Abstract
Modification of the steady-state free precession (SSFP) multipulse technique for the effective detection of nuclear quadrupole resonance (NQR) signals was studied. This modification is based on the use of the preparatory pulse in the SSFP pulse sequences. It was shown that under certain conditions the total intensity of accumulated NQR signal can be increased. Experimental results of applying the proposed technique to nitrogen-14 NQR in the sample of sodium nitrite (NaNO2) are presented and convincingly demonstrate the technique’s effectiveness.
Similar content being viewed by others
References
Hirschfeld T., Klainer S.M.: J. Mol. Struct.58, 63–77 (1980)
Buess M.L., Garroway A.N., Miller J.B.: J. Magn. Reson.92, 348–362 (1991)
Yesinowski J.P., Buess M.L., Garroway A.N., Ziegeweid M., Pines A.: Anal. Chem.67, 2256–2263 (1995)
Marino R.A., Klainer S.M.: J. Chem. Phys.67, 3388–3389 (1977)
Klainer S.M., Hirschfeld T.B., Marino R.A. in: Fourier, Hadamard and Hilbert Transforms in Chemistry (Marshall A.G., ed.), pp. 147–182. New York: Plenum 1982.
Harding J.C., Wade D.A., Marino R.A., Sauer E.G., Klainer S.: J. Magn. Reson.36, 21–33 (1979)
Bradford R., Clay C., Strick E.: Phys. Rev.84, 157–158 (1951)
Carr H.Y.: Phys. Rev.112, 1693–1701 (1958)
Ostroff E.D., Waugh J.S.: Phys. Rev. Lett.16, 1097 (1966)
Rudakov T.N., Mikhaltsevich V.T.: Chem. Phys. Lett.363, 1–6 (2002)
Rudakov T.N., Mikhaltsevich V.T.: Phys. Lett. A309, 465–469 (2003)
Ernst R.R., Anderson W.A.: Rev. Sci. Instrum.37, 93–102 (1966)
Freeman R., Hill H.D.W.: J. Magn. Reson.4, 366–383 (1971)
Rudakov T.N., Mikhaltsevich V.T., Selchikhin O.P.: J. Phys. D Appl. Phys.30, 1377–1382 (1997)
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Rudakov, T.N., Mikhaltsevitch, V.T., Flexman, J.H. et al. Modified multipulse technique for the effective detection of pure nuclear quadrupole resonance. Appl. Magn. Reson. 25, 467–474 (2004). https://doi.org/10.1007/BF03166541
Received:
Revised:
Issue Date:
DOI: https://doi.org/10.1007/BF03166541