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Selective inversion in inhomogeneously broadened powder spectra

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Abstract

It is shown how amplitude-modulated radio-frequency pulses optimized for selective inversion of magnetization can be applied to static powder samples with inhomogeneously broadened spectra. Selective one-dimensional methods can in principle provide information similar to two-dimensional exchange spectroscopy, and they are often more efficient for determining the rates of dynamic processes. However, in systems where transverse magnetization is subject to significant homogeneous decay during the rf pulses, selective one-dimensional methods do not necessarily offer the expected advantages over two-dimensional spectroscopy.

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Authors and Affiliations

  1. Section de Chimie, Université de Lausanne, Rue de la Barre 2, CH-1005, Lausanne, Switzerland

    D. Theimer & G. Bodenhausen

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  1. D. Theimer
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  2. G. Bodenhausen
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Theimer, D., Bodenhausen, G. Selective inversion in inhomogeneously broadened powder spectra. Appl. Magn. Reson. 3, 1071–1077 (1992). https://doi.org/10.1007/BF03166174

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  • DOI: https://doi.org/10.1007/BF03166174

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