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Influence of nitroxides on CIDNP of micellised radical pairs and short-lived biradicals

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Abstract

The effects of stable nitroxide radicals on stimulated nuclear polarization (SNP) and chemically induced dynamic nuclear polarization (CIDNP) in short-lived consecutive biradicals and radical pairs in homogeneous solutions as well as spin-correlated radical pairs in micelles were studied in high and low magnetic fields. It is shown that experimentally observed effects of nitroxide additions on CIDNP and SNP can be well simulated taking into account only the increase in the rates of relaxation in the paramagnetic species constituting radical pairs or biradicals. Effects of coherent spin evolution in three-spin systems under study seem to be of negligible importance.

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Authors and Affiliations

  1. Institute of Chemical Physics, Russian Academy of Sciences, Moscow, Russian Federation

    V. F. Tarasov

  2. International Tomography Center, Russian Academy of Sciences, Institutskaya ulitsa 3A, 630090, Novosibirsk, Russian Federation

    S. R. Shakirov, N. V. Lebedeva, V. R. Gorelik & E. G. Bagryanskaya

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  1. S. R. Shakirov
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  2. N. V. Lebedeva
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  3. V. R. Gorelik
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  4. V. F. Tarasov
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  5. E. G. Bagryanskaya
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Shakirov, S.R., Lebedeva, N.V., Gorelik, V.R. et al. Influence of nitroxides on CIDNP of micellised radical pairs and short-lived biradicals. Appl. Magn. Reson. 30, 535–548 (2006). https://doi.org/10.1007/BF03166216

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  • DOI: https://doi.org/10.1007/BF03166216

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