Abstract
A semiquantitative treatment of hyperfine sublevel correlation spectra of aS=1/2,I=1 spin system is presented. The derived closed analytical expressions allow the determination of components of the dipolar and quadrupolar coupling tensors. The method is applicable if nonsecular terms can be neglected and if canonical orientations of the hyperfine interactions can be selected via a dominantg matrix or hyperfine anisotropy.
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Höfer P., Grupp A., Nebenführ H., Mehring M.: Chem. Phys. Lett.132, 279–282 (1986)
Astashkin A.V., Dikanov S.A. Tsvetkov Y.D.: J. Struct. Chem.25, 45 (1984)
Flanagan H.L., Singel D.J.: J. Chem. Phys.87, 5506 (1987)
Benetis N.P., Dikanov S.A.: J. Magn. Reson.175, 124 (2005)
Schweiger A., Jeschke G.: Principles of Pulse Electron Paramagnetic Resonance, p. 49, Oxford: Oxford University Press 2001.
Ramić E., Eichel R.-A., Dinse K.-P., Titz A., Schmidt B.: J. Phys. Chem. B in press (2006)
Stoll S., Schweiger A.: J. Magn. Reson.178, 42–55 (2006)
Dannhäuser J., Donaubauer W., Hampel F., Reiher M., Le Guennic B., Corzilius B., Dinse K.-P., Hirsch A.: Angew. Chem. Int. Ed.45, 3368 (2006)
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Corzilius, B., Ramić, E. & Dinse, K.P. HYSCORE analysis of nitrogen hyperfine interactions. Appl. Magn. Reson. 30, 499–512 (2006). https://doi.org/10.1007/BF03166214
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DOI: https://doi.org/10.1007/BF03166214