materials Aims and scope Submit manuscript

Abstract

The charging characteristics of alumina particles suspended in a molten aluminum was experimentally determined by measuring a potential difference between the cathode of molten aluminum and the anode of molten aluminum containing alumina particles. The potential difference could be successfully measured by means of differential potential analysis. Experimental results show that alumina carries a positive charge by providing quasi-free electrons to the molten aluminum. Thus, the electrification of alumina in the molten aluminum could be indirectly determined by measuring the potential difference hetween two electrodes. The potential differences measured were in the range of 0.010 to 0.05m V, and increaseu as the purity of the alumina improved, and also as the amount of alumina auued to the molten aluminum increased. It is also interesting to note that the potential difference was appreciably increased by doping alumina with silica. whereas it was decreased by doping alumina with lithia.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. F. Yamao, K. Sassa, K. Iwai and S. Asai,Tetsu-to-Hagane 83, 30 (1997).

    CAS  Google Scholar 

  2. J. P. Park, Y. Tanaka, K. Sassa and S. Asai, inInt. Symp. on Electromagnetic Processing of Materials, p. 497, ISIJ, Nagoya, Japan (1994).

    Google Scholar 

  3. K. Hauffe, inOxidation of Metals, p. 8, Plenum press, New York (1965).

    Google Scholar 

  4. O. Kubaschewski and B. E. Hopkins, inOxidatioll of Metals and Alloys, p. 71, Butterworths, London (1967).

    Google Scholar 

  5. Y. H. Paik, H. C. Shin and J. M. Lee,Metals and Materials 4, 995 (1998).

    Article  CAS  Google Scholar 

  6. B. Erdman,Applicatioll Note #200, Keithley Instrument Inc., Cleveland, Ohio (1983).

    Google Scholar 

  7. S. Kal,Solid-State Electronics 18, 169 (1975).

    Article  ADS  Google Scholar 

  8. D. Chapman,Phil. Mag. 25, 475 (1913).

    Google Scholar 

  9. O. Stern,Z. Electrochem. 30, 508 (1924).

    CAS  Google Scholar 

  10. K. Hauffe and A. L. Sierk,Z. Phys. Chem. 196, 160 (1950).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Paik, Y.H., Lee, J.M. Charging characteristics of alumina in molten aluminum. Metals and Materials 5, 345–349 (1999). https://doi.org/10.1007/BF03187756

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03187756

Key words

Navigation