Abstract
Proton spin-lattice relaxation timesT 1 in 17α hydroxy- and 21 hydroxy-progesterones have been performed in the temperature range from 100 to 400 K at the frequencies of 30 and 90 MHz. The dynamic processes involving the methyl group reorientation about the threefold symmetry axis of the C−C bond are separated, and their activation parameters are determined.
Similar content being viewed by others
References
Declerq J.P., Germain G., van Meerssche M.: Cryst. Struct. Commun.1, 9 (1972)
Dideberg O., Campsteyn H., Dupont L.: Acta Crystallogr. B32, 103 (1971)
Szyczewski A., Holderna-Natkaniec K., Natkaniec I.: J. Mol. Struct.650, 69 (2003)
Andrew E.R., Radomski J.: Solid State NMR2, 57 (1993)
Andrew E.R., Radomski J.: Solid Sate NMR2, 57 (1993)
Andrew E.R., Kempka M., Szyzcewski A.: Mol. Phys.88, 605 (1996)
Andrew E.R., Kempka M.: Solid State NMR2, 261 (1993)
Andrew E.R., Peplinska B.: Mol. Phys.70, 505 (1990)
Andrew E.R., Glowinkowski S., Radomski J., Szczesniak E.: Solid State NMR15, 227 (2000)
Steward J.J.P.: J. Comput. Chem.10, 209 (1989), ibid J. Comput. Chem.10, 221 (1989), ibid J. Comput. Chem.12, 320 (1991)
Hehre W.J., Radom L., Schleyer P.R., Pople J.A.: Ab Initio Molecular Orbital Theory. New York: Wiley 1986.
Becke A.D.: J. Chem. Phys.97, 9173 (1992)
Becke A.D.: J. Chem. Phys.98, 5648 (1993)
Lee C., Yang W., Parr R.G.: Phys. Rev. B37, 785 (1988)
Frisch M.J., Trucks G.W., Schlegel H.B., Scuseria G.E., Robb M.A., Cheeseman J.R., Zakrzewski V.G., Montgomery J.A., Stratmann R.E., Burant J.C., Dapprich S., Millam J.M., Daniels A.D., Kudin K.N., Strain M.C., Farkas O., Tomasi J., Barone V., Cossi M., Cammi R., Mennucci B., Pomelli C., Adamo C., Clifford S., Ochterski J., Petersson G.A., Ayala P.Y., Cui Q., Morokuma K., Malick D.K., Rabuck A.D., Raghavachari K., Foresman J.B., Cioslowski J., Ortiz J.V., Stefanov B.B., Liu G., Liashenko A., Piskorz P., Komaromi I., Gomperts R., Martin R.L., Fox D.J., Keith T., Al-Laham M.A., Peng C.Y., Nanayakkara A., Gonzalez C., Challacombe M., Gill P.M.W., Johnson B.G., Chen W., Wong M.W., Andres J.L., Head-Gordon M., Replogle E.S., Pople J.A.: Gaussian 98 (Revision A.7). Pittsburgh, Pa.: Gaussian Inc. 1998.
Jurga K.: J. Phys. E14, 555 (1981)
Kubo R., Tomita K.: J. Phys. Soc. Jpn.9, 888 (1954)
Szyczewski A., Holderna-Natkaniec K., Natkaniec I.: J. Mol. Struct.698, 41 (2004)
Szyczewski A., Holderna-Natkaniec K., Natkaniec I.: J. Mol. Struct.693, 49 (2004)
Dianoux A.J., Lande G. (eds.): Neutron Data Booklet, ILL Neutron for Sciences. Grenoble, France: Institute Laue-Langevin 2003.
Kearley G.J.: J. Chem. Soc., Faraday Trans. 282, 41 (1986)
Holderna-Natkaniec K., Szyczewski A., Natkaniec I., Khavryutchenko V.D.: Appl. Phys. A (Suppl.)2002, 1274.
Szyczewski A., Holderna-Natkaniec K., Natkaniec I.: Solid State NMR25, 21 (2004)
Duax W.L., Norton D.A.: Atlas of Steroid Structure. New York: IFI/Plenum 1975.
Szyczewski A., Holderna-Natkaniec K.: J. Mol. Struct.734, 129 (2005)
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Falinska, K., Holderna-Natkaniec, K., Jurga, K. et al. Proton relaxation studies of 17α hydroxy- and 21 hydroxy-progesterones by1H NMR. Appl. Magn. Reson. 29, 195–204 (2005). https://doi.org/10.1007/BF03167007
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF03167007