Abstract
Low-lying energy states of the [Fe3S4]0 cluster have been calculated by taking into account the double exchange, superexchange and vibronic interaction. It was found that the adiabatic potential of the excited state withS=0 corresponds to the full delocalization of the “excess” charge. From the analysis of experimental data of Mössbauer spectroscopy and the temperature dependence of the magnetic susceptibility the double exchange parametert≥4000 cm−1 and the vibronic interaction parameter λ2/2k cm−1 have been estimated.
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Edwards D.M.: cond-mat/0201558 (2002)
Papaefthymiou V., Girerd J.-J., Moura I., Moura J.J.G., Münck E.: J. Am. Chem. Soc.109, 4703–4710 (1987)
Gayda J.-P., Bertrand P., Theodule F.-X., Moura J.J.G.: J. Chem. Phys.77, 3387–3391 (1982)
Thomson A.J., Robinson A.E., Johnson M.K., Moura J.J.G., Moura I., Xavier A.V., LeGall J.: Biochim. Biophys. Acta.670, 93–100 (1981)
Day E.P., Peterson J., Moura I., Moura J.J.: J. Biol. Chem.263, 3684–3689 (1988)
Weigel J.A., Srivastava K.K.P., Day E.P., Münk E., Holm R.H.: J. Am. Chem. Soc.112, 8015–8023 (1990)
Bednorz J.G., Muller K.A.: Z. Phys. B64, 189–193 (1986)
Borshch S.A., Bominaar E.L., Blondin G., Girerd J.-J.: J. Am. Chem. Soc.115, 5155–5168 (1993)
Blondin G., Girerd J.-J.: Chem. Rev.90, 1359–1376 (1990)
Eremin M.V., Nikitin S.I., Prosvirnin S.Yu., Silkin N.I., Yusupov R.V.: Solid State Commun.117, 297–301 (2001)
Judd B.R., Operator Techniques in Atomic Spectroscopy. New York: McGraw Hill 1963.
Anderson P.W., Hasegawa H.: Phys. Rev.100, 675–681 (1955)
Gaponenko V.A., Eremin M.V., Yablokov Yu.V.: Fiz. Tverd. Tela (Leningrad)15, 1336–1344 (1973)
Bertrand P., Guigliarelli B., More C.: New J. Chem.15, 445–454 (1991)
Gamelin D.R., Bominaar E.L., Kirk M.L., Wieghardt K., Solomon E.I.: J. Am. Chem. Soc.118, 8085–8097 (1996)
Vermaas A., Groeneveld W.L.: Chem. Phys. Lett.27, 583–585 (1974)
Marathe V.R., Mitra S.: Chem. Phys. Lett.27, 103–106 (1974)
Abragam A., Bleaney B.: Electron Paramagnetic Resonance of Transition Ions. Oxford: Clarendon Press 1970.
Alt’shuler S.A., Kozirev B.M.: Electron Paramagnetic Resonance of Transition Metal Compounds. Moscow: Nauka 1972.
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Eremin, M.V., Nikitin, S.I. & Prosvirnin, S.Y. Low-lying states of trinuclear mixed-valence cluster: [Fe3S4]0 . Appl. Magn. Reson. 23, 97–104 (2002). https://doi.org/10.1007/BF03166187
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DOI: https://doi.org/10.1007/BF03166187