Abstract
A novel Co(II) coordination polymer bridged by 1,2,4,5-benzenetetracarboxylate is solvothermally synthesized, which possesses one-dimensional chain structure. The complex crystallizes in the triclinic crystal system,P−1 space group,a = 0.9610(1) nm,b = 0.9684(1) nm,c = 0.7924(1) nm,α = 96.695(9)°,β= 102.741(6)°,γ= 116.551(5)°,V = 0.6236(2) nm3,Z = 2,R 1 = 0.0342,wR 2 = 0.0990. The surface photovoltage spectra measurement shows that the title complex exhibits obvious photovoltage response in the 300–800 nm regions. The variable temperature susceptibility reveals that the complex possesses weak antiferromagnetic property.
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Niu, S., Fan, H., Jin, J. et al. Crystal structure, magnetic and photoelectric properties of coordination polymer [CO2(C3H4N2)4(C10H2O8)] n . Chin.Sci.Bull. 49, 1812–1815 (2004). https://doi.org/10.1007/BF03183405
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DOI: https://doi.org/10.1007/BF03183405