Abstract
The analytical expression describing dynamics of the nuclear magnetization with the use of double resonance nuclear magnetic resonance of a procedure of transfer of spin saturation under photo-induced chemical exchange is obtained. Three different experimental procedures for the definition of the effective rate constants and the quantum yield of responses are considered.
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Lewis F.D., Miller A.M., Salvi G.D.: Inorgan. Chem.34, 3173–3180 (1995)
Tarasov V.F., Bagryanskaya E.G., Shkrob J.A., Avdievich N.Z., Ghatlia N.D., Lukzen N.N., Sagdeev R.Z.: J. Am. Chem. Soc.117, 110–113 (1995)
Pouwels P.J.W., Kaptein R.: Appl. Magn. Reson.7, 107–116 (1994)
Sagdeev R.Z., Valyaev V.I., Leshina T.V., Molin Yu.N.: Chem. Phys. Lett.107, 231–234 (1984)
Sagdeev R.Z., Leshina T.V., Polyakov N.E., Maryasova V.I., Yurkovskaya A.V., Obynochny A.A.: Chem. Phys. Lett.96, 231–234 (1983)
Babailov S.P., Krieger J.H.: Russ. J. Struct. Chem.4, 753–756 (1995)
Babailov S.P., Krieger J.H., Resnikova E.F., Igumenov I.K.: Russ. Chem. Bull.5, 1038–1039 (1997)
Babailov S.P., Krieger J.H.: Chem. Phys. Rep.3, 503–509 (2001)
Babailov S.P., Krieger J.H.: Proceedings of the Joint 29th Ampere and 13th ISMAR International Conference on Magnetic Resonance and Related Phenomena (Ziessow D., Lubitz W., Lendzian F., eds.), vol. 1, pp. 230–231. Berlin: Technical University of Berlin 1998.
Forsen S., Hoffman R.A.: J. Chem. Phys.39, 2892–2895 (1963)
Bloch F.: Phys. Rev.70, 460–481 (1946); Bloembergen N., Purcell E.M., Pound R.V.: Phys. Rev.73, 679–698 (1948)
Anderson P.W.: J. Phys. Soc. Jpn.9, 316 (1954); Kubo R.: J. Phys. Soc. Jpn.9, 935 (1954)
Gutowsky H.S., Holm C.H.: J. Chem. Phys.25, 1228–1234 (1956)
Mc Connell H.M.: J. Chem. Phys.28, 1228–1234 (1956)
Sandstrom J.: Dynamic NMR Spectroscopy. London: Academic Press 1975.
Mann B.E.: J. Magn. Reson.21, 17 (1976); ibid J. Magn. Reson.25, 91 (1977)
Bertini I., Coutsolelos A.G., Dikiy A., Spyroulus G.A., Troganis A.: Inorg. Chem.35, 6308 (1996)
Babailov S.P., Gaun D.D., Krieger J.H.: Instrum. Exp. Tech.3, 164–165 (1999)
Ernst R.R., Bodenhausen G., Wokau A.: Principles of NMR in One and Two Dimensions. Oxford: Clarendon Press 1987.
Bruker Almanac 200. Rheinstetten: Bruker Analytik GmbH 2000.
Babailov S.P., Krieger J.H.: Russ. J. Struct. Chem.4, 714–730 (1998)
Babailov S.P., Coutsolelos A.G., Dikiy A., Spyroulias G.A.: Eur. J. Inorg. Chem.1, 303–306 (2001)
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Babailov, S.P., Krieger, J.H. NMR applications for a study of converted photochemical processes kinetics. Appl. Magn. Reson. 22, 589–595 (2002). https://doi.org/10.1007/BF03166135
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DOI: https://doi.org/10.1007/BF03166135