Skip to main content
Log in

Fabrication of gold nanoelectrodes based on nanolithography electrochemically through a conductive AFM tip

  • Articles
  • Published:
Chinese Science Bulletin

Abstract

Gold nanoelectrodes were fabricated by approach of combining surface self-assembly with nanolithography electrochemically through a conductive AFM tip. The controllable structure with width and distance in nanometer as a template was constructed by nanolithography patterning process, which was accomplished by a conductive AFM tip on certain highly ordered long-tail organosilane monolayers. Then through adsorption of Cd2+ and exposure of the Cd2+-loaded surface to gaseous H2S, CdS nanowires were generated in a template-controlled self-assembly process. Finally, metallic gold nanowires were conversed from CdS nanowires by treatment with the aqueous solution of HAuCl4 via a redox chemical process, which had good conductivity proved by C-AFM.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Maoz, R., Cohen, S. R., Sagiv, J., Nanoelectrochemical patterning of monolayer surfaces: Toward spatially defined self-assembly of nanostructures, Adv. Mater., 1999, 11: 55–61.

    Article  Google Scholar 

  2. Maoz, R., Frydman, E., Cohen, S. R. et al., Constructive nano-lithography: Site-defined silver self-assembly on nanoelectro-chemically patterned monolayer templates, Adv. Mater., 2000, 12: 424–429.

    Article  Google Scholar 

  3. Maoz, R., Frydman, E., Cohen, S. R. et al., Constructive nanolitho-graphy”: inert monolayers as patternable templates forin-situ nanofabrication of metal-semiconductor-organic surface structures—a generic approach, Adv. Mater., 2000, 12: 725–731.

    Article  Google Scholar 

  4. Hoeppener, S., Maoz, R., Cohen, S. R. et al., Metal nanoparticles, nanowires, and contact electrodes self-assembled on patterned monolayer templates-a bottom-up chemical approach, Adv. Mater., 2002, 14: 1036–1041.

    Article  Google Scholar 

  5. Liu, S. T., Maoz, R., Schmid, G. et al., Template guided self-assembly of [Au55] clusters on nanolithographically defined monolayer patterns, Nano Letters, 2002, 2(10): 1055–1060.

    Article  Google Scholar 

  6. Lee, I. Y., Han, S. W., Lee, S. J. et al., Formation of patterned continuous calcium carbonate films on self-assembled monolayers via nanoparticle-directed crystallization, Adv. Mater., 2002, 14(22): 1640–1643.

    Article  Google Scholar 

  7. Kapila, W. M., Amro, N. A., Gamo, J. C. et al., Fabrication of nanometer-sized protein patterns using atomic force microscopy and selective immobilization, Biophysical Journal, 2001, 80: 1891–1899.

    Article  Google Scholar 

  8. Wouters, D., Schubert, U. S., Constructive nanoliography and nanochemistry: local probe oxidation and chemical modification, Langmuir, 2003, 19: 9033–9038.

    Article  Google Scholar 

  9. Jiang, W., Luo, J. B., Wen, S. Z., Tribological properties of OTS self-assembled monolayers, Chinese Science Bulletin, 2001, 46(8): 698–701.

    Article  Google Scholar 

  10. Xu, G. H., Higashitani, K., Formation of OTS self-assembled monolayer on glass surface investigated by AFM, Chemical Journal of Chinese Universities (in Chinese), 2000, 21(8): 1257–1260.

    Google Scholar 

  11. Xu, G. H., Higashotani, K., Changes of the surface adhesion forces during the formation of OTS self-assembled monolayer investigated by AFM, Acta Physico-chemica Sinica (in Chinese), 1999, 15: 458–461.

    Google Scholar 

  12. Baptiste, A., Gibaud, A., Bardeau, J. F. et al., X-ray, micro-raman, and infrared spectroscopy structural characterization of self-assembled multilayer silane films with variable numbers of stacked layers, Langmuir, 2002, 18: 3916–3922.

    Article  Google Scholar 

  13. Hu, R. S., Liu, S. T., Zhu, Z. H. et al., Assembling gold nanoparticles on ultrasmooth silicon surface, Acta Physico-chimica Sinica (in Chinese), 2000, 16(3): 202–206.

    Google Scholar 

  14. Li, Q. G., Zheng, J. W., Liu, Z. F., Site-selective assembly of gold nanoparticles on silicon using AFM nano-oxidation technique, Chemical Journal of Chinese Universities (in Chinese), 2001, 22(7): 1216–1218.

    Google Scholar 

  15. Bietsch, A., Michel, B., Size and grain-boundary effects of a gold nanowire measured by conducting atomic force microscopy, Appl. Phys. Lett., 2002, 80(18): 3346–3348.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Zuliang Du.

About this article

Cite this article

Li, T., Zhang, X., Jiang, X. et al. Fabrication of gold nanoelectrodes based on nanolithography electrochemically through a conductive AFM tip. Chin. Sci. Bull. 50, 2560–2564 (2005). https://doi.org/10.1007/BF03183650

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03183650

Keywords

Navigation