Skip to main content
Log in

Alkyldibenzothiophenes: molecular tracers for filling pathway in oil reservoirs

  • Articles
  • Published:
Chinese Science Bulletin

Abstract

Based on the thermodynamic stability and hydrogen bond mechanisms, alkyldibenzothiophene molecular ratios, 4-/1-MDBT, 2,4-/1,4- and 4,6-/1,4-DMDBT, are used to characterize organic maturity and oil migration, which can act as molecular tracers for the filling orientation and pathway in oil reservoir. The application of aforesaid molecular parameters, in a Neogene sandstone reservoir of the XJ24-3 Oilfield, Zhujiangkou Basin and in an Ordovician carbonate reservoir of Karst pore-fissure-network type in the Tahe Oilfield, Tarim Basin, manifests that those ratios are reliable tracers compared with other molecular ratios, and thus, alkyldibezothiophene parameters may be used in a wide range of maturity, especially for highto post-mature oil and severely biodegraded oil, both of which are short of effective molecular parameters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. England, W., Mackenzie, A. S., Mann, D. M. et al., The movement and entrapment of petroleum fluids in the subsurface, J. Geological Society, 1987, 144: 327–347.

    Article  Google Scholar 

  2. Larter, S. R., Aplin, A. C., Geochemistry of reservoirs: an introduction, The Geochemistry of Reservoirs (eds. Cubitt, J. M., England, W. A.), London: The Geological Society Publishing House, 1995, 5–32.

    Google Scholar 

  3. Stoddart, D. P., Hall, P. B., Larter, S. R. et al., The reservoir geochemistry of the Edifisk Field, Norwegian North Sea, The Geochemistry of Reservoirs (eds. Cubitt, J. M., England, W. A.), London: The Geological Society Publishing House, 1995, 257–279.

    Google Scholar 

  4. Li, M., Larter, S. R., Stoddart, D. et al., Fractionation of pyrrolic nitrogen compounds in petroleum during migration-related geochemical parameters, The Geochemistry of Reservoirs (eds. Cubitt, J. M., England, W. A.), London: The Geological Society Publishing House, 1995, 103–123.

    Google Scholar 

  5. Li, M., You, H., Fowler, M. G. et al., Geochemical constraints on models for secondary petroleum migration along the Upper Devonian Rimbey-Meadowbrook reef trend in central Alberta, Canada, Organic Geochemistry, 1998, 29: 163–182.

    Article  Google Scholar 

  6. Horsfield, B., Clegg, H., Wilkes, H. et al., Maturity control of carbazole distributions in petroleum systems, Naturwissenschaften, 1998, 85: 233–237.

    Article  Google Scholar 

  7. Wang, T. G., Li, S. M., Zhang, S. C., Oil migration in the Lunnan region, Tarim Basin, China based on the pyrrolic nitrogen compound distribution, J. Petroleum Science & Engineering, 2004, 41(1): 123–134.

    Article  Google Scholar 

  8. Hughes, W. B., Use of thiophenic organosulfur compounds in characterizing crude oils derived from carbonate versus siliclastic sources, Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks (ed. Palacas, J. B.), AAPG Studies in Geology, Oklahoma: AAPG Press, 1984, 18: 181–196.

    Google Scholar 

  9. Connan, J., Bouroullec, J., Dessort, D. et al., The microbial input in carbonate-anhydrite facies of Sabkha palaeoenvironment from Guatemala: A molecular approach, Advances in Organic Geochemistry 1985 (eds. Leythhaeuser, D., Rullkötter, J.), Organic Geochemistry, 1986, 10: 29–50.

  10. Budzinski, H., Garrigues, P., Connan, J. et al., Determination of maturity indicators in alkylated aromatic series by gas chromatography-mass spectrometry (GC-MS), Organic Geochemistry: Adevances and Applications in Energy and the Natural Environment, 15th Meeting of the EAOG, Poster Abstracts (ed. Manning, D. A. C.), Manchester: Manchester University Press, 1991, 619–623.

    Google Scholar 

  11. Chakhmakhchev, A., Suzuki, M., Takayama, K. et al., Distribution of alkylated dibenzothiophenes in petroleum as a tool for maturity assessments, Organic Geochemistry, 1997, 26(7–8): 483–490.

    Article  Google Scholar 

  12. Radke, M., Application of aromatic compounds as maturity indicators in source rocks and crude oils, Marine and Petroleum Geology, 1988, 5: 224–236.

    Article  Google Scholar 

  13. Santamaria-Orozco, D., Horsfield, B., Di Primio, R. et al., Influence of maturity on distributions of benzo- and dibenzothiophenes in Tithonian source rocks and crude oils, Sonda de Campeche, Mexico, Organic Geochemistry, 1988, 28 (7–8): 423–439.

    Google Scholar 

  14. Bao Jianping, Wang Tieguan, Chen Fajing, Relative abundance of alkyl dibenzothiophene in the source rocks and their geochemical significances, J. University of Petroleum, China (Edition of Natural Science) (in Chinese with English abstract), 1996, 20(1): 19–23.

    Google Scholar 

  15. Li Jinggui, Research development and prospect of maturity parameters of methylated dibenzothiophenees in marine carbonate rocks, Acta Sedimentologica Sinica (in Chinese with English abstract), 2000, 18 (3): 480–483.

    Google Scholar 

  16. Luo Jian, Chen Keming, Fu Lixin, Alkylated dibenzothiophene index—A new method to assess thermal maturity of source rocks, Acta Petrolei Sinica (in Chinese with English abstract), 2001, 22 (3): 27–31.

    Google Scholar 

  17. Wu Zhijun, Luo Binjie, Wang Youxiao et al., Distribution of dibenzothiophenes in crude oils from Tarim Basin and identification of major source rocks, Acta Sedimentologica Sinica (in Chinese with English abstract), 1995, 13(3): 98–106.

    Google Scholar 

  18. Lee, M. L., Vassllaros, D. L., White, C. M. et al., Retention indices for programmed-temperature capillary-column gas chromatography of polycyclic aromatic hydrocarbons, Analytical Chemistry, 1979, 51(5): 768–773.

    Article  Google Scholar 

  19. Wang Tieguan, Wang Chunjiang, He Faqi et al., Determination of double filling ratio of mixed crude oils in the Ordovician oil reservoir, Tahe Oilfield, Petroleum Geology & Experiment (in Chinese with English abstract), 2004, 26(1): 74–79.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Tieguan Wang.

About this article

Cite this article

Wang, T., He, F., Li, M. et al. Alkyldibenzothiophenes: molecular tracers for filling pathway in oil reservoirs. Chin.Sci.Bull. 49, 2399–2404 (2004). https://doi.org/10.1007/BF03183429

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF03183429

Keywords

Navigation