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Friedel-crafts reaction

Part IX. The action of propionic and butyric anhydrides on orcinol and further evidence of λ-substitution in resorcinol derivatives

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Summary

The study of the action of propionic and butyric anhydrides in presence of anhydrous aluminium chloride on orcinol shows that γ-substitution takes place almost exclusively. Therefore, this provides a conveniem method for the synthesis of hitherto unknown γ-orc-propiophenone and γ-orcbutyrophenone. Some of their interesting derivatives have been prepared. A study has been made of some deivatives of 5-hydroxy-4∶7-dimethyl-coumarin.

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References

  1. Desai and (Miss.) VakilProc. Ind. Acad. Sci., 1940,12, 391.

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  2. — and EkhlasIbid.,, 1938,8, 567.

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Authors and Affiliations

  1. Department of Chemical Technology, Bombay University, Bombay

    R. D. Desai & M. M. Gaitonde

  2. Chemistry Department, St. Xavier’s College, Bombay

    R. D. Desai & M. M. Gaitonde

Authors
  1. R. D. Desai
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  2. M. M. Gaitonde
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Desai, R.D., Gaitonde, M.M. Friedel-crafts reaction. Proc. Indian Acad. Sci. (Math. Sci.) 25, 364 (1947). https://doi.org/10.1007/BF03170770

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  • DOI: https://doi.org/10.1007/BF03170770

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